Pretreatment of phosphating wastewater with different advanced oxidation processes

doi:10.19965/j.cnki.iwt.2023-1024

Industrial Water Treatment ›› 2024, Vol. 44 ›› Issue (11): 61-66. doi: 10.19965/j.cnki.iwt.2023-1024

• RESEARCH AND EXPERIMENT • Previous Articles Next Articles

Pretreatment of phosphating wastewater with different advanced oxidation processes

Chenfei ZHANG¹^,²(), Can HE¹^,³^,⁴(), Zhongguo ZHANG¹^,³^,⁴, Jianbing WANG², Jian ZHANG¹^,³^,⁴, Mengyu WANG¹^,⁵, Hongfang SUN¹^,³^,⁴, Zhifeng HU¹^,³^,⁴, Chenhao GONG¹^,³^,⁴, Junxing HAN¹^,³^,⁴, Yue SHAN¹^,³^,⁴

^1. Institute of Resources and Environment, Beijing Academy of Science and Technology, Beijing 100089, China
^2. School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China
^3. Key Laboratory of Energy-Water Conservation and Wastewater Resources Recovery, China National Light Industry, Beijing 100089, China
^4. The National Engineering Laboratory of Circular Economy (Industrial Wastewater Utilization and Industrial Water Conservation), Beijing 100089, China
^5. School of Environment, Beijing Jiaotong University, Beijing 100044, China

Received:2024-07-22 Online:2024-11-20 Published:2024-12-09

不同高级氧化工艺预处理磷化废水

张辰飞¹^,²(), 何灿¹^,³^,⁴(), 张忠国¹^,³^,⁴, 王建兵², 张健¹^,³^,⁴, 王梦玉¹^,⁵, 孙红芳¹^,³^,⁴, 胡智丰¹^,³^,⁴, 宫晨皓¹^,³^,⁴, 韩军兴¹^,³^,⁴, 单悦¹^,³^,⁴

^1. 北京市科学技术研究院资源环境研究所，北京 100089
^2. 中国矿业大学（北京）化学与环境工程学院，北京 100083
^3. 中国轻工业节能节水与废水资源化重点实验室，北京 100089
^4. 全国循环经济工程实验室（工业废水资源化及工业节水），北京 100089
^5. 北京交通大学环境学院，北京 100044

作者简介:
张辰飞（2000— ），硕士。E-mail：zchenfei66@163.com
何灿，博士，正高级工程师。E-mail：hecan086@163.com。
基金资助:
国家重点研发计划项目(2022YFC3203004); 北京市科技计划项目(Z201100008220012); 北京市科学技术研究院市级财政创新工程项目(24CA006)

Abstract

Abstract:

The effects of three oxidation processes, ozone (O₃) oxidation, O₃/potassium peroxymonosulfate (PMS) oxidation, and O₃/hydrogen peroxide (H₂O₂) oxidation, on the treatment of phosphating wastewater were compared. Additionally, the quality of effluent was analyzed through measurements of COD, UV₂₅₄, and three-dimensional fluorescence spectra, highlighting the influence of various advanced oxidation processes on the wastewater effluent quality and the removal pathways. The results showed that increasing the ozone dosage and adding appropriate amounts of PMS and H₂O₂ could enhance the removal of organic contaminants from phosphating wastewater. With initial COD of (130±20) mg/L, reaction time of 120 minutes, and ozone dosage of 7.65 mg/min, the COD removal rate was only 37% by the ozonation process, the COD removal rate reached 45.65% by the O₃/PMS oxidation process with PMS mass concentration of 2 g/L, the COD removal rate reached 58.3% by the O₃/H₂O₂ oxidation process with 0.5 g/L dosage of H₂O₂ (30% concentration). Among the three methods, the O₃/H₂O₂ process demonstrated the highest efficacy in removing COD from phosphating wastewater, as the synergistic production of more highly oxidative free radicals by O₃ and H₂O₂enhancd the oxidation capacity of the system. All three processes effectively degraded aromatic compounds and fluorescent substances in wastewater, while the individual O₃oxidation and the O₃/PMS process mainly degraded substances resembling proteins into fulvic and humic-like materials, and the O₃/H₂O₂ oxidation process could further degrade these fulvic and humic-like substances.

Key words: phosphating wastewater, pretreatment, ozonation, O₃/PMS, O₃/H₂O₂

摘要：

对比研究了单独臭氧（O₃）氧化、O₃/单过硫酸氢钾（PMS）氧化和O₃/过氧化氢（H₂O₂）氧化3种工艺预处理磷化废水的效果。通过对不同工艺处理后出水COD、UV₂₅₄和三维荧光光谱分析，研究不同高级氧化工艺对磷化废水出水水质的影响及去除途径。研究表明，增加臭氧投加量和添加适量的PMS、H₂O₂都可以提高对磷化废水出水中有机污染物的去除效果。废水初始COD （130±20） mg/L、反应120 min、O₃投加量7.65 mg/min时，单独臭氧氧化工艺，COD的去除率仅为37%；O₃/PMS氧化工艺，PMS投加量2 g/L，COD的去除率为45.65%；O₃/H₂O₂氧化工艺，H₂O₂（质量分数30%）投加量为0.5 g/L，COD去除率达到58.3%。3种工艺中O₃/H₂O₂对磷化废水中COD去除效果最好，O₃和H₂O₂协同产生更多强氧化性自由基，提高了反应体系的氧化能力。3种工艺对废水中的芳香族化合物及荧光类物质均有明显的降解作用，单独O₃氧化和O₃/PMS氧化工艺主要是将废水中类蛋白等物质降解为类富里酸和类腐殖酸类物质，O₃/H₂O₂氧化工艺可以对类富里酸和类腐殖酸类物质进一步降解。

关键词: 磷化废水, 预处理, 臭氧氧化, O₃/PMS, O₃/H₂O

CLC Number:

X703
X76

Chenfei ZHANG, Can HE, Zhongguo ZHANG, Jianbing WANG, Jian ZHANG, Mengyu WANG, Hongfang SUN, Zhifeng HU, Chenhao GONG, Junxing HAN, Yue SHAN. Pretreatment of phosphating wastewater with different advanced oxidation processes[J]. Industrial Water Treatment, 2024, 44(11): 61-66.

张辰飞, 何灿, 张忠国, 王建兵, 张健, 王梦玉, 孙红芳, 胡智丰, 宫晨皓, 韩军兴, 单悦. 不同高级氧化工艺预处理磷化废水[J]. 工业水处理, 2024, 44(11): 61-66.

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URL: https://www.iwt.cn/EN/10.19965/j.cnki.iwt.2023-1024

https://www.iwt.cn/EN/Y2024/V44/I11/61

Figures/Tables 7

Table 1 Characteristics of phosphating wastewater

项目	pH	COD/（mg·L^-1）	UV₂₅₄/cm^-1
数值	6.50±0.5	130±20	1.622±0.1

Table 2 Composition of phosphating wastewater

物质名称	质量分数/%	质量浓度/（μg∙L^-1）
油酸酰胺	0.15
烃类油	0.13
三甘醇单丁醚	0.05
丙二醇苯醚	0.05
硫酸钠+磷酸盐	0.23
铜		0.89
镉		0.22
铬		6.06
铍		0.21
砷		15.8
锌		4 830
铅		0.52
镍		9 060
铁		651
硒		0.59
锰		15 400

Fig.1 Effect of ozone dosage on COD of phosphating wastewater

Fig.2 Effect of PMS dosage on COD of phosphating wastewater

Fig.3 Effect of H₂O₂ dosage on COD of phosphating wastewater

Fig.4 UV₂₅₄ variation of effluent in different processes

Fig.5 3DEEM of effluent from different processes

References 19

1	刘绍根. 汽车涂装废水处理技术［J］. 工业用水与废水，2001，32（2）：11-13.
	LIU Shaogen. Treatment technology of automobile painting wastewater［J］. Industrial Water & Wastewater，2001，32（2）：11-13.
2	马细平. 汽车涂装废水处理工艺论析［J］. 资源节约与环保，2016，11：71.
	MA Xiping. Discussion on treatment technology of automobile painting wastewater［J］. Resources Economization & Environmental Protection，2016，11：71.
3	陈静怡，肖厚荣，刘鹤，等. 硫酸亚铁处理磷化废水工艺优化研究［J］. 蚌埠学院学报，2021，10（5）：19-23.
	CHEN Jingyi， XIAO Hourong， LIU He，et al. Optimization of phosphating wastewater treatment process by ferrous sulfate［J］. Journal of Bengbu University，2021，10（5）：19-23.
4	曾德芳，徐保林. 沉淀-絮凝结合法处理磷化废水的研究［J］. 环境工程学报，2009，3（5）：795-798.
	ZENG Defang， XU Baolin. Study on phosphorus removal from phosphorus-containing wastewater by sedimentation-flocculation precipitation［J］. Chinese Journal of Environmental Engineering，2009，3（5）：795-798.
5	王雪宁，杨晶晶，周晓吉，等. 汽车涂装废水处理技术的研究进展［J］. 涂料工业，2020，50（8）：64-70.
	WANG Xuening， YANG Jingjing， ZHOU Xiaoji，et al. The progress in wastewater treatment technology in automobile painting process［J］. Paint & Coatings Industry，2020，50（8）：64-70.
6	陈烨，董菲菲，陆骏，等. 混凝芬顿法处理汽车涂装有机废水［J］. 材料保护，2018，51（9）：126-129.
	CHEN Ye， DONG Feifei， LU Jun，et al. Treatment of organic wastewater in the process of automobile coating with coagulation-flocculation coupled with Fenton process［J］. Materials Protection，2018，51（9）：126-129.
7	万晓卉，张利，孙志国，等. 臭氧微气泡催化氧化处理实际汽车配件废水研究［J］. 河南化工，2020，37（12）：6-10.
	WAN Xiaohui， ZHANG Li， SUN Zhiguo，et al. Study on the treatment of automobile parts wastewater by ozone microbubble catalytic oxidation［J］. Henan Chemical Industry，2020，37（12）：6-10.
8	曾丽，徐洪亮，曾淼，等. 混凝-臭氧氧化法处理汽车喷漆废水的研究［J］. 材料保护，2019，52（9）：143-146.
	ZENG Li， XU Hongliang， ZENG Miao，et al. Treatment of automobile spray paint wastewater with combined coagulation-flocculation and ozone oxidation［J］. Materials Protection，2019，52（9）：143-146.
9	宋帅楠. 催化臭氧过硫酸盐耦合高级氧化处理高浓度丙烯腈废水［D］. 大连：大连理工大学，2017.
	SONG Shuainan. Treatment of high concentration acrylonitrile wastewater by catalytic ozone persulfate coupled with advanced oxidation［D］. Dalian：Dalian University of Technology，2017.
10	于译博. 臭氧过一硫酸盐耦合催化氧化体系的建立及研究［D］. 哈尔滨：哈尔滨工业大学，2021.
	YU Yibo. Establishment and study of ozone persulfate coupled catalytic oxidation system［D］. Harbin：Harbin Institute of Technology，2021.
11	YANG Ying， GUO Hongguang， ZHANG Yongli，et al. Degradation of bisphenol A using ozone/persulfate process：Kinetics and mechanism［J］. Water，Air，& Soil Pollution，2016，227（2）：53. doi:10.1007/s11270-016-2746-x
12	DE LAAT J， LE TRUONG G. Kinetics and modeling of the Fe（Ⅲ）/H₂O₂ system in the presence of sulfate in acidic aqueous solutions［J］. Environmental Science & Technology，2005，39（6）：1811-1818. doi:10.1021/es0493648
13	何灿，陈卓苗，李懿南，等. 不同高级氧化工艺处理焦化废水二级生化工艺出水研究［J］. 洁净煤技术，2019，25（3）：122-128.
	HE Can， CHEN Zhuomiao， LI Yi’nan，et al. Treatment of the secondary biochemical effluent from coking wastewater by different advanced oxidation processes［J］. Clean Coal Technology，2019，25（3）：122-128.
14	ANDREOZZI R， CAPRIO V， MAROTTA R. Iron（Ⅲ）（hydr）oxide-mediated photooxidation of 2-aminophenol in aqueous solution：A kinetic study［J］. Water Research，2003，37（15）：3682-3688. doi:10.1016/s0043-1354(03)00271-9
15	MARTINS R C， QUINTA-FERREIRA R M. Comparison of advanced oxidation processes（AOPs） based on O₃ and H₂O₂ for the remediation of real wastewaters［J］. Journal of Advanced Oxidation Technologies，2011，14（2）：282-291. doi:10.1515/jaots-2011-0214
16	CHEN Wen， WESTERHOFF P， LEENHEER J A，et al. Fluorescence excitation-emission matrix regional integration to quantify spectra for dissolved organic matter［J］. Environmental Science & Technology，2003，37（24）：5701-5710. doi:10.1021/es034354c
17	BAKER A， INVERARITY R， CHARLTON M，et al. Detecting river pollution using fluorescence spectrophotometry：Case studies from the Ouseburn，NE England［J］. Environmental Pollution，2003，124（1）：57-70. doi:10.1016/s0269-7491(02)00408-6
18	YANG Wenlan， LI Xuchun， PAN Bingcai，et al. Effective removal of effluent organic matter（EfOM） from bio-treated coking wastewater by a recyclable aminated hyper-cross-linked polymer［J］. Water Research，2013，47（13）：4730-4738. doi:10.1016/j.watres.2013.05.032
19	PATEL-SORRENTINO N， MOUNIER S， BENAIM J Y. Excitation-emission fluorescence matrix to study pH influence on organic matter fluorescence in the Amazon Basin Rivers［J］. Water Research，2002，36（10）：2571-2581. doi:10.1016/s0043-1354(01)00469-9

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