工业水处理 ›› 2016, Vol. 36 ›› Issue (12): 90-93. doi: 10.11894/1005-829x.2016.36(12).022

• 试验研究 • 上一篇    下一篇

电解催化氧化法处理含酚废水技术及机理研究

滕厚开, 谢陈鑫   

  1. 中海油天津化工研究设计院有限公司, 天津 300131
  • 收稿日期:2016-11-21 出版日期:2016-12-20 发布日期:2016-12-26
  • 作者简介:滕厚开(1963-),教授级高工,硕士生导师。E-mail:tenghk@cnooc.com.cn。

Research on the technology and mechanism of electrolytic catalysis oxidation method for treating phenol-containing wastewater

Teng Houkai, Xie Chenxin   

  1. CenerTech Tianjin Chemical Research & Design Institute Co., Ltd., Tianjin 300131, China
  • Received:2016-11-21 Online:2016-12-20 Published:2016-12-26

摘要:

以聚合前驱体方法制备了Ti/SnO2平板电极,用SEM和XRD表征了电极表面涂层形貌及结构。以自制Ti/SnO2电极为阳极,电解催化氧化法处理100 mg/L的含酚废水,试验表明电催化系统能够产生羟基自由基,自制Ti/SnO2电极具有良好的催化活性和使用寿命。当电流密度为0.01 A/cm2、极板间距为14 mm、初始pH为4,电解催化时间50 min后,出水苯酚去除率几乎为100%。

关键词: Ti/SnO2, 电解催化, 苯酚

Abstract:

The Ti/SnO2 plate electrode has been prepared by polymeric precursor process. The surface coatingsform and structure of the electrode are characterized by scanning electron microscope(SEM) and X-Ray Diffraction (XRD),respectively. The results show that the homemade Ti/SnO2 electrode has good catalytic activity and service life. Using this homemade Ti/SnO2 electrode as anode,the results of tests show that the electrolytic catalysis system can produce ·HO. 100 mg/L of phenol-containing wastewater is to be treated,when the current density is 0.01 A/cm2,plate spacing 14 mm,initial pH 4,and electrolysis catalysis time 50 min,the effluent phenol removing rate is almost 100%.

Key words: Ti/SnO2, electro-catalysis, phenol

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