工业水处理 ›› 2009, Vol. 29 ›› Issue (11): 56-58. doi: 10.11894/1005-829x.2009.29(11).56

• 试验研究 • 上一篇    下一篇

A/O—混凝工艺处理氰酚废水的研究

张晓辉1,2, 皮科武3, 胡林2, 崔建宇2, 曹奇光1   

  1. 1. 北京电子科技职业学院生物系, 北京 100029;
    2. 中国农业大学资源与环境学院, 北京 100094;
    3. 湖北工业大学化学与环境工程学院, 湖北武汉 430068
  • 收稿日期:2009-07-20 出版日期:2009-11-20 发布日期:2010-10-01
  • 作者简介:张晓辉(1980- ),2004年毕业于武汉理工大学,博士。电话:13717698464,E-mail:zxh11218@sina.com。
  • 基金资助:

    北京电子科技职业学院自然科学基金(08KK007);北京市职业院校教师素质提高工程项目

Study on the treatment of phenol and cyanide wastewater by A/O-flocculation process

Zhang Xiaohui1,2, Pi Kewu3, Hu Lin2, Cui Jianyu2, Cao Qiguang1   

  1. 1. Department of Biotechnology, Beijing Vocational College of Electronic Science,Beijing 100029, China;
    2. College of Resource and Environmental Sciences, China Agricultural University,Beijing 100094, China;
    3. School of Chemical and Environmental Engineering, Hubei University of Technology, Wuhan 430068, China
  • Received:2009-07-20 Online:2009-11-20 Published:2010-10-01

摘要:

采用后继混凝沉淀的A/O工艺对含酚、氰的焦化废水进行了处理,运行结果表明:废水中酚质量浓度从287~681mg/L降至1.0mg/L以下,氰化物质量浓度从0.72~11.4mg/L降至0.5mg/L以下,完全达到了《污水综合排放标准》(GB8978—1996)的二级排放标准;CODCr从3879~6378mg/L降至116.1~184.2mg/L,氨氮从145.6~200mg/L降至11.64~25.26mg/L,大多数时间达到排放标准。

关键词: 氰酚废水, 好氧工艺, 厌氧工艺, 混凝

Abstract:

Steel pickling waste has been treated by using a 5 L airlift membrane reactor which couples with a 19-channel porcelain membrane element.The results show that when the aeration volume is in the range of 0.5-2.5 m3/h,membrane flux can be maintained above 60 L/(m2·h).In addition,increasing the aeration amount is good for increasingthe circulating liquid flux.Under stable operating conditions,the suspended solids concentration of ferrichydroxide in liquid,temperature(1-45 ℃) and operation pressure(0.025-0.1 MPa) show a linear relationship withmembrane flux.Under the following conditions: Fe2+ mass concentration is 400 mg/L of pickling liquid waste,dissolvedoxygen 70%,pressure difference 0.1 MPa,room temperature 18-25℃,pH 6-9,and the hydraulic retentiontime 2 h,the turbidity of effluent water is <2 NTU,pH accords with the national discharge standards.

Key words: phenol and cyanide wastewater, aerobic process, anoxic process, flocculation

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