金属催化剂在宽泛pH进行Fenton反应的进展

doi:10.11894/iwt.2020-0230

摘要/Abstract

摘要：

Fenton反应广泛应用于有机废水处理，但传统的Fenton反应只能在pH较低的酸性环境下进行。为克服经典Fenton反应低pH的局限性，进行了多种方式改良。其中，在Fenton反应中采用金属催化剂能有效拓宽反应pH范围，减少铁渣生成，加快H₂O₂分解。综述了金属催化剂在宽泛pH范围进行Fenton反应降解有机污染物的基本原理和最新研究进展。

关键词: Fenton反应, 金属催化剂, pH

Abstract:

Fenton reaction is widely used in organic wastewater treatment. The traditional Fenton reaction can only be carried out in a acidic environment with lower pH. Variety of methods have been improved to overcome the limitations of the low pH in the classic Fenton reaction. Among of them, the use of metal catalysts in the Fenton reaction can effectively broaden the reaction pH range, reduce the formation of iron slag, and accelerate the decomposition of H₂O₂. This article reviews the basic principles and latest research progress of metal catalysts for Fenton reaction degradation of organic pollutants in a wide pH range.

Key words: Fenton reaction, metal catalyst, pH

中图分类号:

X703

李孟宣,盛光遥,何岸飞. 金属催化剂在宽泛pH进行Fenton反应的进展[J]. 工业水处理, 2021, 41(2): 20-25.

Mengxuan Li,Guangyao Sheng,Anfei He. Progress of metal catalysts for Fenton reaction at a wide range of pH[J]. Industrial Water Treatment, 2021, 41(2): 20-25.

https://www.iwt.cn/CN/Y2021/V41/I2/20

图/表 2

参考文献 51

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催化剂	催化剂支撑材料	降解目标物	最优结果	催化剂稳定性	适用pH范围	参考文献
α-Fe₂O₃	硅藻土	亚甲基蓝（MB）	120 min后去除率达到98%	重复使用5次，稳定性良好	在pH为2.0~8.0范围内去除效果良好	〔26〕
α-Fe₂O₃	石墨相碳氮化物（g-C3N4）	四环素（TC）	60 min后去除率为95%	重复使用5次，稳定性良好	在pH为2.01~9.09范围内去除效果良好	〔27〕
γ-Fe₂O₃	石墨烯	亚甲基蓝（MB）	100 min后去除率为99%	重复使用8次，稳定性良好	在pH为2.0~10.2范围内去除效果良好	〔28〕
Fe₃O₄	石墨烯	苯酚、2-NP、2-CP	120 min后苯酚去除率为92.43%，2-NP去除率为98.87%，2-CP去除率为97.15%	重复使用10次，稳定性良好	在pH为3.0~11.0范围内去除效果良好	〔29〕
Fe₃O₄	生物炭	乙苯	40 min后去除率为99.33%	—	在pH为3~10范围内去除效果良好	〔30〕
纳米零价铁（NZVI）	树胶黄花胶（GT）	阿西莫拉（CIP）	60 min后去除率为85%	—	在pH为3.5~9.5范围内去除效果良好	〔31〕
FeOOH	活性炭	活性艳橙（X-GN）	240 min后去除率达到98%	重复使用4次，稳定性良好	在pH为2~9范围内去除效果良好	〔32〕

催化剂	催化剂支撑材料	降解目标物	最优结果	催化剂稳定性	适用pH范围	参考文献
α-Fe₂O₃	硅藻土	亚甲基蓝（MB）	120 min后去除率达到98%	重复使用5次，稳定性良好	在pH为2.0~8.0范围内去除效果良好	〔26〕
α-Fe₂O₃	石墨相碳氮化物（g-C3N4）	四环素（TC）	60 min后去除率为95%	重复使用5次，稳定性良好	在pH为2.01~9.09范围内去除效果良好	〔27〕
γ-Fe₂O₃	石墨烯	亚甲基蓝（MB）	100 min后去除率为99%	重复使用8次，稳定性良好	在pH为2.0~10.2范围内去除效果良好	〔28〕
Fe₃O₄	石墨烯	苯酚、2-NP、2-CP	120 min后苯酚去除率为92.43%，2-NP去除率为98.87%，2-CP去除率为97.15%	重复使用10次，稳定性良好	在pH为3.0~11.0范围内去除效果良好	〔29〕
Fe₃O₄	生物炭	乙苯	40 min后去除率为99.33%	—	在pH为3~10范围内去除效果良好	〔30〕
纳米零价铁（NZVI）	树胶黄花胶（GT）	阿西莫拉（CIP）	60 min后去除率为85%	—	在pH为3.5~9.5范围内去除效果良好	〔31〕
FeOOH	活性炭	活性艳橙（X-GN）	240 min后去除率达到98%	重复使用4次，稳定性良好	在pH为2~9范围内去除效果良好	〔32〕

催化剂	降解目标物	反应条件	结果	催化剂稳定性	适用pH范围	参考文献
FeCeOx 复合材料	罗丹明B（RhB）	催化剂1.5 g/L，[H2O2]=80 mmol/L，pH=5.0，温度35 ℃	150 min后去除率达到98%	重复使用3次，去除率下降至70%；可以通过简单的热处理（500 ℃，2 h）使催化剂重新活化	在pH为3.0~9.0范围内去除效果良好	〔45〕
LFO-15Cu 复合材料	甲基橙（MO）	催化剂0.8 g/L，H2O2 0.3 g/L，pH=5.0，温度25 ℃，可见光	60 min后去除率达到92.9%	重复使用4次，去除率下降至88.5%	在pH为4.0~8.0范围内去除效果良好	〔46〕
CuFeO2 微粒	双酚A（BPA）	催化剂1 g/L，[H2O2]=20 mmol/L，pH=5.0	120 min后去除率为99.7%	重复使用6次，去除率没有明显变化	在pH为4.0~8.0范围内去除效果良好	〔44〕
CuVOx 复合材料	氟康唑（FLC）	催化剂1 g/L，[H2O2]=50 mmol/L，pH=3.0	90 min后去除率为100%	重复使用5次，去除率下降至81%	在pH为3.0~9.0范围内去除效果良好	〔47〕
Fe0.75Cu0.25 （BDC）	磺胺甲恶唑（SMX）	催化剂0.5 g/L，[H2O2]=6 mmol/L，pH=5.6，温度25 ℃	120 min后去除率为100%	重复使用3次，去除率没有明显变化	在pH为4.0~8.6范围内去除效果良好	〔48〕

催化剂	降解目标物	反应条件	结果	催化剂稳定性	适用pH范围	参考文献
FeCeOx 复合材料	罗丹明B（RhB）	催化剂1.5 g/L，[H2O2]=80 mmol/L，pH=5.0，温度35 ℃	150 min后去除率达到98%	重复使用3次，去除率下降至70%；可以通过简单的热处理（500 ℃，2 h）使催化剂重新活化	在pH为3.0~9.0范围内去除效果良好	〔45〕
LFO-15Cu 复合材料	甲基橙（MO）	催化剂0.8 g/L，H2O2 0.3 g/L，pH=5.0，温度25 ℃，可见光	60 min后去除率达到92.9%	重复使用4次，去除率下降至88.5%	在pH为4.0~8.0范围内去除效果良好	〔46〕
CuFeO2 微粒	双酚A（BPA）	催化剂1 g/L，[H2O2]=20 mmol/L，pH=5.0	120 min后去除率为99.7%	重复使用6次，去除率没有明显变化	在pH为4.0~8.0范围内去除效果良好	〔44〕
CuVOx 复合材料	氟康唑（FLC）	催化剂1 g/L，[H2O2]=50 mmol/L，pH=3.0	90 min后去除率为100%	重复使用5次，去除率下降至81%	在pH为3.0~9.0范围内去除效果良好	〔47〕
Fe0.75Cu0.25 （BDC）	磺胺甲恶唑（SMX）	催化剂0.5 g/L，[H2O2]=6 mmol/L，pH=5.6，温度25 ℃	120 min后去除率为100%	重复使用3次，去除率没有明显变化	在pH为4.0~8.6范围内去除效果良好	〔48〕

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