INDUSTRIAL WATER TREATMENT ›› 2014, Vol. 34 ›› Issue (6): 17-20. doi: 10.11894/1005-829x.2014.34(6).017

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Preparation of coconut shell-based activated carbon and its kinetics on the adsorption of acidic scarlet GR dye

Jiang Boquan, Zeng Fang, Zeng Qingfang, Chen Jianxin, Liu Yude   

  1. School of Environmental and Chemical Engineering, Nanchang University, Nanchang 330031, China
  • Received:2014-02-12 Online:2014-06-20 Published:2014-07-05

椰壳活性炭的制备及吸附酸性大红GR染料动力学

蒋柏泉, 曾芳, 曾庆芳, 陈建新, 刘玉德   

  1. 南昌大学环境与化学工程学院, 江西南昌 330031
  • 作者简介:蒋柏泉(1949-),教授。电话:13397080986,E-mail:jbq_win@163.com
  • 基金资助:

    国家自然科学基金资助项目(20807020)

Abstract: Coconut shell has been used for the preparation of activated carbon and the adsorption treatment of acidic red GR dye wastewater. By single-factor and response surface experiments, it is ascertained that the optimized technological parameters of the coconut shell-based activated carbon are as follows:liquid-solid ratio is 3.1 mL/g, phosphoric acid mass fraction 66%, activation time 2.5 h and activation temperature 602℃. Under these conditions, the adsorption capacity of the activated carbon for acidic scarlet GR dye is 1682 mg/g. The technological parameters model set up Design-expert 7.0 software are in good agreement with experimental results. SEM indicates that the prepared activated carbon has uniform nano-microporous structure. The adsorption action of the prepared activated carbon for acidic scarlet GR dye complies with pseudo-second order kinetics equation.

Key words: wasted coconut shell, activated carbon, acidic scarlet GR dye, adsorption kinetics

摘要: 采用椰壳制备活性炭吸附处理酸性大红GR染料废水。通过单因素和响应面实验确定了椰壳活性炭制备的最优工艺参数:液固比为3.1 mL/g,磷酸质量分数为66%,活化时间为2.5 h,活化温度为602℃,此条件下制备的活性炭对酸性大红GR染料的吸附容量为1682 mg/g。以Design-expert7.0软件建立的工艺参数模型与实验结果有较好的吻合度。SEM显示,制备的活性炭具有均匀的纳米级微孔结构。制备的活性炭对酸性大红GR染料的吸附行为符合准二级动力学方程。

关键词: 废椰壳, 活性炭, 酸性大红GR染料, 吸附动力学

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