工业水处理 ›› 2007, Vol. 27 ›› Issue (4): 51-54. doi: 10.11894/1005-829x.2007.27(4).51

• 试验研究 • 上一篇    下一篇

生物质煤气废水氨氮脱除的研究

张文华1, 袁玮1, 周江菊1, 吴创之2, 杨秀山3   

  1. 1. 凯里学院生物科学技术系, 贵州 凯里 556000;
    2. 中科院广州能源研究所, 广东 广州 510070;
    3. 首都师范大学生命科学学院, 北京 100037
  • 收稿日期:2006-12-04 修回日期:2006-12-04 出版日期:2007-04-20 发布日期:2010-10-01
  • 作者简介:张文华(1965- ) , 1987 年毕业于西南民族学院化学系, 1996 年获西南农业大学农学硕士学位, 2000 年—2001 年首都师范大学生物系访问学者, 2002 年—2003年中科院广州能源研究所高级访问学者, 教授。E-mail:zhwh0808@sina.com。
  • 基金资助:

    国家“十五”科技攻关项目(2002BA40302);北京市自然科学基金项目(502003)

Study on the removal of ammonia-nitrogen from biomass gasification wastewater

Zhang Wenhua1, Yuan Wei1, Zhou Jiangju1, Wu Chuangzhi2, Yang Xiushan3   

  1. 1. Department of Biological Science and Technology, Kaili College, Kaili 556000, China;
    2. Institute of Energy Resources, China Academy Science, Guangzhuo 510070, China;
    3 College of Life Science, Capital Normal University, Beijing 100037, China
  • Received:2006-12-04 Revised:2006-12-04 Online:2007-04-20 Published:2010-10-01

摘要:

生物质煤气废水是一种新出现的高浓度氨氮有机废水。作者采用化学沉淀法去除该废水中的氨氮,研究了不同沉淀剂、pH、温度和搅拌时间对氨氮去除效果的影响。结果表明,MgCl2+Na3PO4·12H2O明显优于其他沉淀剂组合。当n(Mg2+)∶n(NH4+)∶n(PO43-)=1∶1∶1、pH10.0、温度30℃、搅拌时间30min时,废水中的氨氮质量浓度从处理前的222mg/L降到17mg/L,去除率为92.3%。

关键词: 化学沉淀, 生物质气化, 洗焦废水, 氨氮去除

Abstract:

The biomass gasification wastewater is a newtype of organic wastewater with high concentration ammonia-nitrogen.In order to remove ammonia-nitrogen from this wastewater, chemical precipitation process has been carried out. The effects of the different types and dosage of precipitants, pH, temperature and stirring time on the removal of ammonia-nitrogen are investigated. The results show that MgCl2+Na3PO4·12H2O is significantly better than other combination. When n(Mg2+)∶n(NH4+)∶n(PO43-)-1∶1∶1, pH is 10.0, temperature is 30 ℃ and stirring time is 30 min, after the wastewater,whose ammonia-nitrogen contents was 222 mg/L, was treated, the ammonia-nitrogen content goes down to 17 mg/L, and the removal rate of ammonia-nitrogen is 92.3%.

Key words: chemical precipitation, biomass gasification, coke-washing wastewater, removal of ammonia-nitrogen

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