工业水处理 ›› 2020, Vol. 40 ›› Issue (3): 89-93. doi: 10.11894/iwt.2019-0238

• 试验研究 • 上一篇    下一篇

Fe3O4/MnO2纳米复合材料光催化深度处理造纸废水

杜杨柳1,2(),贾少武1,2,兰蕾1,2,李富强1,2,彭叶灿1,2,周敬红1,2,王双飞1,2   

  1. 1. 广西大学轻工与食品工程学院, 广西南宁 530004
    2. 广西壮族自治区清洁化制浆造纸及污染控制重点实验室, 广西南宁 530004
  • 收稿日期:2019-12-26 出版日期:2020-03-20 发布日期:2020-03-20
  • 作者简介:杜杨柳(1993—),在读硕士。电话:15877186763, E-mail:dylhardwork@163.com

Advanced treatment of paper-making wastewater by photocatalysis with Fe3O4/MnO2 nanocomposites

Yangliu Du1,2(),Shaowu Jia1,2,Lei Lan1,2,Fuqiang Li1,2,Yecan Peng1,2,Jinghong Zhou1,2,Shuangfei Wang1,2   

  1. 1. College of Light Industry and Food Engineering, Guangxi University, Nanning 530004, China
    2. Guangxi Key Laboratory of Clean Pulp&Papermaking and Pollution Control, Nanning 530004, China
  • Received:2019-12-26 Online:2020-03-20 Published:2020-03-20

摘要:

采用水热法和共沉淀法制备磁性纳米Fe3O4/MnO2复合材料并作为光催化剂使用,运用XRD、FESEM、VSM等手段对该光催化剂进行表征,并将其用于光催化处理造纸废水生化出水。研究了催化剂的投加量、反应初始pH等因素对废水深度处理效率的影响。实验结果表明,在优化条件下,造纸废水CODCr的去除率可达57.67%,出水CODCr为50.84 mg/L。该光催化剂具备一定的可循环性,可以作为一种新型的非均相光催化剂用于造纸废水生化出水的深度处理。

关键词: 造纸废水, 磁性催化剂, 光催化, 深度处理

Abstract:

Magnetic Fe3O4/MnO2 nanocomposite photocatalysts were prepared by hydrothermal method and coprecipitation process. The photocatalysts were characterized by means of XRD, FESEM and VSM, and then used to treat the biochemical effluent of paper-making wastewater. The effects of catalyst dosage and initial pH on the efficiency of wastewater treatment were studied. The experimental results showed that under the optimal conditions, the removal efficiency of CODCr in paper-making wastewater could reach 57.67%, and CODCr in the effluent was 50.84 mg/L. The photocatalyst has certain recyclability and can be used as a new heterogeneous photocatalyst for the advanced treatment of paper-making wastewater.

Key words: paper-making wastewater, magnetic catalyst, photocatalytic, advanced treatment

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