工业水处理 ›› 2011, Vol. 31 ›› Issue (6): 39-42. doi: 10.11894/1005-829x.2011.31(6).39

• 试验研究 • 上一篇    下一篇

油田注入水硫酸钡动态结垢机理研究

古昕, 刘宏芳, 齐公台, 侯艳红   

  1. 华中科技大学化学与化工学院湖北省材料化学与服役失效重点实验室,湖北 武汉 430074
  • 收稿日期:2011-03-31 出版日期:2011-06-20 发布日期:2011-06-14
  • 作者简介:古昕(1986- ), 2008 级华中科技大学在读研究生。电话:13995593970, E-mail:xinwei_0206@sina.com。联系人:刘宏芳, 教授, E-mail:liuhf2003@yahoo.com.cn。

Dynamic scaling mechanisms of BaSO4 from oilfield injected water

Gu Xin, Liu Hongfang, Qi Gongtai, Hou Yanhong   

  1. Key Laboratory of Hubei Material Chemistry and Service Invalidation,College of Chemistry and Chemical Engineering,Huazhong University of Science and Technology,Wuhan 430074,China
  • Received:2011-03-31 Online:2011-06-20 Published:2011-06-14

摘要:

采用在线显微成像及统计分析技术手段,设计模拟油田注水系统的动态条件下金属材料表面硫酸钡的结垢规律。并借助AFM及SEM技术分析结垢状况及程度随时间的变化规律。结果表明,高温高流速下硫酸钡结垢程度最大,管壁粗糙度越大,结垢越严重。对于BaSO4垢,在实验速度为1.2 m/s时处于一种过渡状态,此时晶核生长和流体的冲刷破坏达到动态平衡。在80℃,1.97 m/s流速下最容易形成致密的垢层,形成稳定垢层需要的时间为900 s。

关键词: 油田注水, 硫酸钡, 结垢机理, 动态监测

Abstract:

By means of the on-line microscopic imaging technique and statistical analysis,the scaling regularity of BaSO4 on metallic material surface under dynamic environment in the stimulated oilfield water injecting system has been designed. Furthermore,scanning electron microscopy (SEM) and atomic force microscopy (AFM) are used for analyzing the variations of the scaling status and extent with time. The results demonstrate that the scale is the most serious at high temperatures and flow velocities,and the coarser of the tube wall,the more serious of the tendency of the scale formation. Moreover,in the range of the experimental flow rate,1.2 m/s is in the transition state,and the growth of the crystal and the erosion of the fluid come to a dynamic equilibrium. The compact scale layer is prone to form at 80 ℃ and 1.97 m/s,and the time needed to form a stable scale layer is about 900 s.

Key words: oilfield injected water, BaSO4, scaling mechanisms, dynamic monitoring

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