INDUSTRIAL WATER TREATMENT ›› 2018, Vol. 38 ›› Issue (2): 63-66. doi: 10.11894/1005-829x.2018.38(2).060

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Synthesis of rGO-CeO2-Fe2O3 and the treatment of highly acidic dye wastewater

Zhang Wenjun, Li Cuiluo, Li Yingjie, Zhang Xiaoxiong   

  1. School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, China
  • Received:2017-10-19 Online:2018-02-20 Published:2018-03-03

rGO-CeO2-Fe2O3的制备及高酸性染料废水的处理

章文军, 李翠落, 李英杰, 张晓雄   

  1. 河北工业大学化工学院, 天津 300130
  • 作者简介:章文军(1969-),博士,硕士生导师,教授。电话:022-60200451,E-mail:wjzhang@hebut.edu.cn。

Abstract: The rGO-CeO2-Fe2O3 composite material has been prepared by hydrothermal method using graphene oxide as carrier. The composite material has been characterized by XRD,SEM,EDS and FT-IR,and its photo-catalytic degradation performance and mechanisms investigated. The results show that the catalytic degradation effect of rGO-CeO2-Fe2O3 composite on the highly acidic dye wastewater is obviously better than that of rGO-CeO2 and rGO-Fe2O3,and the dye degradation rate is as high as 97.64%,under UV irradiation for 30 min. The addition of rGO and CeO2 has accelerated the charge transfer efficiency and reduced the electron-hole recombination rate,which significantly improves the photo-catalytic activity of Fe2O3.

Key words: rGO-CeO2-Fe2O3, photo-catalytic, highly acidic dye wastewater

摘要: 以氧化石墨烯为载体,通过水热法制备rGO-CeO2-Fe2O3复合材料。采用XRD、SEM、EDS和FT-IR对制备的复合材料进行了表征,并对其光催化降解性能和机理进行了研究。结果表明:rGO-CeO2-Fe2O3复合材料对高酸性染料废水的光催化降解效果明显优于rGO-CeO2和rGO-Fe2O3,紫外光照30 min,染料降解率高达97.64%。rGO和CeO2的加入,加快了电荷传输效率,降低了电子-空穴复合率,明显提高了Fe2O3的催化活性。

关键词: rGO-CeO2-Fe2O3, 光催化, 高酸性染料废水

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