INDUSTRIAL WATER TREATMENT ›› 2017, Vol. 37 ›› Issue (2): 51-55. doi: 10.11894/1005-829x.2017.37(2).051

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Preparation of GO/Fe3O4/ZnO composite and its photo-assisted Fenton degradation of phenol

Li Chengxi1, Wu Kunkun1, Meng Zuchao1, Liu Xiang1, Li Qianding1, Song Jiuxu2   

  1. 1. College of Chemistry and Chemical Engineering, Xi'an Shiyou University, Xi'an 710065, China;
    2. School of Electronic Engineering, Xi'an Shiyou University, Xi'an 710065, China
  • Received:2016-11-17 Online:2017-02-20 Published:2017-02-25

GO/Fe3O4/ZnO的制备及其光助Fenton降解苯酚

李成希1, 吴坤坤1, 孟祖超1, 刘祥1, 李谦定1, 宋久旭2   

  1. 1. 西安石油大学化学化工学院, 陕西西安 710065;
    2. 西安石油大学电子工程学院, 陕西西安 710065
  • 通讯作者: 孟祖超,E-mail:zcmeng@xsyu.edu.cn。 E-mail:zcmeng@xsyu.edu.cn
  • 作者简介:李成希(1991-),在读硕士。E-mail:lichengxi121314@foxmail.com。
  • 基金资助:

    陕西省自然科学基金项目(2013JQ2015);陕西省教育厅基金项目(2013JK0673);国家级大学生创新创业训练计划资助项目(201210705041);西安石油大学博士科研启动基金资助项目(Ys29031618)

Abstract:

The composite material GO/Fe3O4/ZnO has been prepared by hydrothermal method,and characterized by SEM,XRD and FT-IR. Having phenol as the degradation target,the influences of the factors,such as the dosages of the composite material GO/Fe3O4/ZnO,and H2O2,the concentration of phenol,the pH,etc. on the degradation effect of phenol are discussed. The experimental results show that using the composite materials,under the following conditions:the GO/Fe3O4/ZnO dosage is 200 mg/L,H2O2 dosage 12 mmol/L,and pH=7.2,88.85 mg/L of oilfield wastewater is treated by the photo-catalysis Fenton degradation process. 60 min later,the phenol degradation rate can reach 98%.

Key words: graphene, photo-catalysis, Fenton system, visible light

摘要:

采用水热法制备了GO/Fe3O4/ZnO复合材料,并用SEM、FT-IR、XRD等手段对其进行了表征。以苯酚为降解目标,探讨了GO/Fe3O4/ZnO复合材料用量、H2O2投加量、苯酚浓度和pH等因素对降解苯酚效果的影响。实验结果表明,在GO/Fe3O4/ZnO投加量为200 mg/L,H2O2投加量为12 mmol/L,pH=7.2的条件下,利用该复合材料对苯酚质量浓度为88.85 mg/L的油田污水进行光催化Fenton降解,60 min后,苯酚降解率可达98%。

关键词: 石墨烯, 光催化, Fenton体系, 可见光

CLC Number: