工业水处理 ›› 2006, Vol. 26 ›› Issue (12): 34-37. doi: 10.11894/1005-829x.2006.26(12).34

• 试验研究 • 上一篇    下一篇

自然有机物对地下水混凝除铁的影响试验研究

马满英1,2, 施周1, 余健1, 刘有势2   

  1. 1. 湖南大学土木工程学院, 湖南长沙 410082;
    2. 湖南工业大学科技学院, 湖南株洲 412011
  • 收稿日期:2006-07-13 出版日期:2006-12-20 发布日期:2010-10-01
  • 作者简介:马满英(1967- ),湖南大学市政工程专业博士生,湖南工业大学副教授,研究方向为水质净化和水污染控制。

Research on the impact of natural organic matter on coagulation removal of iron from groundwater

Ma Manying1,2, Shi Zhou1, Yu Jian1, Liu Youshi2   

  1. 1. College of Civil Engineering, Hunan University, Changsha 410082, China;
    2. College of Science and Technology, Hunan Polytechnic University, Zhuzhou 412011, China
  • Received:2006-07-13 Online:2006-12-20 Published:2010-10-01

摘要:

通过模拟试验,考察了自然有机物的浓度、分子质量以及溶液的pH、温度对地下水混凝除铁的影响,并研究了预氧化在混凝除铁中的作用。结果表明,有机物的浓度越高、分子质量越大,有机铁的去除率越高。当Fe2+与分子质量>10 ku的有机物络合时,用混凝除铁能取得良好的效果;当Fe2+与分子质量<4 ku的有机物络合时,采用预氧化混凝工艺能达到较好的除铁效果。在pH6.0~7.5的范围内,降低pH有利于混凝除铁。温度升高对混凝除铁有利。

关键词: 自然有机物, 除铁, 混凝

Abstract:

By simulating experiments, the effects of the molecular weight and the concentration of natural organic matter on coagulation removal of iron fromgroundwater have been investigated, and some impact factors such as pH, solution temperature on them have been studied. The action of pre-oxidation on coagulation removal of iron has been studied as well. The experiments showthat the removal of iron increases with the increasing of the molecular weight and the concentration of organic matter. Alum coagulation is very effective on the removal of iron(Ⅱ)complexed by organic matter with molecular weight greater than 10 000 u. Iron(Ⅱ)complexed by organics with molecular weight less than 4 000 u is amenable to be removed by pre-oxidation followed by alum coagulation. pH value decreasing is beneficial to coagulation removal of complexed iron over the pH range from 6.0 to 7.5. When solution temperature increases, removal efficiency of complexed iron also increases.

Key words: natural organic matter, iron removal, coagulation

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