工业水处理 ›› 2009, Vol. 29 ›› Issue (6): 48-50. doi: 10.11894/1005-829x.2009.29(6).48

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N- MAM/AA/MA 共聚物的合成及水处理性能

冯晨辉, 周桃玉, 李淑静, 魏无际   

  1. 南京工业大学,江苏南京210009
  • 收稿日期:2008-11-19 出版日期:2009-06-20 发布日期:2010-10-01
  • 通讯作者: 周桃玉,Zhouttyy@sina.com E-mail:Zhouttyy@sina.com
  • 作者简介:冯晨辉(1982- ),2009 年毕业于南京工业大学,硕士。电话:13914705175,E-mail:fengchenhui2003@163.com

Synthesis and water treatment capacity of the N-MAM/AA/MA copolymer

Feng Chenhui, Zhou Taoyu, Li Shujing, Wei Wuji   

  1. Nanjing University of Technology, Nanjing 210009, China
  • Received:2008-11-19 Online:2009-06-20 Published:2010-10-01

摘要:

实验室水相合成了“N-羟甲基丙烯酰胺/丙烯酸/丙烯酸甲酯”三元共聚物,采用红外光谱(FT-IR)、静态 阻垢(SAS)、旋转挂片腐蚀试验(RCC)、电化学极化曲线(EPC)等方法进行了分析测试。结果表明:实验合成样品作为 水处理剂单剂投加,其阻碳酸钙垢的SAS 结果优于对照样T-225,同时EPC 显示其兼具一定的缓蚀性能,主要为阴 极型腐蚀抑制机理;样品与锌盐复配使用,RCC 结果显示其碳钢腐蚀速率为0.104 mm/a,稳锌率可达20.5%。

关键词: N-羟甲基丙烯酰胺, 丙烯酸, 三元共聚物合成, 阻垢, 缓蚀

Abstract:

The ternary copolymer, N-hydroxymethyl acrylamide (N-MAM)/ acrylic acid (AA)/ methyl acrylate (MA) has been synthesized in water phase in laboratory. It is analyzed by means of FT-infrared (FT-IR), static antiscale (SAS), and rotary coupon corrosion (RCC) and electrochemical polarization curve (EPC) tests. The results show that the SAS of calcium carbonate result of the synthesized sample as adding water treatment agent monomer is better than the contrast sample, T-225. At the same time, it shows that it also has corrosion inhibition capacity to a certain extent; mainly is cathodic corrosion mechanism. The RCC result of using zincate compound shows that the corrosion rate of carbon steel is 0.104 mm/a, and Zn2+ stability kept in solution is up to 20.5%.

Key words: N-hydroxymethyl acrylamide, acrylic acid, ternary copolymer synthesis, scale inhibition, corrosion inhibition

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