Highly efficient adsorption capacity of MIL-53(Fe) metal organic framework material for congo red

doi:10.11894/1005-829x.2017.37(1).006

Abstract

Abstract:

The regular-shaped (triangular pyramid) metal organic framework (MOF) material MIL-53(Fe) has been prepared by a hydro-thermal method, and characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM).Using congo red as model pollutant, the adsorption effect of the prepared MIL-53(Fe) MOF material on congo red is investigated.The results show that the adsorption kinetics of MIL-53(Fe) for congo red complies with pseudo-second-order kine-tics and the adsorption model complies with Langmuir isotherm model.The maximum adsorption capacity of MIL-53(Fe) material for congo red is 1 482 mg/g.It is expected that MIL-53(Fe) MOF can be used as highly efficient adsorption material for removing congo red from dyestuff wastewater.

Key words: metal organic framework material, MIL-53(Fe), adsorption, congo red

摘要：

通过水热法制备规则外形的MIL-53（Fe）金属有机骨架材料（MOF），并通过傅里叶红外光谱（FT-IR）、X射线衍射（XRD）、扫描电镜（SEM）和透射电镜（TEM）对材料进行表征。以刚果红作为目标物，研究所制得的MOF材料对其的吸附行为。结果表明，MIL-53（Fe）对刚果红的吸附动力学符合准二级动力学，吸附模型符合Langmuir吸附模型。MIL-53（Fe）材料对刚果红的最大吸附量为1 482 mg/g，是可望用于去除染料废水刚果红的高效吸附材料。

关键词: 金属有机骨架材料, MIL-53(Fe), 吸附, 刚果红

CLC Number:

X703.1

Xie Jianxin, Chen Wenjing, Wu Yunying, Wu Xianxue, Zhao Qingrui. Highly efficient adsorption capacity of MIL-53(Fe) metal organic framework material for congo red[J]. INDUSTRIAL WATER TREATMENT, 2017, 37(1): 27-30.

谢建新, 陈文静, 吴云英, 伍贤学, 赵庆蕊. MIL-53渊Fe冤金属骨架材料对刚果红的高效吸附[J]. 工业水处理, 2017, 37(1): 27-30.

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https://www.iwt.cn/EN/Y2017/V37/I1/27

References

[1] Dias E M,Petit C. Towards the use of metal-organic frameworks for water reuse:a review of the recent advances in the field of organic po-llutants removal and degradation and the next steps in the field[J]. Journal of Materials Chemistry A,2015,3(45):22484-22506.
[2] 梁琼,汤斌斌,杨胜祥,等. 改性山核桃外果皮炭对碱性染料的吸附特性研究[J]. 工业水处理,2016,36(2):51-54.
[3] Tan K B,Vakili M,Horri B A,et al.Adsorption of dyes by nanoma-terials:Recent developments and adsorption mechanisms[J]. Separa-tion and Purification Technology,2015,150:229-242.
[4] Cui Y,Li B,He H,et al,Metal-organic frameworks as platforms for functional materials[J]. Accounts of Chemical Research,2016,49(3):483-493.
[5] Huo S H,Yan X P.Metal-organic framework MIL-100(Fe) for the adsorption of malachite green from aqueous solution[J]. Journal of Materials Chemistry,2012,22(15):7449-7455.
[6] Ai L,Li L,Zhang C,et al. MIL-53(Fe):A metal-organic framework with intrinsic peroxidase-like catalytic activity for colorimetric bio-sensing[J]. Chemistry-A European Journal,2013,19(45):15105-15108.
[7] 张秀蓉,龚继来,曾光明,等. 磁性氧化石墨烯制备及去除水中刚果红的研究[J]. 中国环境科学,2013,33(8):1379-1385.
[8] Liang X,Zhao L. Room-temperature synthesis of air-stable cobalt nanoparticles and their highly efficient adsorption ability for congo red[J]. Rsc Advances,2012,2(13):5485-5487.
[9] Xu Y,Jin J,Li X,et al. Fabrication of hybrid magnetic HKUST-1 and its highly efficient adsorption performance for congo red dye[J]. Rsc Advances,2015,5(25):19199-19202.
[10] Wang X X,Li Z X,Yu B,et al.Synthesis and characterizations of a bis(triazole)-based 3D crystalline copper(Ⅱ) MOF with high adso-rption capacity for congo red dye[J]. Inorganic Chemistry Comm-unications,2015,54:9-11.
[11] Xiao S L,Li Y H,Ma P J,et al. Synthesis and characterizations of two bis(benzimidazole)-based cobaltous coordination polymers with high adsorption capacity for congo red dye[J]. Inorganic Chemistry Communications,2013,37(6):54-58.
[12] Jin L N,Qian X Y,Wang J G,et al. MIL-68(In) nano-rods for the removal of congo red dye from aqueous solution[J]. Journal of Co-lloid and Interface Science,2015,453:270-275.
[13] Xiao L,Xiong Y,Tian S,et al. One-dimensional coordination supra-molecular polymer[Cu(bipy)(SO₄)]_n as an adsorbent for adso-rption and kinetic separation of anionic dyes[J]. Chemical Engineer-ing Journal,2015,265:157-163.

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