工业水处理 ›› 2014, Vol. 34 ›› Issue (1): 43-46. doi: 10.11894/1005-829x.2014.34(1).043

• 试验研究 • 上一篇    下一篇

高氨氮管件生产废水处理工艺研究

李和林, 刘东方, 杨俊梅, 徐璐, 张嵩涛, 刘岩   

  1. 南开大学环境科学与工程学院, 天津 300071
  • 收稿日期:2013-11-04 出版日期:2014-01-20 发布日期:2014-02-27
  • 作者简介:李和林(1990-),硕士。E-mail:helin_l@163.com

Research on the treatment of wastewater from the production of high-ammonia/nitrogen pipe fittings

Li Helin, Liu Dongfang, Yang Junmei, Xu Lu, Zhang Songtao, Liu Yan   

  1. College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China
  • Received:2013-11-04 Online:2014-01-20 Published:2014-02-27

摘要:

管件生产废水属于高酸性废水,废水含有高浓度的氨氮以及Fe2+、Zn2+等金属离子,缺少有机物,水质呈现 “低碳高氮”特征。通过水质分析,选用“物化+生化”的组合处理工艺处理该废水。利用二级中和、混凝沉淀作为物化预处理工艺,并采用“A/O/A/O”型SBR反应器进行生物脱氮。针对组合处理工艺的试验研究表明:该工艺对TFe、Zn2+的去除率可达99%以上,出水TN<10 mg/L。处理水水质优于《污水综合排放标准》(GB 8978—1996)的一级标准,可全部作为厂区回用水。

关键词: 酸性废水, 除铁, 除锌, 生物脱氮

Abstract:

The wastewater from the production of pipe fittings is highly acidic. The wastewater contains highly concentrated ammonia/nitrogen, as well as metallic ions, such as Fe2+, Zn2+, etc. and is lack of organic matter. Its water quality is characterized by "low carbon & high nitrogen". By analyzing the wastewater quality, the combined physico-chemical and bio-chemical process has been selected. The two-stage neutralization-coagulation precipitation process is used for the physico-chemical pretreatment, and A/O/A/O-type SBR is used for biological denitrification. The results indicate that by this process the removing rates of TFe and Zn2+ could be above 99%, 10 mg/L. The treated water quality is superior to the first class Integrated Wastewater Discharge Standard(GB 8978—1996), and the effluent can fully be reused in the factory.

Key words: acidic wastewater, removal of iron, removal of zinc, biological denitrification

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