INDUSTRIAL WATER TREATMENT ›› 2007, Vol. 27 ›› Issue (6): 25-27. doi: 10.11894/1005-829x.2007.27(6).25

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Study on the decolorization efficiency of the dye, acidic black 10B wastewater by Ce4+

Zhai Yongqing, Zhang Shaoyang   

  1. College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China
  • Received:2006-11-10 Online:2007-06-20 Published:2010-10-01

Ce4+对酸性黑10B染料脱色效果研究

翟永清, 张少阳   

  1. 河北大学化学与环境科学学院, 河北 保定 071002
  • 作者简介:翟永清(1970- ) , 2003 年河北大学博士毕业, 教授。电话: 0312- 7553670, E-mail: zhaiyongqinghbu@163.com
  • 基金资助:

    河北省教育厅博士基金资助项目(B2004205)

Abstract:

The decolorizing rate of the dye, acidic black 10B, wastewater with Ce4+ as oxidant has been studied, and the effects of various factors on the decolorizing rate of the dye have been investigated. The results show that the appropriate conditions are as follows: pH=1, Ce( SO4) 2·4H2O 80 mg/L, t = 120 min, illuminated by ultraviolet radiation when the initial concentration of the dye is 10 mg/L. When the reacting time is 120 min, the decolorizing rate can reach about 97%.Therefore, Ce4+ is an effective, economical, safe, nontoxic, environmental benign water treatment reagent. Besides, the investigation shows that the velocity of decolorizing can be greatly enhanced by ultraviolet radiation.

Key words: dye wastewater, ultraviolet radiation, decolorizing rate

摘要:

以Ce4+为氧化剂对酸性黑10B水溶性染料模拟废水进行脱色处理,研究了各种反应条件对脱色率的影响,并且对脱色反应机理进行了分析。结果表明:在染料的初始质量浓度为10 mg/L,pH=1,Ce( SO4) 2·4H2O投加量为80 mg/L,紫外灯光照,反应时间为120 min的条件下,脱色率可达到97%。说明以Ce4+为氧化剂对酸性黑10B水溶性染料具有很好的脱色效果,且脱色速率快,药品用量少,成本低,安全无毒,在废水处理上有较大的应用前景。此外,研究发现:紫外灯照射可大大提高脱色速率,缩短脱色时间。

关键词: 染料废水, 紫外照射, 脱色率

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