Advances in the treatment of phenol-containing wastewater by advanced oxidation technologies in China and abroad

doi:10.11894/1005-829x.2011.31.（05）.9

Abstract

Abstract:

Due to its high toxicity and refractory degradation,phenol-containing wastewater treatment has been prevalently concerned by researchers.The mechanisms of the degradation of phenol-containing wastewater by advanced oxidation technologies are expounded.The research progress in and developing trends of the phenol removing technologies in China and abroad,such as wet air oxidation,photocatalytic oxidation，electro-catalysis oxidation,ultrasonic wave oxidation and so on are introduced.The characteristics and superiority of every technology is analyzed.At the end,the application prospect of advanced oxidation technologies for phenol-containing wastewater treatment is forecast.

Key words: phenol-containing wastewater, advanced oxidation, photocatalysis

摘要：

酚类化合物的毒性高、难降解,其处理工艺受到研究者的普遍关注。阐述了高级氧化技术降解含酚废水的作用机理,对湿式氧化、光催化氧化、电催化氧化、超声波氧化等除酚工艺的国内外研究进展和发展趋势进行了介绍,并分析了各工艺的特点与优势,最后对高级氧化工艺处理含酚废水的应用前景进行展望。

关键词: 含酚废水, 高级氧化, 光催化

Gao Chao, Wang Qishan, Xia Haiyan. Advances in the treatment of phenol-containing wastewater by advanced oxidation technologies in China and abroad[J]. INDUSTRIAL WATER TREATMENT, 2011, 31(5): 9-12.

高超, 王启山, 夏海燕. 国内外高级氧化技术降解含酚废水的研究进展[J]. 工业水处理, 2011, 31(5): 9-12.

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URL: https://www.iwt.cn/EN/10.11894/1005-829x.2011.31.（05）.9

https://www.iwt.cn/EN/Y2011/V31/I5/9

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[26] 王磊,张永明.以光催化氧化与生物降解一体式反应器处理苯酚的研究[J] .上海师范大学学报:自然科学版,2009,38(3):303-309.对氨基苯酚［J］. 环境污染治理技术与设备，2006，7（4）：100-102.

［7］ Pérez I V， Rogak S， Branion R. Supercritical water oxidation of phenol and 2，4-dinitrophenol［J］. The Journal of Supercritical

Fluids，2004，30（1）：71-87.

［8］ Matheswaran M，Moon S Ⅰ. Influence parameters in the ozonation of phenol wastewater treatment using bubble column reactor under continuous circulation［J］. Journal of Industrial and Engineering Chemistry，2009，15（3）：287-292.

［9］ Manojlovic D，Ostojic D R，Obradovic B M，et al. Removal of phenol and chlorophenols from water by new ozone generator［J］. Desalination，2007，213（1/2/3）：116-122.

［10］ Charinpanitkul T，Limsuwan P，Chalotorn C，et al. Synergetic removal of aqueous phenol by ozone and activated carbon within three-phase fluidized-bed reactor［J］. Journal of Industrial and Engineering Chemistry，2010，16（1）：91-95.

［11］ Zazo J A，Casas J A，Mohedano A F，et al. Catalytic wet peroxide oxidation of phenol with a Fe/active carbon catalyst［J］. Applied Catalysis B：Environmental，2006，65（3/4）：261-268.

［12］ Liou R M，Chen S H. CuO impregnated activated carbon for catalytic wet peroxide oxidation of phenol［J］. Journal of Hazar-dous Materials，2007，172（1）：498-506.

［13］ Mahmoud S S，Ahmed M M. Electrocatalytic oxidation of phenol using Ni-Al2O3 composite-coating electrodes［J］. Journal of Alloys and Compounds，2009，477（1/2）：570-575.

［14］ Ma Hongzhu，Zhang Xinhai，Ma Qingliang，et al. Electrochemical catalytic treatment of phenol wastewater［J］. Journal of Hazardous Materials，2009，165（1/2/3）：475-480.

［15］ Li Miao，Feng Chuanping，Hu Weiwu，et al. Electrochemical degradation of phenol using electrodes of Ti/RuO2-Pt and Ti/IrO2-Pt［J］. Journal of Hazardous Materials，2009，162（1）：455-462.

［16］ Pimentel M，Oturan N，Dezotti M，et al. Phenol degradation by advanced electrochemical oxidation process electro-Fenton using a carbon felt cathode［J］. Applied Catalysis B： Environmental，2008，83（1/2）：140-149.

［17］ Zainudin N F，Abdullah A Z，Mohamed A R. Characteristics of supported nano-TiO2/ZSM-5/silica gel（SNTZS）：photocatalytic degradation of phenol［J］. Journal of Hazardous Materials，2010，174（1/2/3）：299-306.

［18］廉今兰，金星. 纳米TiO2-沸石光催化降解含酚废水的研究［J］. 吉林化工学院学报，2009， 26（4）：8-10.

［19］ Chiou C H，Juang R S. Photocatalytic degradation of phenol in aqueous solutions by Pr-doped TiO2 nanoparticles［J］. Journal of Hazardous Materials，2007，149（1）：1-7.

［20］ Kuic H， Koprivanac N，Boic A L，et al. Photo-assisted Fenton type processes for the degradation of phenol： a kinetic study［J］. Journal of Hazardous Materials， 2006，136（3）：632-644.

［21］班福忱，李承斌，程琳，等. Fenton试剂法处理苯酚废水的研究［J］. 化工技术与开发，2009， 38（4）：47-49.

［22］ Liao Qiu，Sun Jing，Gao Lian. Degradation of phenol by heterogeneous Fenton reaction using multi-walled carbon nanotube supported Fe2O3 catalysts［J］. Colloids and Surfaces A： Physicochemical and Engineering Aspects，2009，345（1/2/3）：95-100.

［23］严平，杨晓帆，邬江华，等. 超声波处理苯酚废水的研究［J］. 西南民族大学学报：自然科学版，2008，34（3）：535-538.

［24］孙维义，宋宝增. 微波诱导氧化处理苯酚废水研究［J］. 西南科技大学学报，2008，23（1）： 61-65.

［25］刘琼玉，刘立，崔菲菲. 太阳光Fenton氧化对含酚废水生物降解影响研究［J］. 环境科学与技术，2008，31（7）：116-119.

［26］王磊，张永明. 以光催化氧化与生物降解一体式反应器处理苯酚的研究［J］. 上海师范大学学报：自然科学版，2009，38（3）：303-309.

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