催化臭氧氧化深度处理工业废水的研究及应用

doi:10.11894/1005-829x.2019.39(1).001

摘要/Abstract

摘要： 催化臭氧技术由于能促进臭氧分解产生无选择性的羟基自由基，有效解决难降解有机污染物去除率低的问题，提升废水矿化率和臭氧利用率，已成为当前工业废水深度处理领域的应用研究热点。鉴于工业废水成分复杂、催化剂种类繁多，使得工业废水的催化臭氧化处理的运行效果、控制参数和机理过程存在差异。通过分析目前工业废水催化臭氧化深度处理的相关应用研究，对其影响因素、工艺类型、机理过程进行介绍，总结技术的应用局限性，并对其发展趋势进行展望。

关键词: 催化臭氧化, 工业废水, 深度处理, 催化剂

Abstract: Since catalytic ozonation technology can accelerate ozone decomposition, producing the non-selective hydroxyl radicals,it can effectively promote the degradation of refractory organic pollutants, meanwhile improving the mineralization of wastewater and the utilization of ozone. As a result, catalytic ozonation has attracted a great attention in the field of industrial wastewater treatment. In view of the complex components of industrial wastewater and varieties of reported catalysts, the performance, control parameter and mechanism of this technique are different. By means of analyzing the relevant application research on the catalytic ozonation advanced treatment of industrial wastewater, the influencing factors,process types and mechanism process are introduced in this paper, the application limits of this technology summarized, and the developing trends predicted.

Key words: catalytic ozonation, industrial wastewater, advanced treatment, catalyst

中图分类号:

X703

彭澍晗, 吴德礼. 催化臭氧氧化深度处理工业废水的研究及应用[J]. 工业水处理, 2019, 39(1): 1-7.

Peng Shuhan, Wu Deli. Research on catalytic ozonation and its application to the advanced treatment of industrial wastewater[J]. Industrial Water Treatment, 2019, 39(1): 1-7.

https://www.iwt.cn/CN/Y2019/V39/I1/1

参考文献

[1] Wang Jianlong,Bai Zhiyong. Fe-based catalysts for heterogeneous catalytic ozonation of emerging contaminants in water and wastewater[J]. Chemical Engineering Journal,2017,312:79-98.
[2] 朱秋实,陈进富,姜海洋,等. 臭氧催化氧化机理及其技术研究进展[J]. 化工进展,2014,33(4):1010-1014.
[3] Sanchez-Polo M,Rivera-Utrilla J,von Gunten U. Metal-doped carbon aerogels as catalysts during ozonation processes in aqueous solutions[J]. Water Research,2006,40(18):3375-3384.
[4] Alvarez P M,Garcia-Araya J F,Beltran F J,et al. The influence of various factors on aqueous ozone decomposition by granular activated carbons and the development of a mechanistic approach[J]. Carbon, 2006,44(14):3102-3112.
[5] Faria P C C,Orfao J J M,Pereira M F R. Ozone decomposition in water catalyzed by activated carbon:Influence of chemical and textural properties[J]. Industrial & Engineering Chemistry Research,2006, 45(8):2715-2721.
[6] 刘正乾,胡文斐,杨文花,等. 活性炭催化臭氧氧化水中有机污染物的研究进展[J]. 中国给水排水,2010,26(4):6-9.
[7] 李超,杨彩娟,韦惠民,等. 催化臭氧氧化法处理抗生素废水生化出水[J]. 化工环保,2017,37(1):79-82.
[8] 周洁,徐军,涂勇,等. 催化强化臭氧氧化处理化工园区生化尾水[J]. 环境工程学报,2016,10(3):1081-1086.
[9] Trapido M,Veressinina Y,Munter R,et al. Catalytic ozonation of m-dinitrobenzene[J]. Ozone:Science & Engineering,2005,27(5):359-363.
[10] Sauleda R,Brillas E. Mineralization of aniline and 4-chlorophenol in acidic solution by ozonation catalyzed with Fe²⁺ and UVA light[J]. Applied Catalysis B Environmental,2001,29(2):135-145.
[11] Andreozzi R,Caprio V,Insola A,et al. The ozonation of pyruvic acid in aqueous solutions catalyzed by suspended and dissolved manganese[J]. Water Research,1998,32(5):1492-1496.
[12] Von Gunten U. Ozonation of drinking water:Part I. oxidation kinetics and product formation[J]. Water Research,2003,37(7):1443-1467.
[13] Huang Xianfeng,Xie Bihuang,Li Xuchun,et al. Enhanced HO·production from ozonation activated by EDTA[J]. Chemical Engineering Journal,2016,288:562-568.
[14] Staehelin J,Hoigne J. Decomposition of ozone in water:Rate of initiation by hydroxide ions and hydrogen peroxide[J]. Environmental Science & Technology,1982,16(10):676-681.
[15] Pines D S,Reckhow D A. Effect of dissolved cobalt(Ⅱ) on the ozonation of oxalic azcid[J]. Environmental Science & Technology, 2002,36(19):4046.
[16] 胡俊生,任雪冬,马广韬,等. 臭氧高级氧化技术处理酸性红B染料废水[J]. 沈阳建筑大学学报(自然科学版),2009,25(2):320-324.
[17] Grzechulska J,Hamerski M,Morawski A W. Photocatalytic decomposition of oil in water[J]. Water Research,2000,34(5):1638-1644.
[18] 李贞燕,陈冰.·OH对光催化臭氧降解油田采出水中多环芳烃影响的研究[J]. 水处理技术,2015(1):77-80.
[19] 冯玥,石文静,谭德俊,等. 活性炭催化臭氧氧化处理染料废水生化出水研究[J]. 环境科学学报,2013,33(10):2724-2729.
[20] Tamura H,Tanaka A,Mita K Y,et al. Surface hydroxyl site densities on metal oxides as a measure for the ion-exchange capacity[J]. Journal of Colloid and Interface Science,1999,209(1):225-231.
[21] Lü A,Hu C,Nie Y,et al. Catalytic ozonation of toxic pollutants over magnetic cobalt-doped Fe₃O₄ suspensions[J]. Applied Catalysis B Environmental,2012,117/118(1):246-252.
[22] Zhang T,Ma J. Catalytic ozonation of trace nitrobenzene in water with synthetic goethite[J]. Journal of Molecular Catalysis A Chemical,2008,279(1):82-89.
[23] Qi Fei,Chen Zhonglin,Xu Bingbing,et al. Influence of surface texture and acid-base properties on ozone decomposition catalyzed by aluminum(hydroxyl) oxides[J]. Applied Catalysis B:Environmental,2008,84(3/4):684-690.
[24] Dong Y,Yang H,He K,et al. β-MnO₂ nanowires:A novel ozonation catalyst for water treatment[J]. Applied Catalysis B:Environmental, 2009,85(3):155-161.
[25] 陆洪宇,马文成,张梁,等. 臭氧催化氧化工艺深度处理印染废水[J]. 环境工程学报,2013,7(8):2873-2876.
[26] 何帅明,莫立焕,徐峻,等. 活性炭负载铈催化臭氧处理桉木制浆废水[J]. 中国造纸,2016,35(3):1-6.
[27] Sanchez-Polo M,Gunten U V,Rivera-Utrilla J. Efficiency of activated carbon to transform ozone into·OH radicals:Influence of operational parameters[J]. Water Research,2005,39(14):3189-3198.
[28] Andreozzi R,Insola A,Caprio V,et al. The use of manganese dioxide as a heterogeneous catalyst for oxalic acid ozonation in aqueous solution[J]. Applied Catalysis A General,1996,138(1):75-81.
[29] Beltr N F J,Rivas F J,Montero-de-Espinosa R. A TiO/AlO catalyst to improve the ozonation of oxalic acid in water[J]. Applied Catalysis B Environmental,2004,47(2):101-109.
[30] 庄海峰,韩洪军,单胜道. 污泥基催化剂强化臭氧深度处理煤制气废水中试性能[J]. 哈尔滨工业大学学报,2017,49(2):85-91.
[31] 黎兆中,汪晓军. 臭氧催化氧化深度处理印染废水的效能与成本[J]. 净水技术,2014(6):89-92.
[32] 李立春,张国亮,许丹宇,等. Fenton/MBR/臭氧组合工艺处理丁苯橡胶废水[J]. 中国给水排水,2017(2):87-89.
[33] 钟震,陈建军,张柯. 石化含盐污水深度处理中试研究[J]. 安徽农业科学,2014(22):7571-7573.
[34] 陈中英. 高负荷下臭氧催化氧化深度处理丙烯腈废水运行特性[J]. 工业水处理,2015,35(8):104-106.
[35] 陈莉,周鹏飞,刘洋,等. 电磁催化臭氧氧化在难降解废水升级改造中的应用[J]. 水处理技术,2017(6):120-122.
[36] 边靖,卫佳,李彤,等. 甘泉堡工业园区污水处理工程设计与运行[J]. 中国给水排水,2016(12):85-89.
[37] 李文国,战树岩,刘佩春. 电磁(EM)催化高级氧化用于桥东污水处理厂升级改造[J]. 中国给水排水,2014(10):89-91.
[38] 白小霞,杨庆,丁昀,等. 催化臭氧氧化处理难降解石化废水技术的研究进展[J]. 化工进展,2016,35(1):263-268.
[39] 耿长君,蒲文晶,高薇,等. 臭氧催化氧化法处理污水厂二级出水的中试研究[J]. 化工科技,2016,24(2):44-46.
[40] 苏长春,方健. COBR工艺在含聚污水处理中的应用研究[J]. 工业水处理,2017,37(6):107-109.
[41] 王松,于忠臣,张雪娇,等. Fe²⁺/UV催化臭氧-曝气生物滤池降解腈纶废水研究[J]. 化学通报,2014,77(6):568-572.
[42] Nawrocki J,Kasprzyk-hordern B. The efficiency and mechanisms of catalytic ozonation[J]. Applied Catalysis B:Environmental,2010, 99(1/2):27-42.
[43] 莫立焕,谈金强,王聪聪,等. γ-Al₂O₃催化臭氧深度处理蔗渣制浆废水[J]. 华南理工大学学报(自然科学版),2017,45(2):144-152.
[44] Sui Minghao,Sheng Li,Lu Kexiang,et al. FeOOH catalytic ozonation of oxalic acid and the effect of phosphate binding on its catalytic activity[J]. Applied Catalysis B Environmental,2010,96(1/2):94-100.
[45] 张悦,王兵,任宏洋,等. O₃/Mn₂O₃对钻井废水多相催化臭氧化试验研究[J]. 环境科学学报,2015,35(10):3185-3192.
[46] 金鹏康,贺栋,刘岚,等. 玉裂废水黏度对二氧化锰臭氧催化氧化处理特性的影响[J]. 环境工程学报,2013,7(10):3719-3724.
[47] 武倩,涂勇,徐军,等. 改性活性炭催化臭氧深度处理化工废水的研究[J]. 环境保护科学,2016,42(5):81-85.
[48] 刘玉川,杨刚. TiO₂/AC催化臭氧降解造纸废水[J]. 南京工业大学学报(自然科学版),2017,39(2):31-38.
[49] 李来胜,谢燕华,潘兆琪,等. Ce-MCM-41分子筛催化臭氧氧化水中腐殖酸[J]. 华南师范大学学报(自然科学版),2017,49(2):73-79.
[50] 代莎莎,毛风华. MnOx-GAC催化臭氧化印染废水的实验研究[J]. 水科学与工程技术,2016(5):83-86.
[51] 董淑福. 多相催化臭氧氧化法处理印染废水的研究[J]. 工业水处理,2013,33(4):58-60.
[52] Wu J,Ma L,Zha X,et al. Catalytic ozonation of organic pollutants from bio-treated dyeing and finishing wastewater using recycled waste iron shavings as a catalyst:Removal and pathways[J]. Water Research,2016,92:140-148.
[53] 吴俊,罗丹,全学军. 臭氧催化剂的制备及其应用研究进展[J]. 化工进展,2017,36(3):944-950.
[54] 于忠臣,张雪娇,王松,等. Fe²⁺-Al³⁺紫外催化臭氧法降解腈纶废水研究[J]. 高校化学工程学报,2015(2):465-470.
[55] 韩洪军,庄海峰,赵茜,等. 非均相催化臭氧处理煤化工生化出水[J]. 哈尔滨工业大学学报,2014,46(6):50-54.
[56] Huang X,Xu Y,Shan C,et al. Coupled Cu(Ⅱ)-EDTA degradation and Cu(Ⅱ) removal from acidic wastewater by ozonation:Performance,products and pathways[J]. Chemical Engineering Journal, 2016,299:23-29.
[57] Huang X,Li X,Pan B,et al. Self-enhanced ozonation of benzoic acid at acidic pHs[J]. Water Research,2015,73:9-16.
[58] Buffle M O,von Gunten U. Phenols and amine induced HO·generation during the initial phase of natural water ozonation[J]. Environmental Science & Technology,2006,40(9):3057.
[59] 刘永泽,江进,马军,等. 臭氧氧化过程中羟基自由基产率测定与分析[J]. 哈尔滨工业大学学报,2015,47(2):9-12.
[60] Yang J,Li J,Dong W,et al. Study on enhanced degradation of atrazine by ozonation in the presence of hydroxylamine[J]. Journal Hazardous Materials,2016,316:110-121.
[61] 金鹏康,韩冬,金鑫,等. 多级臭氧气浮一体化装置对污水厂出水的处理效果[J]. 中国给水排水,2015(15):12-15.

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