Influential factors of the combined process hydraulic stirring coprecipitation-microfiltration for the treatment of strontium-containing wastewater

doi:10.11894/1005-829x.2014.35(9).028

INDUSTRIAL WATER TREATMENT ›› 2015, Vol. 35 ›› Issue (9): 28-32. doi: 10.11894/1005-829x.2014.35(9).028

Previous Articles Next Articles

Influential factors of the combined process hydraulic stirring coprecipitation-microfiltration for the treatment of strontium-containing wastewater

Niu Hui, Wu Liya, Zhang Guanghui, Gu Ping

School of Environmental Science and Engineering Tianjin University, Tianjin 300072, China

Received:2015-07-12 Online:2015-09-20 Published:2015-09-23

水力搅拌-微滤工艺处理含锶废水的影响因素

牛蕙, 武莉娅, 张光辉, 顾平

天津大学环境科学与工程学院, 天津 300072

通讯作者: 张光辉,E-mail:z_gh@163.com。 E-mail:z_gh@163.com
作者简介:牛蕙(1990-),硕士。E-mail:niuhui@tju.edu.cn。
基金资助:
国家自然科学基金资助项目(51178301)

Abstract

Abstract:

The combined process hydraulic stirring coprecipitation-microfiltration used for the treatment of strontiumcontaining wastewater has been researched. The effects of hydraulic retention time and crystal seed dosage on strontium removal precipitate thickening result and membrane fouling are investigated emphatically. In the research the hydraulic reactor is designed using CaCO₃ as crystal seed and Na₂CO₃ as precipitating agent and adding FeCl₃ as flocculating agent to the membrane separator so as to remove strontium. The results show that the strontium removing effect is affected by the dual influential factors:the dosage of crystal seeds and hydraulic retention time. When the crystal seed dosage is 0.340 g/L and the hydraulic retention time 60 min the average effluent strontium concentration is 7.84 μg/L the average DF reaches 842 and CF reaches 2 790.

Key words: radioactive wastewater, strontium, microfiltration, coprecipitation

摘要：

采用水力搅拌共沉淀-微滤组合工艺处理含锶废水,着重考察水力停留时间和晶种投加量对除锶效果、沉淀物浓缩效果以及膜污染的影响。研究中设计水力反应器,以CaCO₃ 为晶种,Na₂CO₃ 为沉淀剂,膜分离器中投加FeCl₃为絮凝剂,去除废水中的锶元素。结果表明:除锶效果受晶种投加量和水力停留时间的双重作用影响。当晶种投加量为0.340 g/L,水力停留时间为60 min时,出水锶平均质量浓度为7.84 μg/L,平均DF达到842,CF达到2 790。

关键词: 放射性废水, 锶, 微滤, 共沉淀

CLC Number:

X703.1

Niu Hui, Wu Liya, Zhang Guanghui, Gu Ping. Influential factors of the combined process hydraulic stirring coprecipitation-microfiltration for the treatment of strontium-containing wastewater[J]. INDUSTRIAL WATER TREATMENT, 2015, 35(9): 28-32.

牛蕙, 武莉娅, 张光辉, 顾平. 水力搅拌-微滤工艺处理含锶废水的影响因素[J]. 工业水处理, 2015, 35(9): 28-32.

/ / Recommend / Download Citations

URL: https://www.iwt.cn/EN/10.11894/1005-829x.2014.35(9).028

https://www.iwt.cn/EN/Y2015/V35/I9/28

References

[1] 林灿生. 裂变产物元素过程化学[M]. 北京:中国原子能出版社,2012:291.
[2] 日本福岛核电站发现地下水放射性锶[EB/OL]. [2013-06-20]. http:∥news.xinhuanet.com/word/2013-06/20/c_124880605.htm.
[3] Tan Shengheng,Chen Xuegang,Ye Ying,et al. Hydrothermal removal of Sr²⁺ in aqueous solution via formation of Sr-substituted hydroxyapatite[J]. Journal of Hazardous Materials,2010,179(1/2/3):559-563.
[4] Ahmadi S J,Akbari N,Shiri-Yekta Z,et al. Adsorption of strontium ions from aqueous solution using hydrous, amorphous MnO₂-ZrO₂ composite: a new inorganic ion exchanger[J]. Journal of Radioanalytical and Nuclear Chemistry,2014,299(3):1701-1707.
[5] Seliman A F,Lasheen Y F,Youssief M A E,et al. Removal of some radionuclides from contaminated solution using natural clay:bentonite[J]. Journal of Radioanalytical and Nuclear Chemistry,2014, 300(3):969-979.
[6] Weerasekara N A,Choo K H,Choi S J. Metal oxide enhanced microfiltration for the selective removal of Co and Sr ions from nuclear laundry wastewater[J]. Journal of Membrane Science,2013,447 (22):87-95.
[7] Khani M H,Pahlavanzadeh H,Alizadeh K. Biosorption of strontium from aqueous solution by fungus Aspergillus terreus [J]. Environmental Science and Pollution Reasearch International,2012,19(6): 2408-2418.
[8] Luo Xin,Zhang Guanghui,Wang Xue,et al. Research on a pellet coprecipitation micro-filtration process for the treatment of liquid waste containing strontium[J]. Journal of Radioanalytical and Nuclear Chemistry,2013,298(2):931-939.
[9] 黄羽,顾平,张光辉. 机械搅拌-微滤组合工艺处理含锶废水[J]. 中国给水排水,2014,30(15):25-28.
[10] Wu Liya,Zhang Guanghui,Wang Quanzhen,et al. Removal of strontium from liquid waste using a hydraulic pellet co-precipitation microfiltration(HPC-MF) process[J]. Desalination,2014,349(5): 31-38.
[11] 季晓静,顾平,骆欣,等. 机械搅拌造粒法处理含锶废水[J]. 中国给水排水,2012,28(7):32-37.
[12] Rahardianto A,Gao Junbo,Gabelich C J,et al. High recovery membrane desalting of low-salinity brackish water:Integration of accelerated precipitation softening with membrane RO[J]. Journal of Membrane Science,2007,289(1/2):123-137.
[13] Harms W D Jr,Robinson R B. Softening by fluidized bed crystallizers[J]. Journal of Environmental Engineering,2014,118(4): 513-529.

[1]	Wei JIANG, Xiaodie CAI, Xinyu WEN, Sili CHEN, Jinsong WANG, Zhengke ZHANG. Preparation of mesoporous silica/sodium alginate composites and its removal performance of radioactive Sr²⁺ [J]. Industrial Water Treatment, 2025, 45(3): 90-98.
[2]	Weiqiu YANG, Guangyu SHI. Design and operation of wastewater treatment project for lithium battery production [J]. Industrial Water Treatment, 2025, 45(3): 206-211.
[3]	Jiahao ZHENG, Wei JIANG, Sili CHEN, Xiaoying PENG, Jinsong WANG, Zhengke ZHANG. Removal of Sr²⁺ from radioactive wastewater by the composite MnO₂/MCM-41 [J]. Industrial Water Treatment, 2024, 44(2): 105-111.
[4]	Yang YANG, Jianguo TAO, Ruoxia MA, Lin MAO, Ling WU, Yiren ZHOU. Design and experimental study of mobile emergency treatment device for radioactive wastewater [J]. Industrial Water Treatment, 2023, 43(6): 81-85.
[5]	Zhiwei ZENG, Pan WANG, Jingming ZHAN, Xiangming XUE, Yujian DUAN, Jianyu FU. Carbon fiber evaporative curtain enhanced natural evaporation of low-level radioactive wastewater in evaporation pool [J]. Industrial Water Treatment, 2022, 42(10): 160-165.
[6]	Haodi ZHAO, Yufei SHANGGUAN, Shuili YU. Removal of cesium and strontium from water by an integrated device of adsorption-microfiltration using modified permutate as adsorbent [J]. Industrial Water Treatment, 2022, 42(1): 92-99.
[7]	Yuzhu Gong,Maolei Gong,Shaoxin Kang,Huaifu Wang,Bo Liu,Kun Ren. Application of flat ceramic membrane microfiltration technology in coal-containing wastewater treatment system of power plant [J]. Industrial Water Treatment, 2021, 41(6): 262-265.
[8]	Zongzheng YANG,Yaping ZHU,Liya WU,Jiao WANG,Zexun LI,Yue GUO. Research progress of novel composite materials adsorption strontium in radioactive wastewater [J]. Industrial Water Treatment, 2021, 41(12): 7-14.
[9]	Haiyang Li,Guoling Cheng. Removal of humic acid from water by electrocoagulation-membrane reactor [J]. Industrial Water Treatment, 2020, 40(11): 32-35.
[10]	Cai Chen,Xiaoyan Liu,Xiejuan Lu,Yi'nan Wang,Xiaohui Wu. Application of quaternary ammonium salt chitosan in coagulation-microfiltration process [J]. Industrial Water Treatment, 2020, 40(1): 52-55.
[11]	Zhang Wei. Progress in the application of bentonite to the adsorption for inorganic pollutants in water pollution control [J]. INDUSTRIAL WATER TREATMENT, 2018, 38(11): 10-16.
[12]	Li Lili, Chen Hui, Zhang Yexin, Zhang Yajie, Han Lei. Research on the adsorption capacity of nanotube spheres for uranyl ions [J]. INDUSTRIAL WATER TREATMENT, 2017, 37(3): 34-36.
[13]	Li Jun, Liu Xiangxuan, Chai Yun. Influences of calcination temperature on Fe₂O₃ photocatalytic degradation of unsymmetrical dimethylhydrazine wastewater [J]. INDUSTRIAL WATER TREATMENT, 2017, 37(1): 41-44.
[14]	Han Fei, Wang Lijuan, Li Jing, Li Yibing. Study on the treatment of simulated cesium containing wastewater by adsorption-microfiltration coupling process [J]. INDUSTRIAL WATER TREATMENT, 2016, 36(3): 35-39.
[15]	Jia Lin, Liu Yang, Zhang Guanghui, Gu Ping. Research progress in the removal of radioactive iodonucleoid from the water body [J]. INDUSTRIAL WATER TREATMENT, 2015, 35(7): 10-13,18.

Please choose a citation manager

Content to export

Influential factors of the combined process hydraulic stirring coprecipitation-microfiltration for the treatment of strontium-containing wastewater

水力搅拌-微滤工艺处理含锶废水的影响因素

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

模态框（Modal）标题

Please choose a citation manager

Content to export

Influential factors of the combined process hydraulic stirring coprecipitation-microfiltration for the treatment of strontium-containing wastewater

水力搅拌-微滤工艺处理含锶废水的影响因素

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments