工业水处理 ›› 2014, Vol. 34 ›› Issue (1): 37-39. doi: 10.11894/1005-829x.2014.34(1).037

• 试验研究 • 上一篇    下一篇

壳聚糖/Y 分子筛复合材料的制备及其对Cu2+吸附研究

李海明1,2   

  1. 1. 天津大学材料科学与工程学院, 天津 300072;
    2. 天津城建大学材料系, 天津 300384
  • 收稿日期:2013-11-09 出版日期:2014-01-20 发布日期:2014-02-27
  • 作者简介:李海明(1980-),博士,讲师。E-mail:leon677@126.com
  • 基金资助:

    天津市自然科学基金(10JCYBJC10500)

Preparation and copper ions adsorption properties of chitosan/Y molecular sieve composites

Li Haiming1,2   

  1. 1. School of Material Science and Engineering, Tianjin University, Tianjin 300072, China;
    2. Department of Material Science and Engineering, Tianjin Chengjian University, Tianjin 300384, China
  • Received:2013-11-09 Online:2014-01-20 Published:2014-02-27

摘要:

在微波辐射下制备了壳聚糖/Y分子筛复合材料(CTS/Y),考察了其对Cu2+吸附性能。结果表明:Y分子筛质量分数为6%时CTS/Y对Cu2+吸附量最大;随交联剂用量增大,树脂吸附量先增加后降低;溶液pH为5.2时对Cu2+吸附量最大。动力学研究表明吸附过程符合准二级动力学模型。

关键词: 壳聚糖, 微波辐射, 铜离子

Abstract:

A novel chitosan-based composite(CTS/Y) made from chitosan and Y molecular sieve has been prepared under microwave irradiation and its adsorption capacity for copper ions is investigated. The results show that the adsorption capacity of CTS/Y reaches the maximum when the content of Y molecular sieve is 6%. With the increase of cross-linker dosage, the adsorption capacity of Cu2+ on CTS/Y increases firstly and then decreases. The adsorption capacity reaches the maximum when pH of Cu2+ solution is 5.2. The kinetic research shows that the adsorption process conforms to pseudo-second-order kinetic model.

Key words: chitosan, microwave irradiation, copperions

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