工业水处理 ›› 2016, Vol. 36 ›› Issue (2): 90-93. doi: 10.11894/1005-829x.2016.36(2).090

• 分析与监测 • 上一篇    下一篇

盐析效应对水中油含量测定影响的研究

李国轲1, 高肖汉1,2, 王兴旺3, 焦玉娟1, 罗冠华1, 吕雪川1, 范志平2   

  1. 1. 辽宁石油化工大学化学化工与环境学部化学与材料学院, 辽宁抚顺 113001;
    2. 辽宁石油化工大学化学化工与环境学部生态环境研究院, 辽宁抚顺 113001;
    3. 中国石油工程设计有限公司北京分公司油田化学部, 北京 100083
  • 收稿日期:2015-10-16 出版日期:2016-02-20 发布日期:2016-02-26
  • 通讯作者: 高肖汉,E-mail:gaoxhan@163.com。 E-mail:gaoxhan@163.com
  • 作者简介:李国轲(1988-),硕士。电话:18741391583,E-mail:guokelongyan@126.com。
  • 基金资助:

    国家自然科学基金项目(21003069;21103078);辽宁石油化工大学环境科学与工程学科创新团队资助项目([2014]11号)

Study on the influences of the salting out effect on the determination of oil content in water

Li Guoke1, Gao Xiaohan1,2, Wang Xingwang3, Jiao Yujuan1, Luo Guanhua1, Lü Xuechuan1, Fan Zhiping2   

  1. 1. School of Chemistry and Material Science, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning University of Petroleum Chemical Technology, Fushun 113001, China;
    2. Institute of Ecological Environment, College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning University of Petroleum Chemical Technology, Fushun 113001, China;
    3. Department of Oilfield Chemistry, Beijing Company, China Petroleum Engineering Co., Ltd., Beijing 100083, China
  • Received:2015-10-16 Online:2016-02-20 Published:2016-02-26

摘要:

用环己烷、环己烯和苯分别配制3种类型的模拟水样,采用四氯化碳萃取红外分光光度法测定水中的油含量,研究了盐析效应对饱和烃、不饱和烃与芳香烃含量测定的影响。结果表明,盐析效应对饱和烃含量测定的影响非常小,而对不饱和烃与芳香烃含量测定的影响比较大。在此基础上研究了盐析效应对石化废水和油田废水中油含量测定的影响。

关键词: 红外分光光度法, 氯化钠, 盐析效应, 萃取, 油含量

Abstract:

Three types of simulated water samples have been prepared with cyclohexane,cyclohexene,and benzene. The oil content in water has been extracted with carbon tetrachloride and determined by infrared spectrophotometry. The influences of salting out effect on the content determination of saturated hydrocarbon,unsaturated hydrocarbon and aromatic hydrocarbon are studied. The results show that the salting out effect has little influence on the content determination of saturated hydrocarbon,but has greater influence on the content determination of unsaturated hydro-carbon and aromatic hydrocarbon. Based on this,the influence of the salting out effect on the oil content determina-tion of wastewater from petrochemical plants and oilfields are studied.

Key words: infrared spectrophotometry, sodium chloride, salting out effect, extraction, oil content

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