Industrial Water Treatment ›› 2019, Vol. 39 ›› Issue (5): 57-60. doi: 10.11894/iwt.2018-0446

• Research and Experiment • Previous Articles     Next Articles

Influence of sulfide ion on steel corrosion in CO2 containing sewage water

Chunping Liu1(),Xia Han2,*()   

  1. 1. Energy Management and Environmental Protection Department of China Petrochemical Corporation Co., Ltd., Beijing 100728, China
    2. Sinopec Energy Conservation and Environmental Protection Engineering Technology Co., Ltd., Dongying 257026, China
  • Received:2019-03-20 Online:2019-05-20 Published:2019-08-07
  • Contact: Xia Han E-mail:Liucp@sinopec.com;sjyhx@163.com
  • Supported by:
    国家科技支撑计划课题(2012BAC24B04)

含CO2油田采出水中S2-对碳钢腐蚀行为的影响

刘春平1(),韩霞2,*()   

  1. 1. 中国石油化工集团有限公司能源管理与环境保护部, 北京 100728
    2. 中石化节能环保工程科技有限公司, 山东东营 257026
  • 通讯作者: 韩霞 E-mail:Liucp@sinopec.com;sjyhx@163.com
  • 作者简介:刘春平(1967-),硕士,高级工程师。E-mail:Liucp@sinopec.com
  • 基金资助:
    国家科技支撑计划课题(2012BAC24B04)

Abstract:

Aiming at the corrosion problem of produced water in high CO2 content oilfield, the corrosion behavior of carbon steel by S2- produced by SRB propagation in produced water and S2- carried by formation in development process were studied by corrosion electrochemical method. It was recognized that S2- produced by SRB propagation and S2- carried by formation in development process had little difference in effect on the corrosion behavior of carbon steel, a small amount of S2- could inhibit the corrosion of carbon steel, but when the concentration of S2- in sewage was more than 0.5 mg/L, S2- promoted the corrosion with the prolongation of time.

Key words: S2- concentration, corrosion behavior, sulfate reducing bacteria, characteristics of corrosion product film

摘要:

针对高含CO2油田采出水的腐蚀问题,利用腐蚀电化学方法,分别研究了采出水中由硫酸盐还原菌(SRB)繁殖产生的S2-及开发过程由地层携带的S2-对碳钢的腐蚀行为,通过研究认识到SRB繁殖产生的S2-和开发过程由地层携带的S2-对碳钢腐蚀行为的影响差别不大;且少量的S2-对碳钢的腐蚀有抑制作用,但当污水中S2-质量浓度大于0.5 mg/L时,随着时间的延长S2-对腐蚀起一定促进作用。

关键词: S2-浓度, 腐蚀行为, 硫酸盐还原菌, 腐蚀产物膜特点

CLC Number: