Preparation and photocatalytic properties of MOF-808/MIL-101（Fe）

doi:10.19965/j.cnki.iwt.2022-1056

Abstract

Abstract:

The metal-organic framework MOF-808/MIL-101（Fe） was prepared by solvothermal method. Rhodamine B（RhB） was used as the target pollutant to investigate the photocatalytic performance of MOF-808/MIL-101（Fe） composite. The results showed that when the mass fraction of MOF-808 was 7%，the performance of photocatalytic degradation of pollutants reached more than 95% under visible light. And the removal efficiency of the photocatalyst remained above 90% after 5 cycles of regeneration. In addition，through a series of characterizations such as XRD，FT-IR，UV-vis and TGA，the phase composition，thermal stability，photogenerated charge separation rate and optical properties of the composites were characterized and analyzed. Compared with a single type of photocatalyst，the composite material could effectively improve the separation efficiency of photogenerated electrons and showed excellent performance in the degradation of organic dye RhB. Radical trapping experiments showed that superoxide radicals and holes were the main active species，and a possible photocatalytic mechanism was proposed based on the above experiments and characterizations.

Key words: Zr-MOF, metal organic frameworks, photocatalysis

摘要：

利用溶剂热法制备复合型MOF-808/MIL-101（Fe）光催化剂。使用罗丹明B（RhB）作为目标污染物，通过调节不同MOF-808的负载量探究MOF-808/MIL-101（Fe）复合材料光催化性能与负载量之间关系。结果表明，在MOF-808质量分数为7%时，在可见光下其对RhB的光催化降解率可达95%以上，再生循环5个周期，光催化剂的去除率仍然维持90%以上，良好的循环稳定性源于复合材料的构建能有效地抑制电子和空穴的复合。通过XRD、FT-IR、UV-vis和TGA等一系列表征手段对复合物的物相组成、热稳定性、光生电荷分离率和光学性质等进行分析，复合材料的构建相较于单一类型的光催化剂有效地提高了光生电子的分离效率，在降解有机染料RhB方面表现出优异的性能。通过自由基捕获实验研究催化过程中可能存在的活性物种，实验表明超氧自由基和空穴是主要的活性物种，基于以上实验和表征提出了可能的光催化机理。

关键词: Zr-MOF, 金属有机骨架, 光催化

CLC Number:

TQ426.9
X703

Yun YANG, Yuanyuan ZHOU, Hao HU, Shuijin YANG. Preparation and photocatalytic properties of MOF-808/MIL-101（Fe）[J]. Industrial Water Treatment, 2023, 43(8): 97-103.

杨赟, 周媛媛, 胡豪, 杨水金. MOF-808/MIL-101（Fe）的制备及其光催化性能[J]. 工业水处理, 2023, 43(8): 97-103.

/ / Recommend / Download Citations

URL: https://www.iwt.cn/EN/10.19965/j.cnki.iwt.2022-1056

https://www.iwt.cn/EN/Y2023/V43/I8/97

Figures/Tables 9

Fig. 1 XRD patterns of MOF-808，MIL-101（Fe），MFML-7 and MFML-7 sample after five recycles

Fig. 2 FT-IR patterns of MOF-808，MIL-101（Fe） and MFML-7

Fig. 3 TGA patterns of MIL-101（Fe）and MFML-7

Fig. 4 Degradation diagram （a） and kinetic study （b） of RhB by samples

Fig. 5 SEM images of MFML-7 samples

Fig. 6 UV-Vis DRS spectra（a） and band gap（b）

Fig. 7 Photoresponse current （a） and electrical impedance spectrum （b）

Fig. 8 Effects of different scavengers on the photocatalytic property

Fig. 9 Photocatalytic mechanism of MOF-808/MIL-101（Fe） composites

References 23

1	ZHANG Qian， ZHAO Zhongkun， SHEN Zhurui，et al. One-step hydrothermal method to synthesize Bi/Bi₂MoO₆ composite for photoelectric catalyst［J］. Functional Materials Letters，2017，10（5）：1750053. doi:10.1142/S1793604717500539
2	CHANKHANITTHA T， NANAN S. Visible-light-driven photocatalytic degradation of ofloxacin（OFL） antibiotic and Rhodamine B（RhB） dye by solvothermally grown ZnO/Bi₂MoO₆ heterojunction［J］. Journal of Colloid and Interface Science，2021，582（Pt A）：412-427. doi:10.1016/j.jcis.2020.08.061
3	LIU Lumin， CHEN Zhao， ZHANG Jianwei，et al. Treatment of industrial dye wastewater and pharmaceutical residue wastewater by advanced oxidation processes and its combination with nanocatalysts：A review［J］. Journal of Water Process Engineering，2021，42：102122. doi:10.1016/j.jwpe.2021.102122
4	欧阳平，杜杰，张贤明，等. 吸附材料改性研究进展［J］. 应用化工，2021，50（2）：522-525，531. doi:10.3969/j.issn.1671-3206.2021.02.052
	OUYANG Ping， DU Jie， ZHANG Xianming，et al. Research progress on modification of adsorption materials［J］. Applied Chemical Industry，2021，50（2）：522-525，531. doi:10.3969/j.issn.1671-3206.2021.02.052
5	俞坤，葛玉杰，谢水波，等. 聚吡咯/石墨相氮化碳光催化材料的制备及其铀降解性能研究［J］. 应用化工，2021，50（1）：35-38. doi:10.3969/j.issn.1671-3206.2021.01.009
	YU Kun， GE Yujie， XIE Shuibo，et al. Synthesis of PPy/g-C₃N₄ photocatalytic materials and its degradation properties towards uranium［J］. Applied Chemical Industry，2021，50（1）：35-38. doi:10.3969/j.issn.1671-3206.2021.01.009
6	杨水金，彭放，周国辉，等. H₃PW₆Mo₆O₄₀/TiO₂-SiO₂光催化降解有机污染物的研究［J］. 徐州工程学院学报：自然科学版，2016，31（1）：19-26.
	YANG Shuijin， PENG Fang， ZHOU Guohui，et al. Photocatalytic degradation of organic dyes with H₃PW₆Mo₆O₄₀/TiO₂-SiO₂ ［J］. Journal of Xuzhou Institute of Technology（Natural Sciences Edition），2016，31（1）：19-26.
7	杨水金，胡豪，陈璐，等. CQDs/Bi₂SiO₅的制备及其光催化性能的研究［J］. 徐州工程学院学报：自然科学版，2020，35（4）：7-12.
	YANG Shuijin， HU Hao， CHEN Lu，et al. Study on preparation of CQDs/Bi₂SiO₅ and its photocatalytic performance［J］. Journal of Xuzhou Institute of Technology（Natural Sciences Edition），2020，35（4）：7-12.
8	杨水金，胡豪，周烽，等. H₆P₂Mo₉W₉O₆₂/MIL-101（Fe）的制备及其吸附甲基紫研究［J］. 徐州工程学院学报：自然科学版，2021，36（1）：7-14.
	YANG Shuijin， HU Hao， ZHOU Feng，et al. Preparation of H₆P₂Mo₉W₉O₆₂/MIL-101（Fe） and its adsorption for methyl violet［J］. Journal of Xuzhou Institute of Technology（Natural Sciences Edition），2021，36（1）：7-14.
9	惠尉添，史丽珠，赵毅，等. H₂O₂气相高级氧化法脱除烟气中多污染物研究进展［J］. 应用化工，2022，51（4）：1124-1128. doi:10.3969/j.issn.1671-3206.2022.04.043
	HUI Weitian， SHI Lizhu， ZHAO Yi，et al. Research progress on removal of multiple pollutants from flue gas by H₂O₂ advanced oxidation in gas phase［J］. Applied Chemical Industry，2022，51（4）：1124-1128. doi:10.3969/j.issn.1671-3206.2022.04.043
10	BANDEHALI S， SANAEEPUR H， EBADI AMOOGHIN A，et al. Biodegradable polymers for membrane separation［J］. Separation and Purification Technology，2021，269：118731. doi:10.1016/j.seppur.2021.118731
11	WAN Jun， YANG Weijie， LIU Jiaqing，et al. Enhancing an internal electric field by a solid solution strategy for steering bulk-charge flow and boosting photocatalytic activity of Bi₂₄O₃₁Cl _x Br_10- _x ［J］. Chinese Journal of Catalysis，2022，43（2）：485-496. doi:10.1016/s1872-2067(21)63897-4
12	DUAN Zeyu， ZHAO Xiaojun， WEI Chuanwan，et al. Ag-Bi/BiVO₄ chain-like hollow microstructures with enhanced photocatalytic activity for CO₂ conversion［J］. Applied Catalysis A：General，2020，594：117459. doi:10.1016/j.apcata.2020.117459
13	LI Guiliang， QI Yanmin， LIN Haibo，et al. Ni-metal-organic-framework（Ni-MOF） membranes from multiply stacked nanosheets（MSNs） for efficient molecular sieve separation in aqueous and organic solvent［J］. Journal of Membrane Science，2021，635：119470. doi:10.1016/j.memsci.2021.119470
14	YUE Ke， ZHANG Xiaodong， JIANG Shuntong，et al. Recent advances in strategies to modify MIL-125（Ti） and its environmental applications［J］. Journal of Molecular Liquids，2021，335：116108. doi:10.1016/j.molliq.2021.116108
15	QIN Xiangtao， QIANG Taotao， CHEN Lu，et al. Construction of 3D N-CQD/MOF-5 photocatalyst to improve the photocatalytic performance of MOF-5 by changing the electron transfer path［J］. Microporous and Mesoporous Materials，2021，315：110889. doi:10.1016/j.micromeso.2021.110889
16	VAHABI A H， NOROUZI F， SHEIBANI E，et al. Functionalized Zr-UiO-67 metal-organic frameworks：Structural landscape and application［J］. Coordination Chemistry Reviews，2021，445：214050. doi:10.1016/j.ccr.2021.214050
17	HUANG Zheao， ZHOU Jianqing， ZHAO Yingying，et al. Stable core-shell ZIF-8@ZIF-67 MOFs photocatalyst for highly efficient degradation of organic pollutant and hydrogen evolution［J］. Journal of Materials Research，2021，36：602-614. doi:10.1557/s43578-021-00117-5
18	LIU Lulu， ZHANG Lei， WANG Feng，et al. Bi-metal-organic frameworks type Ⅱ heterostructures for enhanced photocatalytic styrene oxidation［J］. Nanoscale，2019，11（16）：7554-7559. doi:10.1039/c9nr00790c
19	SAMY M， IBRAHIM M G， FUJII M，et al. CNTs/MOF-808 painted plates for extended treatment of pharmaceutical and agrochemical wastewaters in a novel photocatalytic reactor［J］. Chemical Engineering Journal，2021，406：127152. doi:10.1016/j.cej.2020.127152
20	SHI Huilong， LI Chunhu， WANG Liang，et al. Selective reduction of nitrate into N₂ by novel Z-scheme NH₂-MIL-101（Fe）/BiVO₄ heterojunction with enhanced photocatalytic activity［J］. Journal of Hazardous Materials，2022，424：127711. doi:10.1016/j.jhazmat.2021.127711
21	GU Yulong， LUO Hongsi， XU Wei，et al. Fabrication of MOF-808（Zr） with abundant defects by cleaving ZrO bond for oxidative desulfurization of fuel oil［J］. Journal of Industrial and Engineering Chemistry，2022，105：435-445. doi:10.1016/j.jiec.2021.10.005
22	田倩，吕勇，李晨光，等. g-C₃N₄的制备及其光催化降解诺氟沙星的机理及产物毒性研究［J］. 工业水处理，2022，42（11）：84-93.
	TIAN Qian， Yong LYU， LI Chenguang，et al. Preparation of g-C₃N₄ and its photocatalytic degradation mechanism of Norfloxacin and product toxicity evaluation［J］. Industrial Water Treatment，2022，42（11）：84-93.
23	张先盼，罗秋霞，严小琴，等. Fe₃O₄@Ag₃PO₄/AgCl光催化剂的制备及光降解性能研究［J］. 工业水处理，2021，41（8）：81-86.
	ZHANG Xianpan， LUO Qiuxia， YAN Xiaoqin，et al. Study on preparation and photocatalytic degradation performance of Fe₃O₄@Ag₃PO₄/AgCl［J］. Industrial Water Treatment，2021，41（8）：81-86.

[1]	Yabin JIN, Tiantian XU, Dezhong ZHAO, Le ZHANG, Zhenjie WAN, Gaoming ZHANG. Advances in the synthesis of Bi₂O₃-based composite photocatalysts and the applications in water treatment [J]. Industrial Water Treatment, 2025, 45(3): 10-21.
[2]	Wei DONG, Li LIN, Huaizhang GU, Yunqiang LUO, Ping MA, Xiangyang LI. Photocatalytic properties of dual Z-scheme Bi₂MoO₆/Bi₂WO₆/Ag₃PO₄ heterojunction [J]. Industrial Water Treatment, 2024, 44(8): 81-89.
[3]	Bin TAN, Huiru HAO, Yutong XIANG, Yuning LIU, Qian ZHANG. Degradation of Enrofloxacin by photocatalytic system based on BC-BiOI/PMS [J]. Industrial Water Treatment, 2024, 44(6): 143-150.
[4]	Hongsen HUANG, Xinyu ZHENG, Zhenfeng LIN, Yongfu GUO. Photocatalytic properties of Z-scheme heterojunction BiO_2- _x /ZnWO₄ on antibiotics in water [J]. Industrial Water Treatment, 2024, 44(4): 138-146.
[5]	Youzhi YAO, Fei HUA, Kang WU, Zhou YE, Zhongliang ZHANG, Cheng QIAN. Research progress on photocatalytic degradation of organic pollutants in wastewater by graphene-based composites [J]. Industrial Water Treatment, 2024, 44(11): 1-8.
[6]	Guoyu LIU, Xiangyu CAO, Jianhua ZHENG. Research progress on cobalt-based oxide photocatalysts for degradation of organic pollutants [J]. Industrial Water Treatment, 2024, 44(11): 27-34.
[7]	Guohui WANG, Jiaguo YAN, Yanli Li, Xin WANG, Mei CHEN. Research progress of fouling mitigation in photocatalysis coupled membrane filtration systems [J]. Industrial Water Treatment, 2024, 44(10): 82-91.
[8]	Chuanxi YANG, Xiaoguang LIU, Chang GAO, Xiaoning WANG, Yonglin LIU, Wenping DONG, Lin LIU, Haofen SUN, Changqing LIU, Weiliang WANG. Research progress of novel two-dimensional layered nanomaterials MXene-based photocatalyst in water treatment [J]. Industrial Water Treatment, 2024, 44(1): 22-31.
[9]	Zhen WANG, Xiaohuan ZHENG, Yi YUAN, Kai ZHU, Yang WEI, Li XU, Gaoping XU. Progress of photocatalysis for the removal of natural organic matter from water [J]. Industrial Water Treatment, 2023, 43(9): 43-50.
[10]	Wei CHEN, Wenli HU, Yumin CUI. Preparation and performance for ZrO₂-CNB composite photocatalysts [J]. Industrial Water Treatment, 2023, 43(7): 113-119.
[11]	Lihua LIU, Shan ZHONG, Lishan ZHANG, Baojiang LIU. Preparation of Ti-doped BiOCl nanosheets and its piezoelectric photocatalytic performance [J]. Industrial Water Treatment, 2023, 43(5): 101-106.
[12]	Ruilin PANG, Chuangrong MO, Xuetang XU, Jie PAN. Degradation of orange Ⅱ by Bi₂WO₆ photocatalyisis combined with peroxymonosulfate [J]. Industrial Water Treatment, 2023, 43(4): 71-77.
[13]	Longli LIN, Guoguang LIU, Lihua SHI, Simei LIU, Jingyong LIU. Study on photocatalytic degradation of naproxen in water by improved TiO₂ [J]. Industrial Water Treatment, 2023, 43(4): 85-91.
[14]	Baoning CHEN, Chunhua DING, Yanxiong FANG, Quanbing LIU. Preparation and photocatalytic properties of Ag₂O/WO₃-SiO₂ aerogels [J]. Industrial Water Treatment, 2023, 43(2): 136-141.
[15]	Han SUN. Modification of C₃N₄ based on photogenerated electron modulation and its visible-light photodegradation performance [J]. Industrial Water Treatment, 2023, 43(2): 98-103.

Please choose a citation manager

Content to export