Industrial Water Treatment ›› 2020, Vol. 40 ›› Issue (11): 102-105, 110. doi: 10.11894/iwt.2019-1078

• Water Treatment in Oil-Gas Field • Previous Articles     Next Articles

The research and application of treatment agent for high salinity fracturing flowback fluid

Feng Gao1(),Fang Cheng1,Jun Hu1,Tengfei Chen1,Zhongcong Zhao2   

  1. 1. Xi'an Changqing Chemical Group Co., Ltd., PetroChina Changqing Oilfield Company, Xi'an 710018, China
    2. College of Petroleum Engineering, Yangtze University, Wuhan 430100, China
  • Received:2020-07-06 Online:2020-11-20 Published:2020-11-24

高矿化度压裂返排液处理剂的研究应用

高峰1(),程芳1,胡军1,陈腾飞1,赵众从2   

  1. 1. 中国石油长庆油田分公司西安长庆化工集团有限公司, 陕西西安 710018
    2. 长江大学石油工程学院, 湖北武汉 430100
  • 作者简介:高峰(1987-),油气田开发工程师。电话:15249101857, E-mail:gaofeng0_cq@petrochina.com.cn

Abstract:

The contents of sodium, calcium, magnesium, iron, barium, aluminum, manganese in the high salinity fracturing flowback fluid were determined by atomic absorption spectrum. From the analysis on the effect of Ca2+, Mg2+, Fe3+ on the solubility of hydrophobically associating polymer, it was found that Ca2+ was main factor. The ion treatment agent which could quickly react with calcium ions has been developed indoors to form water-soluble chelating polymers. This could largely eliminate the effects of metal ions on the solubility of hydrophobically associating polymer. This treatment agent had been applied in15 wells of Changqing Gasfield and 3 900 m3 treatment fluid had been recovered. It could not only accelerate the recycling of water resources, but also reduce environmental pollutions.

Key words: high salinity, hydrophobically associating polymer, fracturing flowback fluid

摘要:

采用原子吸收法测定了高矿化度压裂返排液水样中钠、钙、镁、铁、钡、铝、锰等7种金属元素的含量,通过分析Ca2+、Mg2+、Fe3+对疏水缔合聚合物溶解能力的影响,确定了Ca2+是主要因素。室内开发了能络合游离Ca2+的处理剂,使其形成水溶性螯合物,消除金属离子对疏水缔合聚合物溶解能力的影响。在长庆油田15口井进行了现场应用,回收处理液3 900 m3,不仅促进了水资源的循环利用,而且减少了环境污染。

关键词: 高矿化度, 疏水缔合聚合物, 返排液

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