Synergistic degradation of phenol by Ag3PO4 photocatalytic-ozone catalytic oxidation

doi:10.19965/j.cnki.iwt.2022-0241

Abstract

Abstract:

A photocatalytic-catalytic ozone oxidation synergistic system was constructed with Ag₃PO₄ as photocatalyst and ozone was introduced，which greatly improved the degradation efficiency of phenol. The phenol（30 mg/L） solution could be completely degraded after 6 minutes and the time was shortened by 3 times compared with the single oxidation technology when the same degradation efficiency was achieved. The improvement of the synergistic degradation performance was due to the electrophilic characteristics of ozone. It not only accelerated the migration of photogenerated charges and improved the photocatalytic degradation activity，but also improved the efficiency of ozone utilization，and catalyzed the decomposition of ozone to generate more hydroxyl radicals（·OH） to synergistically improved the degradation and mineralization performance of phenol. It was further verified that ·OH was the main active species in the synergistic degradation system by quenching experiments. The effects of ozone concentration，catalyst dosage，phenol concentration and acidity and alkalinity on the degradation efficiency were investigated，and the photocatalysis-ozone catalytic oxidation synergistic degradation mechanism was proposed.

Key words: photocatalysis, ozone catalytic oxidation, synergistic degradation, Ag₃PO₄

摘要：

以Ag₃PO₄为光催化剂并通入臭氧构建了光催化-催化臭氧氧化协同体系，大幅度提高了对苯酚的降解效率。协同处理6 min后可将30 mg/L的苯酚溶液完全降解，在达到相同降解效率时，与单一氧化技术相比时间缩短了3倍。协同体系降解性能的提升源于臭氧的亲电特性，不仅加速了光生电荷的迁移，提升了光催化降解活性；同时还有效提高了臭氧利用效率，催化分解臭氧能产生更多的羟基自由基（·OH），协同促进了苯酚的降解矿化性能。进一步通过猝灭实验验证了·OH是协同降解体系的主要活性物种，考察了臭氧浓度、催化剂投加量、苯酚浓度和酸碱性对降解效率的影响，探讨了光催化-臭氧催化氧化协同降解苯酚的降解机理。

关键词: 光催化, 臭氧催化氧化, 协同降解, 磷酸银

CLC Number:

X703.1

Weijia AN,Tao Yang,Lingyu TIAN,Wenquan CUI,Yinghua LIANG. Synergistic degradation of phenol by Ag₃PO₄ photocatalytic-ozone catalytic oxidation[J]. Industrial Water Treatment, 2023, 43(1): 83-88.

安伟佳,杨涛,田玲玉,崔文权,梁英华. Ag₃PO₄光催化-臭氧催化氧化协同降解苯酚[J]. 工业水处理, 2023, 43(1): 83-88.

/ / Recommend / Download Citations

URL: https://www.iwt.cn/EN/10.19965/j.cnki.iwt.2022-0241

https://www.iwt.cn/EN/Y2023/V43/I1/83

Figures/Tables 4

References 21

1	BRILLAS E， GARCIA-SEGURA S. Benchmarking recent advances and innovative technology approaches of Fenton，photo-Fenton，electro-Fenton，and related processes：A review on the relevance of phenol as model molecule［J］. Separation and Purification Technology，2020，237：116337. doi:10.1016/j.seppur.2019.116337 doi: 10.1016/j.seppur.2019.116337 URL
2	孙家宁，孙韶华，宋娜，等. 高级氧化技术去除水中溴系阻燃剂的研究进展［J］. 工业水处理，2022，42（2）：19-26. URL
	SUN Jianing， SUN Shaohua， SONG Na，et al. Research progress of advanced oxidation technology to remove brominated flame retardants from water［J］. Industrial Water Treatment，2022，42（2）：19-26. URL
3	HU Jinshan， ZHANG Pengfei， AN Weijia，et al. In-situ Fe-doped g-C₃N₄ heterogeneous catalyst via photocatalysis-Fenton reaction with enriched photocatalytic performance for removal of complex wastewater［J］. Applied Catalysis B：Environmental，2019，245：130-142. doi:10.1016/j.apcatb.2018.12.029 doi: 10.1016/j.apcatb.2018.12.029 URL
4	刘畅，王宇寒，胡清，等. 太阳光/CuMnFe LDHs催化剂/过一硫酸盐体系降解双酚A［J］. 环境工程学报，2021，15（11）：3545-3560. doi:10.12030/j.cjee.202106117 doi: 10.12030/j.cjee.202106117 URL
	LIU Chang， WANG Yuhan， HU Qing，et al. Degradation of bisphenol A using CuMnFe LDHs catalyst and peroxymonosulfate under solar light［J］. Chinese Journal of Environmental Engineering，2021，15（11）：3545-3560. doi:10.12030/j.cjee.202106117 doi: 10.12030/j.cjee.202106117 URL
5	LIU Li， QI Yuehong， LU Jinrong，et al. A stable Ag₃PO₄@g-C₃N₄ hybrid core@shell composite with enhanced visible light photocatalytic degradation［J］. Applied Catalysis B：Environmental，2016，183：133-141. doi:10.1016/j.apcatb.2015.10.035 doi: 10.1016/j.apcatb.2015.10.035 URL
6	GUO Zhuang， CAO Hongbin， WANG Yuxian，et al. High activity of g-C₃N₄/multiwall carbon nanotube in catalytic ozonation promotes electro-peroxone process［J］. Chemosphere，2018，201：206-213. doi:10.1016/j.chemosphere.2018.02.176 doi: 10.1016/j.chemosphere.2018.02.176 URL
7	YANG Jin， XIAO Jiadong， CAO Hongbin，et al. The role of ozone and influence of band structure in WO₃ photocatalysis and ozone integrated process for pharmaceutical wastewater treatment［J］. Journal of Hazardous Materials，2018，360：481-489. doi:10.1016/j.jhazmat.2018.08.033 doi: 10.1016/j.jhazmat.2018.08.033 URL
8	YANG Tangtao， PENG Junmin， ZHENG Yun，et al. Enhanced photocatalytic ozonation degradation of organic pollutants by ZnO modified TiO₂ nanocomposites［J］. Applied Catalysis B：Environmental，2018，221：223-234. doi:10.1016/j.apcatb.2017.09.025 doi: 10.1016/j.apcatb.2017.09.025 URL
9	LU Jiang， SUN Jingxiang， CHEN Xixi，et al. Efficient mineralization of aqueous antibiotics by simultaneous catalytic ozonation and photocatalysis using MgMnO₃ as a bifunctional catalyst［J］. Chemical Engineering Journal，2019，358：48-57. doi:10.1016/j.cej.2018.08.198 doi: 10.1016/j.cej.2018.08.198 URL
10	LIU Li， DING Lan， LIU Yongguang，et al. A stable Ag₃PO₄@PANI core@shell hybrid：Enrichment photocatalytic degradation with π-π conjugation［J］. Applied Catalysis B：Environmental，2017，201：92-104. doi:10.1016/j.apcatb.2016.08.005 doi: 10.1016/j.apcatb.2016.08.005 URL
11	张海兵，周亚松，郭绍辉，等. 高级氧化技术处理苯胺废水应用进展［J］. 工业水处理，2021，41（6）：167-172. doi:10.11894/iwt.2020-0641 doi: 10.11894/iwt.2020-0641 URL
	ZHANG Haibing， ZHOU Yasong， GUO Shaohui，et al. Advances of advanced oxidation process to treat aniline wastewater［J］. Industrial Water Treatment，2021，41（6）：167-172. doi:10.11894/iwt.2020-0641 doi: 10.11894/iwt.2020-0641 URL
12	LIU Li， DING Lan， LIU Yongguang，et al. A stable Ag₃PO₄@PANI core@shell hybrid：Enrichment photocatalytic degradation with π-π conjugation［J］. Applied Catalysis B：Environmental，2017，201：92-104. doi:10.1016/j.apcatb.2016.08.005 doi: 10.1016/j.apcatb.2016.08.005 URL
13	DONG Pengyu， WANG Yuhua， CAO Baocheng，et al. Ag₃PO₄/reduced graphite oxide sheets nanocomposites with highly enhanced visible light photocatalytic activity and stability［J］. Applied Catalysis B：Environmental，2013，132/133：45-53. doi:10.1016/j.apcatb.2012.11.022 doi: 10.1016/j.apcatb.2012.11.022 URL
14	MA Jianfeng， LIU Qing， ZHU Lifang，et al. Visible light photocatalytic activity enhancement of Ag₃PO₄ dispersed on exfoliated bentonite for degradation of rhodamine B［J］. Applied Catalysis B：Environmental，2016，182：26-32. doi:10.1016/j.apcatb.2015.09.004 doi: 10.1016/j.apcatb.2015.09.004 URL
15	CUI Wenquan， AN Weijia， LIU Li，et al. Novel Cu₂O quantum dots coupled flower-like BiOBr for enhanced photocatalytic degradation of organic contaminant［J］. Journal of Hazardous Materials，2014，280：417-427. doi:10.1016/j.jhazmat.2014.08.032 doi: 10.1016/j.jhazmat.2014.08.032 URL
16	HUANG Shuquan， XU Yuanguo， ZHOU Ting，et al. Constructing magnetic catalysts with in-situ solid-liquid interfacial photo-Fenton-like reaction over Ag₃PO₄@NiFe₂O₄ composites［J］. Applied Catalysis B：Environmental，2018，225：40-50. doi:10.1016/j.apcatb.2017.11.045 doi: 10.1016/j.apcatb.2017.11.045 URL
17	LI Dongsheng， LIU Yong， YANG Yantao，et al. Rational construction of Ag₃PO₄/WO₃ step-scheme heterojunction for enhanced solar-driven photocatalytic performance of O₂ evolution and pollutant degradation［J］. Journal of Colloid and Interface Science，2022，608：2549-2559. doi:10.1016/j.jcis.2021.10.178 doi: 10.1016/j.jcis.2021.10.178 URL
18	HU Panru， LIU Li， AN Weijia，et al. Use of a core-shell composite Ag₃PO₄@TCNQ to improve photocatalytic activity and stability［J］.Applied Surface Science，2017，425：329-339. doi:10.1016/j.apsusc.2017.07.003 doi: 10.1016/j.apsusc.2017.07.003 URL
19	LIU Jisheng， FENG Chujun， LI Yanlin，et al. Photocatalytic detoxification of hazardous pymetrozine pesticide over two-dimensional covalent-organic frameworks coupling with Ag₃PO₄ nanospheres［J］. Separation and Purification Technology，2022，288：120644. doi:10.1016/j.seppur.2022.120644 doi: 10.1016/j.seppur.2022.120644 URL
20	吴雅琴，熊威，邹方远，等. 臭氧技术处理含盐对氯苯酚废水的研究［J］. 水处理技术，2022，48（1）：108-111.
	WU Yaqin， XIONG Wei， ZOU Fangyuan，et al. Research on ozonation to treat sodium salt p-chlorophenol wastewater［J］. Technology of Water Treatment，2022，48（1）：108-111.
21	AN Weijia， TIAN Lingyu， HU Jinshan，et al. Efficient degradation of organic pollutants by catalytic ozonation and photocatalysis synergy system using double-functional MgO/g-C₃N₄ catalyst［J］. Applied Surface Science，2020，534：147518. doi:10.1016/j.apsusc.2020.147518 doi: 10.1016/j.apsusc.2020.147518 URL

[1]	Yabin JIN, Tiantian XU, Dezhong ZHAO, Le ZHANG, Zhenjie WAN, Gaoming ZHANG. Advances in the synthesis of Bi₂O₃-based composite photocatalysts and the applications in water treatment [J]. Industrial Water Treatment, 2025, 45(3): 10-21.
[2]	Wei DONG, Li LIN, Huaizhang GU, Yunqiang LUO, Ping MA, Xiangyang LI. Photocatalytic properties of dual Z-scheme Bi₂MoO₆/Bi₂WO₆/Ag₃PO₄ heterojunction [J]. Industrial Water Treatment, 2024, 44(8): 81-89.
[3]	Zheng LIU, Long YANG, Zuoxu ZHOU, Lei ZHANG, Xunsheng JI. An advanced treatment project of wastewater from PA66 salt producted by butadiene process [J]. Industrial Water Treatment, 2024, 44(7): 185-189.
[4]	Bin TAN, Huiru HAO, Yutong XIANG, Yuning LIU, Qian ZHANG. Degradation of Enrofloxacin by photocatalytic system based on BC-BiOI/PMS [J]. Industrial Water Treatment, 2024, 44(6): 143-150.
[5]	Hongsen HUANG, Xinyu ZHENG, Zhenfeng LIN, Yongfu GUO. Photocatalytic properties of Z-scheme heterojunction BiO_2- _x /ZnWO₄ on antibiotics in water [J]. Industrial Water Treatment, 2024, 44(4): 138-146.
[6]	Xueliang WANG, Yongkui YANG. Engineering application of ozone catalytic oxidation in the treatment of monocrystalline silicon cutting fluid wastewater [J]. Industrial Water Treatment, 2024, 44(3): 195-198.
[7]	Youzhi YAO, Fei HUA, Kang WU, Zhou YE, Zhongliang ZHANG, Cheng QIAN. Research progress on photocatalytic degradation of organic pollutants in wastewater by graphene-based composites [J]. Industrial Water Treatment, 2024, 44(11): 1-8.
[8]	Guoyu LIU, Xiangyu CAO, Jianhua ZHENG. Research progress on cobalt-based oxide photocatalysts for degradation of organic pollutants [J]. Industrial Water Treatment, 2024, 44(11): 27-34.
[9]	Guohui WANG, Jiaguo YAN, Yanli Li, Xin WANG, Mei CHEN. Research progress of fouling mitigation in photocatalysis coupled membrane filtration systems [J]. Industrial Water Treatment, 2024, 44(10): 82-91.
[10]	Yongnian GUAN. Treatment of TFT-LCD wastewater by hydrolysis acidification+ two-stage AO/MBR+ozone catalytic oxidation+BAF+air flotation process [J]. Industrial Water Treatment, 2024, 44(10): 207-214.
[11]	Chuanxi YANG, Xiaoguang LIU, Chang GAO, Xiaoning WANG, Yonglin LIU, Wenping DONG, Lin LIU, Haofen SUN, Changqing LIU, Weiliang WANG. Research progress of novel two-dimensional layered nanomaterials MXene-based photocatalyst in water treatment [J]. Industrial Water Treatment, 2024, 44(1): 22-31.
[12]	Jinqi YU, Lei SUN, Guanghua HUANG, Caixing TIAN, Heqing ZHANG, Qingyuan TONG. Preparation of magnetic catalyst and its application in ozone catalytic oxidation combined with magnetic separation process [J]. Industrial Water Treatment, 2023, 43(9): 110-118.
[13]	Zhen WANG, Xiaohuan ZHENG, Yi YUAN, Kai ZHU, Yang WEI, Li XU, Gaoping XU. Progress of photocatalysis for the removal of natural organic matter from water [J]. Industrial Water Treatment, 2023, 43(9): 43-50.
[14]	Baoliang LIU, Zhihao YU, Qian PENG, Dongsheng LI, Huijun XU, Qingyang DU, Boming ZHANG. Preparation of TiOF₂ nano-catalyst and its ozone catalytic oxidation performance [J]. Industrial Water Treatment, 2023, 43(8): 115-122.
[15]	Yun YANG, Yuanyuan ZHOU, Hao HU, Shuijin YANG. Preparation and photocatalytic properties of MOF-808/MIL-101（Fe） [J]. Industrial Water Treatment, 2023, 43(8): 97-103.

Please choose a citation manager

Content to export

Synergistic degradation of phenol by Ag₃PO₄ photocatalytic-ozone catalytic oxidation

Ag₃PO₄光催化-臭氧催化氧化协同降解苯酚

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

Figures/Tables 4

References 21

Related Articles 15

Recommended Articles

Metrics

Comments

模态框（Modal）标题

Please choose a citation manager

Content to export