工业水处理 ›› 2015, Vol. 35 ›› Issue (11): 18-22. doi: 10.11894/1005-829x.2015.35(11).018

• 试验研究 • 上一篇    下一篇

微滤再生处理钛白粉生产三洗废水工艺研究

徐竟成, 郭浩博, 杨斯棋, 李光明, 黄翔峰   

  1. 同济大学环境科学与工程学院, 长江水环境教育部重点实验室, 上海 200092
  • 收稿日期:2015-09-21 出版日期:2015-11-20 发布日期:2015-11-26
  • 作者简介:徐竟成(1961-),教授,博士生导师.电话:021-65982010,E-mail:xujick@tongji.edu.cn.
  • 基金资助:

    国家科技支撑计划项目(2009ZX07317-005)

Research on the microfiltration regenerating treatment of the third-washing wastewater in titanium dioxide production

Xu Jingcheng, Guo Haobo, Yang Siqi, Li Guangming, Huang Xiangfeng   

  1. Key Laboratory of Yangtze River Water Environment of Education Ministry, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China
  • Received:2015-09-21 Online:2015-11-20 Published:2015-11-26
  • Contact: 10.11894/1005-829x.2015.35(11).018

摘要:

采用微滤错流工艺再生处理钛白粉生产过程中产生的三洗废水,降低二氧化钛颗粒物浓度,使其达到一洗、二洗工艺用水要求.试验结果表明:出水TiO2质量浓度低于2 mg/L,满足回用要求;膜面流速、跨膜压差、料液浓度三因素对稳态通量影响显著,影响过程受驱动力、滤饼压实程度及流体冲刷程度多重影响;采用超声清洗后的膜纯水通量高,且清洗效果随清洗次数的增加衰减较小.

关键词: 钛白粉生产, 三洗废水, 微滤, 稳态膜通量, 膜清洗

Abstract:

The microfiltration crossflow process has been used for the regenerating treatment of the third-washing wastewater in titanium dioxide production,so as to reduce the particle concentration of titanium dioxide,making it to meet the process water requirements of the first-washing and second-washing. The experimental results show that the concentration of TiO2 in the effluent is below 2 mg/L,which satisfies reuse requirements. The three factors: membrane surface flow velocity,transmembrane pressure and feed concentration have significant influences on steadystate flux,and the influencing process are affected by driving forces,compaction degree of filter cake and the degree of fluid scouring. The membrane pure water flux increases after the wastewater has been cleaned with ultrasonic. With the increase of washing times,the washing effect does not decrease much.

Key words: titanium dioxide production, third-washing wastewater, microfiltration, steady membrane flux, membrane cleaning

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