工业水处理 ›› 2020, Vol. 40 ›› Issue (1): 48-52. doi: 10.11894/iwt.2018-1143

• 试验研究 • 上一篇    下一篇

蒙脱石负载BiOI/BiOBr的合成及光催化降解罗丹明B

刘超(),檀林,范鹏凯,王吉中   

  1. 河北地质大学宝石与材料工艺学院, 河北石家庄 050031
  • 收稿日期:2019-12-11 出版日期:2020-01-20 发布日期:2020-01-16
  • 作者简介:刘超(1978—),博士,副教授。电话:13931157532, E-mail:yikeschao@126.com
  • 基金资助:
    河北省自然科学基金资助项目(B2016403011);河北省高等学校科学技术研究重点项目(ZD2017012)

Synthesis of montmorillonite-supported BiOI/BiOBr and its photocatalytic degradation of RhB

Chao Liu(),Lin Tan,Pengkai Fan,Jizhong Wang   

  1. College of Gemmology and Material Technics, Hebei GEO University, Shijiazhuang 050031, China
  • Received:2019-12-11 Online:2020-01-20 Published:2020-01-16
  • Supported by:
    河北省自然科学基金资助项目(B2016403011);河北省高等学校科学技术研究重点项目(ZD2017012)

摘要:

以硝酸铋、碘化钾和十六烷基三甲基溴化铵(CTAB)为原料,钙基蒙脱石为载体采用水热法合成了具有可见光响应的蒙脱石负载型BiOI/BiOBr异质结光催化剂。采用SEM、XRD、FT-IR、UV-Vis DRS等表征方法对其组成、晶型、形貌和光学吸收性能进行了研究。以有机染料罗丹明B(RhB)为目标降解物,考察了合成的负载型异质结催化剂的光催化活性,并初步探讨了其光催化性能提高的机理。

关键词: BiOI/BiOBr, 蒙脱石, 光催化降解, 罗丹明B

Abstract:

A heterojunction photocatalyst, montmorillonite-supported BiOI/BiOBr with visible light response, was synthesized by hydrothermal method using bismuth nitrate, potassium iodide and cetyltrimethylammonium bromide (CTAB) as raw materials and calcium-based montmorillonite as a carrier. The composition, crystalline, morphology and optical absorption properties of the samples were studied by means of SEM, XRD, FT-IR and UV-Vis DRS, respectively. The photocatalytic activity of the synthesized supported heterojunction catalyst was investigated using Rhodamine B(RhB) as the degradation object. The mechanism of the improved photocatalytic activity of the photocatalysts was also preliminarily discussed.

Key words: BiOI/BiOBr, montmorillonite, photocatalytic degradation, Rhodamine B

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