Fenton氧化处理难降解有机废水研究进展

doi:10.19965/j.cnki.iwt.2021-0368

摘要/Abstract

摘要：

Fenton氧化属于高级氧化技术，具有反应时间短、降解效率高、操作简单等优点，是处理难降解有机废水方法中最具应用前景的方法之一。然而，传统Fenton氧化法存在一些技术缺陷，包括反应pH范围过窄、产生含铁污泥以及H₂O₂投加量较高等。针对Fenton氧化的局限性，综述了解决这些问题的最新技术措施，包括拓展Fenton初始反应pH至中性或碱性、减少铁泥产生及铁泥循环利用、原位产生H₂O₂，并对每种措施的基本原理及处理难降解有机污染物的应用进行了综述。

关键词: Fenton氧化, 难降解有机废水, 原位产生H₂O₂, 铁泥减量, 宽pH范围

Abstract:

Fenton oxidation is an advanced oxidation technology with the advantages of short reaction time，high degradation efficiency and simple operation，so it is one of the most promising methods for the treatment of refractory organic wastewater. However，there are some technical defects in the traditional Fenton oxidation process，including the narrow pH value of the reaction，the production of iron-containing sludge and the addition of high dose H₂O₂ and so on. In view of the limitations of Fenton oxidation，the latest technical measures to solve these problems are reviewed in this paper，including expanding the initial pH of Fenton to neutral or alkaline，reducing the production and recycling of iron mud，and generating H₂O₂ in situ. The basic principle of each measure and its application in the treatment of refractory organic pollutants are reviewed.

Key words: Fenton oxidation, refractory organic wastewater, H₂O₂ produced in situ, iron sludge reduction, wide pH range

中图分类号:

X703

王锐, 刘宪华, 王勇, 邵宗泽. Fenton氧化处理难降解有机废水研究进展[J]. 工业水处理, 2022, 42(5): 58-66.

Rui WANG, Xianhua LIU, Yong WANG, Zongze SHAO. Research progress of Fenton oxidation treatment refractory organic wastewater[J]. Industrial Water Treatment, 2022, 42(5): 58-66.

https://www.iwt.cn/CN/Y2022/V42/I5/58

图/表 6

图1 Fenton技术文献发表趋势分析

Fig. 1 Trend analysis of Fenton technical literature

图2 Fenton技术处理废水的研究进展

Fig. 2 Research progress of Fenton technology for wastewater treatment

图3 电-Fenton反应机理示意

Fig. 3 Schematic diagram of electro-Fenton reaction mechanism

图4 微生物电-Fenton工作原理示意

Fig. 4 Schematic diagram of the working principle of microbial electro-Fenton

图5 FBR-Fenton反应器（a）和FBR-光Fenton反应器（b）示意

Fig. 5 Schematic diagram of FBR-Fenton reactor（a） and FBR-photo-Fenton reactor（b）

表1 均相Fenton与非均相Fenton的优缺点对比

Table 1 Comparison of advantages and disadvantages of homogeneous Fenton and heterogeneous Fenton

可在较宽的pH范围内操作；

减少了铁污泥的形成；催化剂易于处理，可重复使用

高剂量H₂O₂，化学成本高；反应速率低；催化剂不易合成

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