BDD电极在难降解废水处理中的应用研究进展

doi:10.11894/1005-829x.2017.37(11).011

摘要/Abstract

摘要： 介绍了BDD电极的电化学特性、氧化机理及制备技术。重点总结了BDD电极在酚类、染料、农药、医药等难降解模拟废水和垃圾渗滤液、印染、制药、城镇污水处理厂出水等实际废水中的应用研究进展。提出开发大面积BDD电极制备技术，提高电极电催化性能和稳定性，增强基底附着力，开发组合工艺技术是未来BDD电极实现工业化应用的研究方向。

关键词: 掺硼金刚石(BDD)电极, 电化学高级氧化法, 难降解废水

Abstract: The electrochemical characteristics,oxidation mechanism and preparation technology of boron-doped diamond(BDD) electrode are introduced. The research progress in the application of BDD electrode to the treatment of simulated refractory wastewater in industries,such as phenols,dyes,pesticides and pharmacy,and effluent from landfill leachates,printing and dyeing,pharmacy and urban sewage treatment plants are summarized emphatically. It is proposed that developing large area BDD electrodes preparation technology,improving electrode electro-catalytic performance and stability,enhancing electrode substrate adhesion,and developing combined process techniques are the research direction for BDD electrodes to achieve industrial application.

Key words: boron doped diamond(BDD) electrode, electrochemical advanced oxidation method(EAOP), refractory wastewater

中图分类号:

X703.1

石艳玲, 姚迎迎, 黄思远. BDD电极在难降解废水处理中的应用研究进展[J]. 工业水处理, 2017, 37(11): 11-16.

Shi Yanling, Yao Yingying, Huang Siyuan. Research progress in the application of BDD electrode to refractory wastewater treatment[J]. INDUSTRIAL WATER TREATMENT, 2017, 37(11): 11-16.

https://www.iwt.cn/CN/Y2017/V37/I11/11

参考文献

[1] 张翼,张荣庆,马静,等.BDD电极电化学高级氧化技术用于有机废水的处理[J].中国给水排水,2006,22(24):15-18.
[2] Fryda M,Matthée T H,Mulcahy S,et al.Fabrication and application of Diachem^® electrodes[J].Diamond and Related Materials,2003,12:1950-1956.
[3] 刘峰斌,汪家道,刘兵,等.掺硼金刚石薄膜的电化学性能[J].功能材料与器件学报,2005,11(3):295-298.
[4] Pleskov Y V,Krotova M D,Elkin V V,et al.Electrochemical behaviour of boron-doped diamond compacts:A new electrode material[J].Electrochimica Acta,2016,201:268-273.
[5] 赵国华,李明利,吴薇薇,等.金刚石膜电极对有机污染物的电催化特性[J].环境科学,2004,25(5):163-167.
[6] Luong J H,Male K B,Glennon J D.Boron-doped diamond electrode:synthesis,characterization,functionalization and analytical applications[J].Analyst,2009,134(10):1965-1979.
[7] 胡晓君,曹华珍,郑国渠,等.掺硼浓度对金刚石薄膜电极电化学性能影响的研究[J].高校化学工程学报,2006,20(6):932-937.
[8] Doi T,Fukaishi T,Hiramatsu C,et al.Effectiveness of a hot-filament chemical vapor deposition method for preparation of a borondoped superconducting diamond film with higher superconducting transition temperature[J].Diamond and Related Materials,2012,25(1):5-7.
[9] 梅倩,赵斌元,李荣斌,等.类金刚石薄膜的气相沉积新型工艺发展[J].材料导报,2014,28(23):94-99.
[10] Liang Qi,Yan C S,Meng Yufei,et al.Recent advances in highgrowth rate single-crystal CVD diamond[J].Diamond and related Materials,2009,18(5/6/7/8):698-703.
[11] 阳硕,满卫东,赵彦君,等.MPCVD法合成单晶金刚石的研究及应用进展[J].真空与低温,2015,21(3):131-136.
[12] Bai Yizhen,Jin Zengsun,Lv Xianyi,et al.Influence of cathode temperature on gas discharge and growth of diamond films in DCPCVD processing[J].Diamond and Related Materials,2005,14(9):1494-1497.
[13] Feng Yujie,Lv Jiangwei,Liu Junfeng,et al.Influence of boron concentration on growth characteristic and electro-catalytic performance of boron-doped diamond electrodes prepared by direct current plasma chemical vapor deposition[J].Applied Surface Science,2011,257(8):3433-3439.
[14] 吕江维.硼掺杂金刚石薄膜电极的制备与性能评价[D].哈尔滨:哈尔滨工业大学,2010.
[15] 庞雅宁,赵国华,刘磊,等.金刚石膜电极电化学氧化提高废水可生化性的研究[J].中国环境科学,2009,29(12):1255-1259.
[16] 高云芳,李建伟,陈新国,等.硼掺杂金刚石膜电极电氧化降解对氯苯酚废水[J].高校化学工程学报,2010,24(6):1052-1058.
[17] Rabaaoui N,Saad M,Moussaoui Y,et al.Anodic oxidation of o-nitrophenol on BDD electrode:variable effects and mechanisms of degradation[J].Journal of Hazardous Materials,2013,250/251:447-453.
[18] Flox C,Arias C,Brillas E,et al.Electrochemical incineration of cresols:A comparative study between PbO₂ and boron-doped diamond anodes[J].Chemosphere,2009,74(10):1340-1347.
[19] Rodrigo M A,Michaud P A,Duo I,et al.Oxidation of 4-chlorophenol at boron-doped diamond electrode for wastewater treatment[J].Journal of the Electrochemical Society,2001,148(5):60-64.
[20] Panizza M,Michaud P A,Cerisola G,et al.Anodic oxidation of 2-naphthol at boron-doped diamond electrodes[J].Journal of Electroanalytical Chemistry,2001,507(1/2):206-214.
[21] Pereira G F,Andrade L S,Rocha-Filho R C,et al.Electrochemical determination of bisphenol A using a boron-doped diamond electrode[J].Electrochimica Acta,2012,82(21):3-8.
[22] Panizza M,Cerisola G.Removal of colour and COD from wastewater containing acid blue 22 by electrochemical oxidation[J].Journal of Hazardous Materials,2008,153(1/2):83-88.
[23] Carvalho C,Fernandes A,Lopes A,et al.Electrochemical degradation applied to the metabolites of Acid Orange 7 anaerobic biotreatment[J].Chemosphere,2007,67(7):1316-1324.
[24] Zhou Minghua,Särkkä H,Sillanpää M.A comparative experimental study on methyl orange degradation by electrochemical oxidation on BDD and MMO electrodes[J].Separation and Purification Technology,2011,78(3)290-297.
[25] Hamza M,Abdelhedi R,Brillas E,et al.Comparative electrochemical degradation of the triphenylmethane dye Methyl Violet with boron-doped diamond and Pt anodes[J].Journal of Electroanalytical Chemistry,2009,627(1/2):41-50.
[26] Florenza X,Solano A M,Centellas F,el al.Degradation of the azo dye Acid Red 1 by anodic oxidation and indirect electrochemical processes based on Fenton's reaction chemistry.Relationship between decolorization,mineralization and products[J].Electrochimica Acta,2014,142:276-288.
[27] Juang Y,Nurhayati E,Huang C,et al.A hybrid electrochemical advanced oxidation/microfiltration system using BDD/Ti anode for acid yellow 36 dye wastewater treatment[J].Separation and Purification Technology,2013,120:289-295.
[28] Polcaro A M,Mascia M,Palmas S,et al.Electrochemical degradation of diuron and dichloroaniline at BDD electrode[J].Electrochimica Acta,2004,49(4):649-656.
[29] Madsen H T,Søgaard E G,Muff J.Study of degradation intermediates formed during electrochemical oxidation of pesticide residue 2,6-dichlorobenzamide (BAM) in chloride medium at boron doped diamond (BDD) and platinum anodes[J].Chemosphere,2015,120:756-763.
[30] Brillas E,Boye B,Sirés I,et al.Electrochemical destruction of chlorophenoxy herbicides by anodic oxidation and electro-Fenton using a boron-doped diamond electrode[J].Electrochimica Acta,2004,49(25):4487-4496.
[31] Pipi A R F,Andrade A R,Brillas E,et al.Total removal of alachlor from water by electrochemical processes[J].Separation&Purification Technology,2014,132(34):674-683.
[32] Brillas E,Sirés I,Arias C,et al.Mineralization of paracetamol in aqueous medium by anodic oxidation with a boron-doped diamond electrode[J].Chemosphere,2005,58(4):399-406.
[33] Ciríaco L,Anjo C,Correia J,et al.Electrochemical degradation of Ibuprofen on Ti/Pt/PbO₂ and Si/BDD electrodes[J].Electrochimica Acta,2009,54(5):1464-1472.
[34] Sopaj F,Rodrigo M A,Oturan N,et al.Influence of the anode materials on the electrochemical oxidation efficiency.Application to oxidative degradation of the pharmaceutical amoxicillin[J].Chemical Engineering Journal,2015,262(3):286-294.
[35] Garcia-Segura S,Cavalcanti E B,Brillas E.Mineralization of the antibiotic chloramphenicol by solar photoelectro-Fenton:From stirred tank reactor to solar pre-pilot plant[J].Applied Catalysis B:Environmental,2014,144(1):588-598.
[36] Benito A,Penadés A,Lliberia J L,et al.Degradation pathways of aniline in aqueous solutions during electro oxidation with BDD electrodes and UV/H₂O₂ treatment[J].Chemosphere,2017,166:230-237.
[37] Lissens G,Pieters J,Verhaege M,et al.Electrochemical degradation of surfactants by intermediates of water discharge at carbon-based electrodes[J].Electrochimica Acta,2003,48(12):1655-1663.
[38] 蒋绍阶,刘静,盛贵尚.掺硼金刚石薄膜电极电化学氧化垃圾渗滤液实验研究[J].水处理技术,2014,40(10):16-23.
[39] Cabeza A,Urtiaga A,Rivero M J,et al.Ammonium removal from landfill leachate by anodic oxidation[J].Journal of Hazardous Materials,2007,144(3):715-719.
[40] Urtiaga A,Rueda A,Anglada Á,et al.Integrated treatment of landfill leachates including electrooxidation at pilot plant scale[J].Journal of Hazardous Materials,2009,166(2/3):1530-1534.
[41] Tsantaki E,Velegraki T,Katsaounis A,et al.Anodic oxidation of textile dyehouse effluents on boron-doped diamond electrode[J].Journal of Hazardous Materials,2012,207/208(12):91-96.
[42] Solanoa A M,Araújoa C K,Meloa J V,et al.Decontamination of real textile industrial effluent by strong oxidant species electrogenerated on diamond electrode:Viability and disadvantages of this electrochemical technology[J].Applied Catalysis B:Environmental,2013,130/131:112-120.
[43] Aquino J M,Pereira G F,Rocha-Filho R C,et al.Electrochemical degradation of a real textile effluent using boron-doped diamond or β-PbO₂ as anode[J].Journal of Hazardous Materials,2011,192(3):1275-1282.
[44] 邢剑飞.掺硼金刚石薄膜电极处理难降解废水的研究[D].上海:上海交通大学,2013.
[45] Domínguez J R,González T,Palo P,et al.Electrochemical degradation of a real pharmaceutical effluent[J].Water Air and Soil Pollution,2012,223(5):2685-2694.
[46] Pérez J F,Llanos J,Sáez C,et al.Treatment of real effluents from the pharmaceutical industry:A comparison between Fenton oxidation and conductive-diamond electro-oxidation[J].Journal of Environmental Management,2017,195:216-223.
[47] Garcia-Segura S,Keller J,Brillas E,et al.Removal of organic contaminants from secondary effluent by anodic oxidation with a borondoped diamond anode as tertiary treatment[J].Journal of Hazardous Materials,2015,283:551-557.
[48] Urtiaga A M,Pérez G,Ibáñez R,et al.Removal of pharmaceuticals from a WWTP secondary effluent by ultrafiltration/reverse osmosis followed by electrochemical oxidation of the RO concentrate[J].Desalination,2013,331:26-34.
[49] Pérez G,Fernández-Alba A R,Urtiaga A M,et al.Electro-oxidation of reverse osmosis concentrates generated in tertiary water treatment[J].Water Research,2010,44(9):2763-2772.
[50] Gargouri B,Gargouri O D,Khmakhem I,et al.Chemical composition and direct electrochemical oxidation of table olive processing wastewater using high oxidation power anodes[J].Chemosphere,2017,166:363-371.
[51] Zhu Xiuping,Ni Jinren,Lai Peng.Advanced treatment of biologically pretreated coking wastewater by electrochemical oxidation using boron-doped diamond electrodes[J].Water Research,2009,43(17):4347-4355.
[52] Troster I,Fryda M,Herrmann D,et al.Electrochemical advanced oxidation process for water treatment using DiaChem^® electrodes[J].Diamond and Related Materials,2002,11(3/4/5/6):640-645.
[53] 李学敏.金刚石薄膜电极的电化学特性及其在污水处理中的应用研究[D].北京:清华大学,2004.
[54] Anglada A,Ibañez R,Urtiaga A,et al.Electrochemical oxidation of saline industrial wastewaters using boron doped diamond anodes[J].Catalysis Today,2010,151(1/2):178-184.

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