工业水处理 ›› 2011, Vol. 31 ›› Issue (1): 61-63. doi: 10.11894/1005-829x.2011.31(1).61

• 试验研究 • 上一篇    下一篇

新型粉煤灰絮凝剂的制备及其应用研究

兰善红1, 杨丹1,2, 范洪波1, 武秀文1   

  1. 1. 东莞理工学院化学与环境工程学院, 广东东莞 523808;
    2. 华南理工大学环境科学与工程学院, 广东广州 510006
  • 收稿日期:2010-12-08 出版日期:2011-01-20 发布日期:2011-02-24
  • 作者简介:兰善红(1972-), 2002年毕业于华南理工大学, 博士, 副教授.Tel:0769-22861661.
  • 基金资助:

    东莞市科技计划项目(2008108101027);
    广东省重大科技专项(2009A080303004)

Preparation of new fly ash flocculant PSPAFC and its application to the simulated wastewater

Lan Shanhong1, Yang Dan1,2, Fan Hongbo1, Wu Xiuwen1   

  1. 1. College of Chemical and Environmental Engineering,Dongguan University of Technology, Dongguan 523808, China;
    2. College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510006, China
  • Received:2010-12-08 Online:2011-01-20 Published:2011-02-24

摘要:

以粉煤灰为主要原料制备复合无机高分子絮凝剂——聚硅磷氯化铝铁(PSPAFC),通过正交实验考察了原料的最佳配比,并对活化过程中的pH范围进行研究。结果表明,制备聚硅磷氯化铝铁的最佳原料配比为n(SiO2)∶n(Al+Fe)为2∶1,n(Al)∶n(Fe)为7∶3,n(P)∶n(Al+Fe)为3∶20,活化硅酸的最佳pH为2.5~3.5。将制备的PSPAFC用于模拟废水的处理,并与聚合氯化铝PAC、聚合氯化铝铁PAFC进行比较,结果表明,PSPAFC具有更好的絮凝效果。

关键词: 粉煤灰, 聚硅磷氯化铝铁, 无机高分子絮凝剂

Abstract:

Inorganic polymer flocculant poly-siliceous phosphoric aluminum ferric chloride(PSPAFC)has been prepared by using fly ash, sodium silicate and sodium phosphate as raw materials.According to the 3-factor orthogonal test, the conditions of preparing PSPAFC are optimized: n(SiO2):n(Al+Fe) is 2:1, n(Al):n(Fe) is 7:3, n(P):n(Al+Fe) is 3:20, pH of activated silicic acid is 2.5-3.5. The PSPAFC prepared by these ratios is used for treating the simulated wastewater. The results show that PSPAFC has better flocculating effect, compared with PAC and PAFC.

Key words: fly ash, poly-siliceous and phosphoric aluminum and ferric chloride(PSPAFC), inorganic polymer flocculant

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