Preparation and adsorption of sodium lignosulfonate grafted sodium polyacrylate resin

doi:10.19965/j.cnki.iwt.2020-1239

Abstract

Abstract:

Sodium lignosulfonate and sodium polyacrylate were used as raw materials to prepare a sodium lignosulfonate grafted sodium polyacrylate resin with heavy metal adsorption properties, and its adsorption properties for heavy metal ions Pb²⁺ and Cu²⁺ in water were studied. Firstly, the influence of initiator dosage, reaction time, reaction temperature and other preparation conditions on the grafting rate of adsorption resin was studied. Secondly, the prepared adsorption resin was characterized by SEM, XRD and FTIR. Finally, the influence of grafting rate, pH, adsorption time, and the initial metal ion concentration on the adsorption effect were investigated. The results showed that the maximum grafting rate was 81.7%, and the maximum adsorption rates of the prepared adsorption resin for Pb²⁺ and Cu²⁺ were 93.28% and 91.46%, respectively. The saturated adsorption capacities were 25.338 1 and 23.675 9 mg/g, respectively.

Key words: sodium lignosulfonate, sodium polyacrylate, grafting, heavy metal, adsorption

摘要：

以木质素磺酸钠和聚丙烯酸钠为原料制备了具有重金属吸附性的木质素磺酸钠接枝聚丙烯酸钠树脂，并研究了其对水中重金属离子Pb²⁺和Cu²⁺的吸附性能。首先研究了引发剂用量、反应时间、反应温度等制备条件对吸附树脂接枝率的影响；其次对制备的吸附树脂进行了SEM、XRD及FTIR表征；最后考察了接枝率、pH、吸附时间、初始金属离子浓度对吸附效果的影响。结果表明：最大接枝率为81.7%；制备的吸附树脂对Pb²⁺和Cu²⁺的最大吸附率分别为93.28%和91.46%，饱和吸附容量分别为25.338 1、23.675 9 mg/g。

关键词: 木质素磺酸钠, 聚丙烯酸钠, 接枝, 重金属, 吸附

CLC Number:

X703

Jie WEI,Ming XU,Hongwei LI. Preparation and adsorption of sodium lignosulfonate grafted sodium polyacrylate resin[J]. Industrial Water Treatment, 2021, 41(10): 72-77.

魏婕,徐铭,李宏伟. 木质素磺酸钠接枝聚丙烯酸钠树脂的制备及其吸附[J]. 工业水处理, 2021, 41(10): 72-77.

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URL: https://www.iwt.cn/EN/10.19965/j.cnki.iwt.2020-1239

https://www.iwt.cn/EN/Y2021/V41/I10/72

Figures/Tables 12

References 20

1	邓景衡, 余侃萍, 肖国光, 等. 吸附法处理重金属废水研究进展[J]. 工业水处理, 2014, 34 (11): 4- 7. doi: 10.11894/1005-829x.2014.34(11).004
2	JIA Kun , HE Xiaohong , ZHOU Xuefei , et al. Solid state effective luminescent probe based on CdSe@CdS/amphiphilic co-polyarylene ether nitrile core-shell superparticles for Ag⁺ detection and optical strain sensing[J]. Sensors and Actuators B: Chemical, 2018, 257, 442- 450. doi: 10.1016/j.snb.2017.10.187
3	向育君, 许爱清, 周信, 等. 改性木质素磺酸钠水凝胶对镉离子的吸附研究[J]. 离子交换与吸附, 2015, 31 (2): 115- 122. URL
4	王珏珏, 张越非, 池汝安, 等. 改性木质素磺酸钠对铅离子的吸附行为研究[J]. 武汉工程大学学报, 2017, 39 (1): 12- 18. doi: 10.3969/j.issn.1674-2869.2017.01.003
5	周海峰, 杨东杰, 伍晓蕾, 等. 漆酶改性木质素磺酸钠的结构表征及吸附特征[J]. 高等学校化学学报, 2013, (1): 232- 238. URL
6	贾振宇, 崔英德, 黎新明, 等. 聚丙烯酸钠高吸水性树脂的改性研究进展[J]. 化工进展, 2004, (5): 468- 471. doi: 10.3321/j.issn:1000-6613.2004.05.003
7	俞洁, 郑继东, 陆泉芳. 壳聚糖/聚丙烯酸水凝胶的制备及对Cu²⁺和Cd²⁺的吸附性能[J]. 精细化工, 2016, 33 (12): 1398- 1404. URL
8	CHEN Fangyan , YE Wei , TANG Yubin . Adsorption of heavy metals by sodium polyacrylate-humic acid-rectorite composite as a novel adsorbent[J]. Advanced Materials Research, 2012, 550 URL
9	杨帆, 高俊发. 聚丙烯酸钠吸附含铜废水的研究[J]. 应用化工, 2012, 41 (4): 602- 605. doi: 10.3969/j.issn.1671-3206.2012.04.013
10	张保平, 马钟琛, 刘运, 等. 木质素的化学改性及其对AuCl的吸附[J]. 化工学报, 2017, 68 (5): 1946- 1953. URL
11	黄祖强, 梁兴唐, 高利, 等. 机械活化甘蔗渣与丙烯酸(钠)的接枝共聚反应[J]. 化工学报, 2009, 60 (6): 1573- 1580. doi: 10.3321/j.issn:0438-1157.2009.06.036
12	郭睿, 宋博, 郭煜, 等. 木质素磺酸盐接枝共聚物的合成及工艺优化[J]. 化工进展, 2018, 37 (5): 335- 340. URL
13	贺龙强, 胡鹏, 刘中阳. 耐盐性淀粉接枝丙烯酸类高吸水性树脂的制备及表征[J]. 化工新型材料, 2015, 43 (8): 96- 98. URL
14	ABDEL M , ZAHRAN H , BASUNI M M . Study on graft-copolymerization of sodium lignosulfonates with acrylic monomers[J]. KGK Rubberpoint, 2015, 68 (9): 35- 40. URL
15	THIRUMAVALAVAN M , LAI Y L , LEE J F . Fourier transform infrared spectroscopic analysis of fruit peels before and after the adsorption of heavy metal ions from aqueous solution[J]. Journal of Chemical & Engineering Data, 2011, 56 (5): 2249- 2255. URL
16	姜立萍. 高分子纳米复合吸附剂在重金属废水处理中的应用[J]. 工业水处理, 2015, 35 (12): 10- 13. doi: 10.11894/1005-829x.2015.35(12).010
17	SUHAS P J M , CARROTT M M L , CARROTT R . Lignin-From natural adsorbent to activated carbon: A review[J]. Bioresource Technology, 2007, 98 (12): 2301- 2312. doi: 10.1016/j.biortech.2006.08.008
18	王寿武, 邓应淼, 周雪婷, 等. 聚丙烯酸钠的合成及性能研究[J]. 精细石油化工进展, 2010, (5): 42- 43. doi: 10.3969/j.issn.1009-8348.2010.05.010
19	夏广洁, 宋萍, 邱宇平. 牛粪源和木源生物炭对Pb(Ⅱ)和Cd(Ⅱ)的吸附机理研究[J]. 农业环境科学学报, 2014, 33 (3): 569- 575. URL
20	ZHU Yinian , JIANG Yanhong , ZHU Zongqiang , et al. Preparation of a porous hydroxyapatite carbon composite with the bio-template of sugarcane top stems and its use for the Pb(Ⅱ) removal[J]. Journal of Cleaner Production, 2018, 187 (1): 650- 661. URL

水平	影响因素
水平	A反应时间/h	B反应温度/益	C引发剂体积/mL	D木质素磺酸钠与聚丙烯酸钠质量比
1	4	50	5	1∶2
2	6	55	10	1∶1
3	8	60	15	2∶1

水平	影响因素
水平	A反应时间/h	B反应温度/益	C引发剂体积/mL	D木质素磺酸钠与聚丙烯酸钠质量比
1	4	50	5	1∶2
2	6	55	10	1∶1
3	8	60	15	2∶1

序号	A	B	C	D	接枝率/%
F1	4	50	5	1∶2	28.0
F2	4	55	10	1∶1	81.6
F3	4	60	15	2∶1	36.3
F4	6	50	10	2∶1	57.6
F5	6	55	15	1∶2	78.3
F6	6	60	5	1∶1	41.7
F7	8	50	15	1∶1	62.1
F8	8	55	5	1∶2	70.2
F9	8	60	10	2∶1	44.5
K₁	48.63	49.23	46.63	58.83
K₂	59.2	76.7	61.23	61.8
K₃	58.93	40.83	58.9	46.13
R	10.57	35.87	14.6	15.67

序号	A	B	C	D	接枝率/%
F1	4	50	5	1∶2	28.0
F2	4	55	10	1∶1	81.6
F3	4	60	15	2∶1	36.3
F4	6	50	10	2∶1	57.6
F5	6	55	15	1∶2	78.3
F6	6	60	5	1∶1	41.7
F7	8	50	15	1∶1	62.1
F8	8	55	5	1∶2	70.2
F9	8	60	10	2∶1	44.5
K₁	48.63	49.23	46.63	58.83
K₂	59.2	76.7	61.23	61.8
K₃	58.93	40.83	58.9	46.13
R	10.57	35.87	14.6	15.67

金属离子	质量浓度（mg·L^-1）	试验值q_e/（mg·g^-1）	准二级吸附动力学方程
金属离子	质量浓度（mg·L^-1）	试验值q_e/（mg·g^-1）	K₁/（g·mg^-1·min^-1）	q_e/（mg·g^-1）	R²
Pb²⁺	50	11.66	0.0084	12.9126	0.9823
Cu²⁺	50	11.43	0.0063	12.9846	0.9848

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