工业水处理 ›› 2020, Vol. 40 ›› Issue (11): 32-35. doi: 10.11894/iwt.2019-1037

• 试验研究 • 上一篇    下一篇

电絮凝-膜分离反应器去除水中腐殖酸

李海洋1,2(),程国玲1,*()   

  1. 1. 东北林业大学林学院, 黑龙江哈尔滨 150040
    2. 中国科学院饮用水科学与技术重点实验室, 中国科学院生态环境研究中心, 北京 100085
  • 收稿日期:2020-07-01 出版日期:2020-11-20 发布日期:2020-11-24
  • 通讯作者: 程国玲 E-mail:751091011@qq.com;chengguoling986@126.com
  • 作者简介:李海洋(1994-),硕士。电话:13269970383, E-mail:751091011@qq.com
  • 基金资助:
    国家自然科学基金项目(51678556)

Removal of humic acid from water by electrocoagulation-membrane reactor

Haiyang Li1,2(),Guoling Cheng1,*()   

  1. 1. School of Forestry, Northeast Forestry University, Harbin 150040, China
    2. Key Laboratory of Drinking Water Science and Technology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
  • Received:2020-07-01 Online:2020-11-20 Published:2020-11-24
  • Contact: Guoling Cheng E-mail:751091011@qq.com;chengguoling986@126.com

摘要:

考察了电絮凝-膜分离反应器(ECMR)去除水中腐殖酸(HA)的效果。研究了不同电化学参数对腐殖酸去除率的影响、ECMR平板陶瓷膜和EC-MF平板陶瓷膜抑制膜污染的作用机制,并进行了比较。结果表明,在电流密度为10 A/m2、初始电导率1 000 μS/cm、初始pH=6、电解时间30 min、初始HA质量浓度5 mg/L时,ECMR工艺对水中HA的去除率为88.3%,ECMR平板陶瓷膜膜通量高于EC-MF平板陶瓷膜20%,HA去除率高8%,所用时间较短。

关键词: 微滤, 电絮凝, 膜反应器, 平板陶瓷膜

Abstract:

Humic acid(HA) removal by electrocoagulation-membrane reactor(ECMR) was investigated. The effects of different electrochemical parameters on the removal of HA were studied. Besides, the mechanism of antifouling by ECMR flat ceramic membrane and EC-MF flat ceramic membrane were compared. The results showed that under the current density 10 A/m2, initial conductivity 1 000 μS/cm, initial pH=6, electrolysis time of 30 min, and initial mass concentration of HA 5 mg/L, the HA removal reached 88.3%. The flux of ECMR flat ceramic membrane showed an enhancement by 20% than that of EC-MF flat ceramic membrane, the removal rate of humic acid was 8% higher, and the time used was shorter.

Key words: microfiltration, electrocoagulation, membrane reactor, flat ceramic membrane

中图分类号: