工业水处理 ›› 2005, Vol. 25 ›› Issue (9): 40-42. doi: 10.11894/1005-829x.2005.25(09).40

• 试验研究 • 上一篇    下一篇

壳聚糖羟丙基三甲基季铵盐的合成及絮凝净水性能

姜翠玉, 宋林花, 朱成君   

  1. 石油大学化学化工学院, 山东东营 257061
  • 收稿日期:2005-06-12 修回日期:2005-06-12 出版日期:2005-09-20 发布日期:2010-10-01
  • 作者简介:姜翠玉(1965- ),1989 年毕业于曲阜师范大学化学系获硕士学位,石油大学化学化工学院副教授。主要从事水处理剂和石油精细化学品的研究,电话:0546- 8392817,E-mail:jiangcy@hdpu.edu.cn

Synthes is of hydroxypropyl-trimethylammonium of chitosan and the study of flocculation functions

Jiang Cuiyu, Song Linhua, Zhu Chengjun   

  1. College of Chemistry & Chemical Engineering, University of Petroleum, Dongying 257061, China
  • Received:2005-06-12 Revised:2005-06-12 Online:2005-09-20 Published:2010-10-01

摘要:

在有机溶剂中合成了壳聚糖羟丙基三甲基季铵盐(HTAC),探索了最佳反应条件,得到了转化率较高、水溶性好的产品。该产品6 mg/L与60 mg/L的聚合铝复配,使孤一、孤五污水站污水浊度分别由90.4 mg/L、64.0 mg/L降到3.6 mg/L、4.2 mg/L。加入该产品40 mg/L和聚合铝50 mg/L,使孤二联污水油质量浓度由2706.8mg/L降到18.5 mg/L,浊度由960 mg/L降到4.4 mg/L,絮凝净水效果十分显著。

关键词: 壳聚糖, 2,3-环氧丙基三甲基氯化铵, 壳聚糖季铵盐, 絮凝剂, 油田污水处理

Abstract:

The most preferable synthesis process for hydroxypropyl-trimethylammonium of chitosan (HTAC) in heterogeneous system is discussed.The obtained quaternary ammonium salt of chitosan is soluble in water and characterized by IR.With 6 mg/L HTAC and 60 mg/L polyaluminium chloride(PAC) added together,the turbidity of wastewater of the 1st Gudao Water Treatment Plant decreases from 90.4 mg/L to 3.6 mg/L and that of the 5th Gudao Water Treatment Plant 64.0 mg/L to 4.2 mg/L.With 40 mg/L HTAC and 50 mg/L PAC added togetheer,the oil content of wastewater of the 2nd Gudao Plant decreases from 2706.8 mg/L to 18.5 mg/L and the turbidity of the wastewater from 960 mg/L to 4.4 mg/L.

Key words: Chitosan, 2, 3- epoxypropyltrimethylammonium chloride, quaternary ammonium salt of chitosan, flocculant, oilfield produced wastewater treatment

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