工业水处理 ›› 2007, Vol. 27 ›› Issue (9): 42-44. doi: 10.11894/1005-829x.2007.27(9).42

• 试验研究 • 上一篇    下一篇

复合催化氧化法处理PTA废水的研究

张跃1, 何淑芹2, 刘建武1, 严生虎1, 沈介发1   

  1. 1. 江苏工业学院精细化工研究所, 江苏 常州 213164;
    2. 中国石油吉林石化公司科技规划处, 吉林市 132021
  • 收稿日期:2007-03-30 修回日期:2007-03-30 出版日期:2007-09-20 发布日期:2010-10-01
  • 作者简介:张跃(1964- ),南京工业大学博士,副研究员,江苏工业学院科技处副处长,发表论文数篇,电话:0519-6330178,E-mail:liujianwu112@163.com

Study on the treatment of PTA wastewater by complex catalytic oxidation

Zhang Yue1, He Shuqin2, Liu Jianwu1, Yan Shenghu1, Shen Jiefa1   

  1. 1. The Research Institute of Fine Chemical Engineering, Jiangsu Polytechnic University, Changzhou 213164, China;
    2. Department of Science and Technology, Jilin Petrochemical Company of PetroChina, Jilin 132021, China
  • Received:2007-03-30 Revised:2007-03-30 Online:2007-09-20 Published:2010-10-01

摘要:

叙述了PTA废水国内外处理技术的现状。试验研究了复合催化氧化法处理PTA废水的效果,系统地考察了pH、反应时间和氧化剂投加量对COD、色度去除率的影响,优化了废水处理的操作条件,最终以较低的成本和方便的操作将PTA混合污水的COD降至420mg/L左右,进一步用生物降解系统进行处理可使其COD降至150mg/L以下。本方法操作简单,工艺流程合理,处理效果好,可操作性强,环境友好。

关键词: 对苯二甲酸, 催化, 氧化, 废水处理

Abstract:

The technical situations of PTA wastewater treatment in China and overseas are described. The influential factors, such as pH, reaction time and the dosage of oxidizing agent, on the removal rates of chroma and COD have been investigated systematically. The operation conditions of the wastewater treatment are optimized through experiments. The CODCr of the PTA water has finally been reduced to 420 mg/L with lower cost and convenient operation. Then, the water goes to the biodegradation system, being treated for lowering its COD to less than 150 mg/L. This method has some merits, including convenient operation, reasonable technical process, ideal treatment effect, operable conditions and friendly environment.

Key words: terephthalic acid, catalysis, oxidation, wastewater treatment

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