巯基功能化镁层状硅酸盐复合材料的构筑及其催化还原性能研究

doi:10.19965/j.cnki.iwt.2022-0796

工业水处理 ›› 2023, Vol. 43 ›› Issue (7): 70-77. doi: 10.19965/j.cnki.iwt.2022-0796

巯基功能化镁层状硅酸盐复合材料的构筑及其催化还原性能研究

何贝贝¹(), 袁玉环², 吕瑞¹^,²()

^1. 绵阳师范学院化学与化学工程学院, 四川绵阳 621000
^2. 西南科技大学环境与资源学院, 四川绵阳 621010

收稿日期:2023-04-29 出版日期:2023-07-20 发布日期:2023-07-17
作者简介:
何贝贝（1996— ），硕士。E-mail：735367187@qq.com
吕瑞，硕士，副教授。E-mail：renny8160@163.com。
基金资助:
国家自然科学基金项目(42061134018)

Construction of thiol-functionalized magnesium phyllosilicate contained nanocomposite and investigation of its catalytic reduction performance

Beibei HE¹(), Yuhuan YUAN², Rui LÜ¹^,²()

^1. School of Chemistry and Chemical Engineering, Mianyang Teachers’ College, Mianyang 621000, China
^2. School of Environment and Resource, Southwest University of Science and Technology, Mianyang 621010, China

Received:2023-04-29 Online:2023-07-20 Published:2023-07-17

摘要/Abstract

关键词: 巯基功能化镁层状硅酸盐, 4-硝基苯酚, 催化还原

Key words: thiol-functionalized magnesium phyllosilicate, 4-nitrophenol, catalytic reduction

中图分类号:

X703.1

何贝贝, 袁玉环, 吕瑞. 巯基功能化镁层状硅酸盐复合材料的构筑及其催化还原性能研究[J]. 工业水处理, 2023, 43(7): 70-77.

Beibei HE, Yuhuan YUAN, Rui LÜ. Construction of thiol-functionalized magnesium phyllosilicate contained nanocomposite and investigation of its catalytic reduction performance[J]. Industrial Water Treatment, 2023, 43(7): 70-77.

https://www.iwt.cn/CN/Y2023/V43/I7/70

图/表 6

图1 Fe₃O₄@MgSH/Ag及其相关组分的表征

Fig.1 Characterization of Fe₃O₄@MgSH/Ag and its related components

图2 催化还原体系的UV-vis光谱图

Fig.2 UV-vis spectra of the catalytic reduction systems

图3 Fe₃O₄@MgSH/Ag催化还原4-NP的动力学（a）及其准一级动力学模型拟合曲线（b）

Fig. 3 Kinetics（a） and quasi first-order kinetic model fitting curve（b）of catalytic reduction of 4-NP by Fe₃O₄@MgSH/Ag

表1 不同催化剂催化还原4-NP的准一级动力学表观速率常数

Table 1 Quasi first-order kinetic apparent rate constants of catalytic reduction of 4-NP with different catalysts

催化剂	k _app	参考文献
C-Pt NPs	0.03 min^-1	〔16〕
Au	0.126 min^-1	〔17〕
Ag-NP/C	0.101 min^-1	〔18〕
Pd/CS-2	0.138 min^-1	〔19〕
Pd	1.02×10^-3 s^-1	〔20〕
Pd NPs@black tea	5.9×10^-4 s^-1	〔21〕
Pt	1.98×10^-3 s^-1	〔22〕
Au/RGO	0.9×10^-3 s^-1	〔23〕
Fe₃O₄@MgSH/Ag	0.160 8 min^-1	本研究

图4 各反应条件对Fe₃O₄@MgSH/Ag催化还原4-NP的影响

Fig.4 The effect of each parameter in the catalytic reduction of 4-NP by Fe₃O₄@MgSH/Ag

图5 Fe₃O₄@MgSH/Ag的循环使用性及稳定性

Fig.5 Recyclability and stability of Fe₃O₄@MgSH/Ag

参考文献 23

1	ESHAQ G， WANG Shaobin， SUN Hongqi，et al. Superior performance of FeVO₄@CeO₂ uniform core-shell nanostructures in heterogeneous Fenton-sonophotocatalytic degradation of 4-nitrophenol［J］. Journal of Hazardous Materials，2020，382：121059. doi:10.1016/j.jhazmat.2019.121059
2	LIU Jiangyong， LI Jinxing， MENG Ru，et al. Silver nanoparticles-decorated-Co₃O₄ porous sheets as efficient catalysts for the liquid-phase hydrogenation reduction of p-nitrophenol［J］. Journal of Colloid and Interface Science，2019，551：261-269. doi:10.1016/j.jcis.2019.05.018
3	AWAD A M， SHAIKH S M R， JALAB R，et al. Adsorption of organic pollutants by natural and modified clays：A comprehensive review［J］. Separation and Purification Technology，2019，228：115719. doi:10.1016/j.seppur.2019.115719
4	ZHANG Chengyu， LUAN Jingde， YU Xiaokun，et al. Characterization and adsorption performance of graphene oxide-montmorillonite nanocomposite for the simultaneous removal of Pb²⁺ and p-nitrophenol［J］. Journal of Hazardous Materials，2019，378：120739. doi:10.1016/j.jhazmat.2019.06.016
5	ZHOU Wei， LI Ting， WANG Jianqiang，et al. Composites of small Ag clusters confined in the channels of well-ordered mesoporous anatase TiO₂ and their excellent solar-light-driven photocatalytic performance［J］. Nano Research，2014，7（5）：731-742. doi:10.1007/s12274-014-0434-y
6	ADITYA T，PAL A，PAL T. Nitroarene reduction：A trusted model reaction to test nanoparticle catalysts［J］. Chemical Communications（Cambridge，England），2015，51（46）：9410-9431. doi:10.1039/c5cc01131k
7	RAZO-FLORES E， DONLON B， LETTINGA G，et al. Biotransformation and biodegradation of N-substituted aromatics in methanogenic granular sludge［J］. FEMS Microbiology Reviews，1997，20（3/4）：525-538. doi:10.1111/j.1574-6976.1997.tb00335.x
8	NARAYANAN K B， SAKTHIVEL N. Synthesis and characterization of nano-gold composite using Cylindrocladium floridanum and its heterogeneous catalysis in the degradation of 4-nitrophenol［J］. Journal of Hazardous Materials，2011，189（1/2）：519-525. doi:10.1016/j.jhazmat.2011.02.069
9	EJIMA H， RICHARDSON J J， LIANG Kang，et al. One-step assembly of coordination complexes for versatile film and particle engineering［J］. Science，2013，341（6142）：154-157. doi:10.1126/science.1237265
10	JU Yi， CUI Jiwei， MÜLLNER M，et al. Engineering low-fouling and pH-degradable capsules through the assembly of metal-phenolic networks［J］. Biomacromolecules，2015，16（3）：807-814. doi:10.1021/bm5017139
11	KEMPASIDDAIAH M， KANDATHIL V， DATEER R B，et al. Efficient and recyclable palladium enriched magnetic nanocatalyst for reduction of toxic environmental pollutants［J］. Journal of Environmental Sciences，2021，101：189-204. doi:10.1016/j.jes.2020.08.015
12	VEISI H， MORADI S B， SALJOOQI A，et al. Silver nanoparticle-decorated on tannic acid-modified magnetite nanoparticles（Fe₃O₄@TA/Ag） for highly active catalytic reduction of 4-nitrophenol，Rhodamine B and Methylene blue［J］. Materials Science & Engineering C，Materials for Biological Applications，2019，100：445-452. doi:10.1016/j.msec.2019.03.036
13	BURKETT S L， PRESS A， Synthesis MANN S.，characterization，and reactivity of layered inorganic-organic nanocomposites based on 2 ∶1 trioctahedral phyllosilicates［J］. Chemistry of Materials，1997，9（5）：1071-1073. doi:10.1021/cm9700615
14	LAGADIC I L， MITCHELL M K， PAYNE B D. Highly effective adsorption of heavy metal ions by a thiol-functionalized magnesium phyllosilicate clay［J］. Environmental Science & Technology，2001，35（5）：984-990. doi:10.1021/es001526m
15	FONSECA M G DA， AIROLDI C. New layered inorganic-organic nanocomposites containing n-propylmercapto copper phyllosilicates［J］. Journal of Materials Chemistry，2000，10（6）：1457-1463. doi:10.1039/b001556n
16	YOU J G， SHANMUGAM C， LIU Yaowen，et al. Boosting catalytic activity of metal nanoparticles for 4-nitrophenol reduction：Modification of metal naoparticles with poly（diallyldimethylammonium chloride）［J］. Journal of Hazardous Materials，2017，324：420-427. doi:10.1016/j.jhazmat.2016.11.007
17	RASHID H， BHATTACHARJEE R R， KOTAL A，et al. Synthesis of spongy gold nanocrystals with pronounced catalytic activities［J］. Langmuir：the ACS Journal of Surfaces and Colloids，2006，22（17）：7141-7143. doi:10.1021/la060939j
18	TANG Shaochun， VONGEHR S， MENG Xiangkang. Carbon spheres with controllable silver nanoparticle doping［J］. The Journal of Physical Chemistry C，2010，114（2）：977-982. doi:10.1021/jp9102492
19	TANG Shaochun， VONGEHR S， HE Guorong，et al. Highly catalytic spherical carbon nanocomposites allowing tunable activity via controllable Au-Pd doping［J］. Journal of Colloid and Interface Science，2012，375（1）：125-133. doi:10.1016/j.jcis.2012.02.045
20	HOSEINI S J， BAHRAMI M， SADRI N，et al. Multi-metal nanomaterials obtained from oil/water interface as effective catalysts in reduction of 4-nitrophenol［J］. Journal of Colloid and Interface Science，2018，513：602-616. doi:10.1016/j.jcis.2017.11.068
21	LEBASCHI S， HEKMATI M， VEISI H. Green synthesis of palladium nanoparticles mediated by black tea leaves（Camellia sinensis） extract：Catalytic activity in the reduction of 4-nitrophenol and Suzuki-Miyaura coupling reaction under ligand-free conditions［J］. Journal of Colloid and Interface Science，2017，485：223-231. doi:10.1016/j.jcis.2016.09.027
22	HOSEINI S J， RASHIDI M， BAHRAMI M. Platinum nanostructures at the liquid-liquid interface：Catalytic reduction of p-nitrophenol to p-aminophenol［J］. Journal of Materials Chemistry，2011，21（40）：16170-16176. doi:10.1039/c1jm11814e
23	LIU Qi， XU Yanru， WANG Aijun，et al. One-step melamine-assisted synthesis of graphene-supported AuPt@Au nanocrystals for enhanced catalytic reduction of p-nitrophenol［J］. RSC Advances，2015，5（116）：96028-96033. doi:10.1039/c5ra21645a

[1]	赵慧, 王富东, 钱光磊, 雷太平, 任春燕, 谢陈鑫. 电催化还原废水中硝酸盐制氨的研究进展[J]. 工业水处理, 2024, 44(1): 60-72.
[2]	李增强. 秸秆纤维素基水凝胶负载Fe₃O₄/Cu催化剂还原硝基苯甲酸[J]. 工业水处理, 2023, 43(5): 141-148.
[3]	肖羽堂,陈苑媚,王冠平,石伟,孙临泉,陈艳芳,缪爱纯. 难降解废水电催化处理研究进展[J]. 工业水处理, 2020, 40(6): 1-6.
[4]	陈嘉瑾, 梁娟, 高智睿, 龙晴. 活性炭掺杂BiVO₄的制备及光催化还原Cr(Ⅳ)的研究[J]. 工业水处理, 2019, 39(9): 75-79.
[5]	裴易凡, 蒋兵, 李怡招, 曹亚丽, 贾殿赠. 纳米镍铁双金属的制备及其处理硝基苯酚废水研究[J]. 工业水处理, 2018, 38(6): 39-41,45.
[6]	周洧兰, 王中琪, 叶正中, 张志军, 王军. Fe-Cu催化还原法预处理附子中药废水研究[J]. 工业水处理, 2013, 33(5): 65-68.
[7]	杨永凡, 费学宁. TiO₂光催化去除废水中重金属离子的研究进展[J]. 工业水处理, 2012, 32(7): 9-14.
[8]	吴德礼, 马鲁铭. 催化还原技术处理水溶液中氯代有机物的实验研究[J]. 工业水处理, 2005, 25(1): 21-24.

选择文件类型/文献管理软件名称

选择包含的内容

巯基功能化镁层状硅酸盐复合材料的构筑及其催化还原性能研究

Construction of thiol-functionalized magnesium phyllosilicate contained nanocomposite and investigation of its catalytic reduction performance

RichHTML

PDF

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 6

参考文献 23

相关文章 8

编辑推荐

Metrics

本文评价

模态框（Modal）标题

选择文件类型/文献管理软件名称

选择包含的内容

巯基功能化镁层状硅酸盐复合材料的构筑及其催化还原性能研究

Construction of thiol-functionalized magnesium phyllosilicate contained nanocomposite and investigation of its catalytic reduction performance

RichHTML

PDF

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 6

参考文献 23

相关文章 8

编辑推荐

Metrics

本文评价