INDUSTRIAL WATER TREATMENT ›› 2011, Vol. 31 ›› Issue (12): 73-76. doi: 10.11894/1005-829x.2011.31(12).73

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Comparative study on the advanced treatment methods for acrylic and its ester wastewater

Li Lifeng,Gu Xihui,Teng Houkai,Chen Jun,Wang Hao,Zhang Yongwei   

  1. CNOOC Tianjin Chemical Research & Design Institute,Tianjin 300131,China
  • Received:2011-09-30 Revised:2011-09-30 Online:2011-12-20 Published:2011-12-31

丙烯酸及其酯废水深度处理方法的比较研究

李立峰,顾锡慧,滕厚开,陈军,王昊,张勇伟   

  1. 中海油天津化工研究设计院, 天津 300131
  • 作者简介:李立峰(1980- ),2007年毕业于四川大学,硕士,工程师电话:022-26689181, E-mail :yxmhlhz@sohu.com

Abstract:

The effects of several advanced treatment methods for acrylic and its ester wastewater,which was biochemically treated,has been investigated.The removing rates of COD by Fenton process and microwave-assisted Fenton process can reach above 85%.The removing rates of COD by ozone oxidation process and iron carbon micro-electrolysis process are both lower than 40%,by ammonium persulfate-assisted ozone oxidation process can reach 79%,and by photoelectro-catalytic oxidation process is less than 8%.The iron carbon micro-electrolysis,Fenton,microwave-assisted Fenton and ozone oxidation can make the biodegradability of wastewater increase from 0.35 to 0.56,0.43,0.44 and 0.40,respectively.The photoelectro-catalytic oxidation process can make the biodegradability of wastewater decline sharply to 0.03.

Key words: acrylic wastewater, ozone oxidation, photoelectro-catalytic oxidation, micro-electrolysis, Fenton

摘要:

探索了几种方法对生化后的丙烯酸及其酯废水深度处理的能力。Fenton法和微波辅助Fenton法对COD的去除率>85%,臭氧氧化法和铁炭微电解法对COD的去除率均<40%,过硫酸铵辅助臭氧氧化法对COD的去除率可达79%,光电催化氧化法对COD的去除率<8%。铁炭微电解法、Fenton法、微波辅助Fenton法、臭氧氧化法可使废水可生化性由0.35分别提高到0.56、0.43、0.44、0.40,光电催化氧化法使废水可生化性锐减为0.03。

关键词: 丙烯酸废水, 臭氧氧化, 光电催化氧化, 微电解, Fenton

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