Research progress in the treatment of organic wastewater by the three-dimensional electrode method

doi:10.11894/1005-829x.2016.36(8).011

Abstract

Abstract:

In comparison with conventional two-dimensional electrodes,the three-dimensional electrode has advantages,such as good mass transfer effect,high current efficiency,high surface/volume ratio,etc. The research and application of organic wastewater treatment have been more and more extensive. The mechanism of three-dimensional electrodes,and classification & preparation methods for particle electrodes are introduced. The combined usage of Fenton,photocatalytic technology,ultrasonic,iron-carbon micro-electrolysis and biological technique are summarized. Moreover,the existing problems of three-dimensional electrode process and future research trends are indicated.

Key words: three-dimensional electrode, Fenton, iron-carbon micro-electrolysis, organic wastewater

摘要：

三维电极相较于二维电极具有传质效果好、电流效率高、体面比大等优点，其处理有机废水的研究和应用也越来越广泛。介绍了三维电极法的机理、粒子电极的分类及制备方法，同时对三维电极法与Fenton法、光催化氧化法、超声法、铁碳微电解法、生物法技术的联用进行了总结，并指出三维电极法目前存在的问题以及未来研究趋势。

关键词: 三维电极, Fenton, 铁碳微电解, 有机废水

CLC Number:

X703

Wu Nana, Zheng Lu, Li Yafeng. Research progress in the treatment of organic wastewater by the three-dimensional electrode method[J]. INDUSTRIAL WATER TREATMENT, 2016, 36(8): 11-15.

吴娜娜, 郑璐, 李亚峰. 三维电极法处理有机废水的研究进展[J]. 工业水处理, 2016, 36(8): 11-15.

/ / Recommend / Download Citations

URL: https://www.iwt.cn/EN/10.11894/1005-829x.2016.36(8).011

https://www.iwt.cn/EN/Y2016/V36/I8/11

References

[1] 刘晶冰,燕磊,白文荣,等.高级氧化技术在水处理的研究进展[J].水处理技术,2011,37(3):11-17.
[2] 王静,冯玉杰,崔玉虹.电化学水处理技术的研究应用进展[J].环境保护,2003(12):19-22.
[3] Simonsson D.Electrochemistry for a cleaner environment[J].Che-mical Society Reviews,1997,26(3):181-189.
[4] Tomat R,Rigo A.Electrochemical oxidation of toluene promoted by OH radicals[J].Journal of Applied Electrochemistry,2004,14(l):1-8.
[5] Zhao Xu,Li Angzhen,Mao Ran,et al.Electrochemical removal of haloacetic acids in a three-dimensional electrochemical reactor with Pd-GAC particles as fixed filler and Pd-modified carbon paper as cathode[J].Water Research,2014,51:134-143.
[6] 班福忱.三维电极-Fenton试剂法处理苯酚废水的试验研究[D].沈阳:东北大学,2009.
[7] 王万鹏,张劲松,周集体,等.三维流化床电极法深度处理焦化废水的研究[J].工业水处理,2009,29(6):24-27.
[8] 张杰,冉献强,范建伟,等.三维电极法处理废水的研究进展[J].四川环境,2011,30(3):119-122.
[9] Kong Wuping,Wang Bo,Ma Hongzhu,et al.Electrochemical treatment of anionic surfactants in synthetic wastewater with three dimensional electrodes[J].Journal of Hazardous Materials,2006,137(3):1532-1537.
[10] Sharifian H,Kirk D W.Electrochemical oxidation of phenol[J].Journal of the Electrochemical Society,1986,133(5):921-924.
[11] 班福忱,刘炯天,程琳,等.不同类型填料的三维电极/Fenton试剂法处理苯酚废水[J].环境污染与防治,2009,31(4):24-27.
[12] 崔晓晓,张永刚.规整型第三电极对三维电极体系性能的影响研究[J].环境科学与技术,2013,36(8):115-119.
[13] 张芳,李光明,盛怡,等.三维电解法处理苯酚废水的粒子电极研究[J].环境科学,2007,28(8):1715-1719.
[14] 程勇,孟庆函,曹兵.负载Ni炭气凝胶粒子电极电催化氧化处理甲基橙废水的研究[J].环境工程学报,2011,5(5):1086-1090.
[15] 辛岳红,魏刚,魏云鹏,等.沸石负载复合氧化物粒子电极的制备及其电催化活性[J].北京化工大学学报:自然科学版,2010,32(2):54-58.
[16] 王昭阳,齐晶瑶,王博,等.钢渣粒子电极三维电催化法处理模拟印染废水[J].哈尔滨工业大学学报,2015,47(8):38-42.
[17] Wang Yaqiong,Gu Bin,Xu Wenlin.Electro-catalytic degradation of phenol on several metal-oxide anodes[J].Journal of Hazardous Materials,2009,162(2/3):1159-1164.
[18] 钟锐超,周德鸿,陈卫国,等.粒子电极堆放方式对三维电极体系性能的影响研究[J].环境科学学报,2011,31(10):2174-2178.
[19] 冯壮壮,梁文艳,王海东,等.三维粒子电极填充方式对焦化废水深度处理能耗的影响[J].环境工程,2015(2):7-10.
[20] Rosales E,Pazos M,Longo M A,et al.Electro-Fenton decoloration of dyes in a continuous reactor:a promising technology in colored wastewater treatment[J].Chemical Engineering Journal,2009,155(1/2):62-67.
[21] Jiang Chengchun,Zhang Jiafa.Progress and prospect in electro-Fenton process for wastewater treatment[J].Journal of Zhejiang University Science A,2007,8(7):1118-1125.
[22] Ogutveren U B,Gönen N,KoParal S.Removalof chromium from aq-ueous solutions and Plating bath rinse by an electrochemical me-thod[J].International Journal of Environmental Studies,1994,45(2):81-87.
[23] 石岩,王启山,岳琳,等.三维电极-电Fenton法处理垃圾渗滤液[J].天津大学学报,2009,42(3):248-252.
[24] Liu Wei,Ai Zhihui,Zhang Lizhi.Design of a neutral three-dimen-sional electro-Fenton system with foam nickel as particle electrodes for wastewater treatment[J].Journal of Hazardous Materials,2012,243:257-264.
[25] Wang C T,Hu J L,Chou W L,et al.Removal of color from real dyeing wastewater by electro-Fenton technology using a three-dimensional graphite cathode[J].Journal of Hazardous Materials,2008,152(2):601-606.
[26] Yang Ying,Li Xinjun,Chen Juntao,et al.Effect of doping mode on the photocatalytic acticities of Mo/TiO₂[J].Journal of Photochem-istry and Photobiology A,2004,163(3):517-522.
[27] 康泽双,苏会东.三维粒子电极光电催化亚甲基蓝研究[J].当代化工,2015,44(7):1693-1696.
[28] 黄驰,顾桂山,王亚楠,等.Ce/TiO₂/Fe₃O₄粒子电极光电催化降解藏红T模拟染料废[J].环境化学,2015,34(5):995-1001.
[29] An Taicheng,Xiong Ya,Li Guiying,et al.Synergetic effect in degra-dation of formic acid using a new photoelectrochemical reactor[J].Journal of Photochemistry and Photobiology,2002,151(1/2/3):155-165.
[30] Holt K B,Del Campo J,Foord J S,et al.Sonoelectrochemistry at pla-tinum and boron-doped diamond electrodes:achieving fast mass tran-sport for slow diffusers[J].Journal of Electroanalytical Chemistry,2001,513(2):94-99.
[31] Klima J,Bernard C,Degrand C.Effects of ultrasound on voltammetric measurements at a solid electrode[J].Journal of Electroanalytical Chemistry,1994,367(1/2):297-300.
[32] Trabelsi F,Ait-Lyazidi H,Ratsimba B,et al.Oxidation of phenol in wastewater by sonoelectrochemistry[J].Chemistry Engineering Sei-ence,1996,51(10):1857-1865.
[33] 曹志斌,王玲,薛建军,等.超声协同三维电极处理染料废水[J].水处理技术,2008,34(11):57-60.
[34] 姜兴华,刘勇健.铁炭微电解法在废水处理中的研究进展及应用现状[J].工业安全与环保,2009,35(1):26-27.
[35] Han Dan,Zhao Youcai,Hong Feiyu.Pretreatment of wastewater con-tained DMF by combined aerobic Fe-C micro-electrolysis and plu-ral three-dimensional electrodes oxidation process[J].Bioinformatics and Biomedical Engineering,2009(6):1-4.
[36] 郑耿涛,李金花,周保学,等.三维电极-铁炭微电解法组合工艺处理黄连素废水[J].净水技术,2011(6):39-43.
[37] 郭劲松,杨琳,陈猷鹏,等.三维电极生物膜反应器全程自养脱氮的启动研究[J].环境科学学报,2012,32(6):1342-1347.
[38] 郭东茹.三维电极-生物膜反应器全程脱氮研究[D].重庆:重庆大学,2011.
[39] 李素梅,郝瑞霞,孟成成.三维电极生物膜反应器低温启动试验研究[J].中国给水排水,2013,29(5):101-105.
[40] Zhou Minghua,Fu Wenjing,Gu Heyan,et al.Nitrate removal from groundwater by a novel three-dimensional electrode biofilm react-or[J].Electrochimica Acta,2007,52(19):6052-6059.
[41] 杨琳,方芳,兰国新,等.电极生物膜自养脱氮系统中的电化学作用[J].环境化学,2014,33(6):1033-1037.
[42] 姚静华,赵国智,田光明.复三维电极-生物膜反应器脱除饮用水中硝酸盐的试验研究[J].环境科学学报,2012,32(6):1333-1341.

Please choose a citation manager

Content to export