工业水处理 ›› 2007, Vol. 27 ›› Issue (6): 61-63. doi: 10.11894/1005-829x.2007.27(6).61

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用于稠油污水处理的高效反相破乳剂的合成

赵林1, 陈英毅2, 李玉娇3, 马超1   

  1. 1. 长江大学石油工程学院油气采钻省重点实验室, 湖北 荆州 434023;
    2. 中石化华北石油局录井公司, 河南 郑州 450006;
    3. 中石油塔里木油田公司勘探开发研究院, 新疆 库尔勒 841000
  • 收稿日期:2007-03-25 修回日期:2007-03-25 出版日期:2007-06-20 发布日期:2010-10-01
  • 作者简介:赵林(1963- ) , 2006 年毕业于四川大学, 博士, 教授。电话: 13907216105
  • 基金资助:

    国家科技部项目(2004BA610A10)

Synthesis of invert-demulsifying agent for dealing with the heavy oil wastewater

Zhao Lin1, Chen Yingyi2, Li Yujiao3, Ma Chao1   

  1. 1. Province Key Lab of Drillng & Exploration of Oil and Gas Engineering, Petroleum Engineering College of Yangtze University, Jingzhou 434023, China;
    2. Logging Company of North China Petroleum, Zhengzhou 450006, China;
    3. Exploration & Development Research Institute of Talimu Oil field Co. , Kuerle 841000, China
  • Received:2007-03-25 Revised:2007-03-25 Online:2007-06-20 Published:2010-10-01

摘要:

稠油污水乳化严重,水质复杂,破乳处理是稠油污水处理中的关键环节。在分析辽河欢四联稠油污水特点的基础上采用环氧氯丙烷、二甲胺和交联剂乙二胺合成了一种聚阳离子季铵盐型反相破乳剂HEY-M,该破乳剂具有强的压缩双电层和击破界面膜作用。HEY-M破乳剂除油效率<96%,是一种高效稠油污水反相破乳剂。

关键词: 稠油污水, 反相破乳, 阳离子聚合物

Abstract:

For the serious situation of heavy oil wastewater emulsification and the high complication of the wastewater quality, the treatment of emulsion has been the key link to deal with heavy oil sewage. It has used epichlorohydrin, dimethylamine and ethylenediamine to synthesize invert-demulsifying agent HEY- M. It is a kind of cationic quaternary ammonium polymer. It has condensed double electrode layer and can break the interface film. It is a highly effective invert-demulsifying agents and its efficiency of oil removal can be up to 96%.

Key words: heavy oil wastewater, invert-demulsion, cationic polymer

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