工业水处理 ›› 2014, Vol. 34 ›› Issue (2): 90-92. doi: 10.11894/1005-829x.2014.34(2).090

• 经验交流 • 上一篇    

碱性高浓度有机废水综合处理及工程应用

王国平1,2, 王宏1, 汪贤玉1, 周转忠1,2, 钱雪明1, 马建明3   

  1. 1. 浙江大洋生物科技集团股份有限公司, 浙江杭州 311616;
    2. 浙江大化浙大生物药物研发中心, 浙江杭州 311616;
    3. 浙江大洋化工股份有限公司质监部, 浙江杭州 311616
  • 收稿日期:2013-11-25 出版日期:2014-02-20 发布日期:2014-02-24
  • 作者简介:王国平(1974-),工程师。电话:086-571-64156863,E-mail:yuiop380@sina.com

Integrated treatment of alkaline highly-concentrated organic wastewater and its engineering application

Wang Guoping1,2, Wang Hong1, Wang Xianyu1, Zhou Zhuanzhong1,2, Qian Xueming1, Ma Jianming3   

  1. 1. Zhejiang Dayang Biotechnology Co., Ltd., Hangzhou 311616, China;
    2. Zhejiang Dahua Zhejiang University Biomedicament R & D Center, Hangzhou 311616, China;
    3. Quality Inspection Department of Zhejiang Dayang Chemical Co., Ltd., Hangzhou 311616, China
  • Received:2013-11-25 Online:2014-02-20 Published:2014-02-24

摘要:

盐酸氨丙啉碱性高浓度有机废水含有大量氯化钠、氢氧化钠、嘧啶类杂环化合物、甲醇、氯仿和其他未知有机物,常规的生化治理成本高且效果差。采用中和+低温沉降+树脂吸附+蒸发浓缩的技术路线可对该废水进行有效治理,所得氯化钠符合工业盐要求,蒸发冷凝水可返回车间作为工艺用水回用。经工程验证,该工艺处理成本约为256元/m3,仅为常规方法的20%,具有很好的经济和社会效益。

关键词: 盐酸氨丙啉, 高浓度有机废水, 大孔吸附树脂, 综合治理

Abstract:

Amprolium hydrochloride alkaline highly-concentrated organic wastewater contains a lot of sodium chloride, sodium hydroxide, heterocyclic pyrimidine compounds, methanol, chloroform and other unknown organic compounds. The costs of its conventional biochemical treatment used to be high, and the efficacy was poor. The neutralization+low-temperature settlement+resin adsorption+evaporation condensation process has been used for efficiently treating the wastewater. The sodium chloride obtained meets the industrial salt requirements. The evaporated condensate returned to the workshop can be reused as process water. The verified engineering result indicates that the costs of treatment are about CNY 256/m3, being only 20% of that by conventional method. This technique has good economic and social benefits.

Key words: amprolium hydrochloride, highly-concentrated organic wastewater, macroporous adsorptive resin, integrated treatment

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