难降解废水生物电化学系统强化处理的研究进展

doi:10.11894/iwt.2019-1112

工业水处理 ›› 2020, Vol. 40 ›› Issue (10): 1-7. doi: 10.11894/iwt.2019-1112

• 专论与综述 • 下一篇

难降解废水生物电化学系统强化处理的研究进展

谢嘉玮¹(),朱国营²,谢军祥¹,常尧枫¹,姜滢¹,郭萌蕾¹,马楫²,陈重军^1,^2,^3,^4,*()

1. 苏州科技大学环境科学与工程学院, 江苏苏州 215009
2. 江苏苏净集团有限公司, 江苏苏州 215122
3. 江苏省环境科学与工程重点实验室, 江苏苏州 215009
4. 江苏水处理技术与材料协同创新中心, 江苏苏州 215009

收稿日期:2020-07-29 出版日期:2020-10-20 发布日期:2020-10-21
通讯作者: 陈重军 E-mail:15195698438@163.com;chongjunchen@163.com
作者简介:谢嘉玮(1997-),硕士研究生。电话:15195698438, E-mail:15195698438@163.com
基金资助:
国家自然科学基金项目(51508366);苏州市民生科技项目(ss2019022);江苏水处理技术与材料协同创新中心预研项目(XTCXSZ2019-3);江苏省环境科学与工程重点实验室开放基金项目(Zd1804);江苏省研究生科研创新计划项目(KYCX20_2780)

Research progress on enhanced treatment of refractory wastewater by bioelectrochemical system

Jiawei Xie¹(),Guoying Zhu²,Junxiang Xie¹,Yaofeng Chang¹,Ying Jiang¹,Menglei Guo¹,Ji Ma²,Chongjun Chen^1,^2,^3,^4,*()

1. School of Environmental Science and Engineering, Suzhou University of Science and Technology, Suzhou 215009, China
2. Jiangsu Sujing Group Co., Ltd., Suzhou 215122, China
3. Jiangsu Provincial Key Laboratory of Environmental Science and Engineering, Suzhou 215009, China
4. Jiangsu Collaborative Innovation Center of Water Treatment Technology and Material, Suzhou 215009, China

Received:2020-07-29 Online:2020-10-20 Published:2020-10-21
Contact: Chongjun Chen E-mail:15195698438@163.com;chongjunchen@163.com

摘要/Abstract

摘要：

工业废水中难降解污染物的强化去除是水处理的研究热点。介绍了生物电化学系统（BES）对废水中难降解污染物的降解原理，分析了电极、外加电压、盐度和电化学活性细菌（EAB）等因素对其处理效能的影响，讨论了其在偶氮染料废水、硝基芳烃废水、氯酚废水等典型难降解工业废水强化处理中的应用效果，并阐述了BES与生物法的耦合工艺及优势。分析认为BES中电极材料的经济性选择和改性修饰、EAB的筛选富集、实际应用电耗成本等是BES大规模应用亟待解决的问题。

关键词: 生物电化学系统, 难降解废水, 电极

Abstract:

The enhanced removal of refractory pollutants from industrial wastewater is a research hotspot in water treatment. This article introduced the principle of bioelectrochemical system(BES) degradation of pollutants in the treatment of refractory wastewater, and analyzed the effects of the factors such as electrodes, applied voltage, salinity, and electrochemically active bacteria(EAB) on the treatment efficiency, and discussed its application effect in the enhanced treatment of typical refractory industrial wastewater such as azo dyes wastewater, nitroaromatics wastewater, and chlorophenol wastewater. As well as the coupling process between BES and biomethods and its advantages were also described. It was considered that the economical selection and modification of electrode materials in BES, the enrichment of EAB screening, and the cost of practical power consumption were the issues that need to be resolved in large-scale applications of BES.

Key words: bioelectrochemical system(BES), refractory wastewater, electrode

中图分类号:

X703

谢嘉玮,朱国营,谢军祥,常尧枫,姜滢,郭萌蕾,马楫,陈重军. 难降解废水生物电化学系统强化处理的研究进展[J]. 工业水处理, 2020, 40(10): 1-7.

Jiawei Xie,Guoying Zhu,Junxiang Xie,Yaofeng Chang,Ying Jiang,Menglei Guo,Ji Ma,Chongjun Chen. Research progress on enhanced treatment of refractory wastewater by bioelectrochemical system[J]. Industrial Water Treatment, 2020, 40(10): 1-7.

https://www.iwt.cn/CN/Y2020/V40/I10/1

图/表 2

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反应器类型	反应器容积/L	废水类型	电极材料	外加电压/V	污染物进水质量浓度/（mg·L^-1）	主要污染物去除率	能耗（产电能力）	文献
MEC-AR	7.5	橙黄Ⅱ染料废水	碳纤维刷	0.5	50	脱色率97.2%	能耗：0.074~0.091 kW·h/kg橙黄Ⅱ	〔43〕
MEC-UASB	10	2，4-二氯硝基苯废水	石墨毡	1.5	50	2，4-二氯硝基苯去除率接近100%	能耗：0.02~0.04 kW·h/g苯胺	〔44〕
MEC-ABR	—	偶氮废水（茜素黄R）	石墨毡	0.7	200	脱色率（96.4±1.8）%	产电能力：24.1 A/m3	〔45〕
MEC-UASB	1.25	偶氮废水（酸性橙7）	碳纤维刷，碳棒	0.5	200	脱色率（94.91±1.55）%	电化学贡献率：（71.96±4.97）%	〔30〕
MEC-CW	0.7	磺胺甲恶唑废水（SMX）	不锈钢环，碳纤维	0.84~1.01	30	SMX去除率95%	产电能力：1.243~5.812 A/m3	〔46〕
MEC-CSTR	—	偶氮废水（茜素黄R）	碳纤维刷	0.5	100	脱色率（97.04±0.06）%	—	〔47〕
MEC-BCOR	5.95	偶氮废水（AO7)	集成碳刷	0.59	100	脱色率（94.62±0.63）%	能耗：（687.57 ± 3.86）J/gAO7	〔48〕

反应器类型	反应器容积/L	废水类型	电极材料	外加电压/V	污染物进水质量浓度/（mg·L^-1）	主要污染物去除率	能耗（产电能力）	文献
MEC-AR	7.5	橙黄Ⅱ染料废水	碳纤维刷	0.5	50	脱色率97.2%	能耗：0.074~0.091 kW·h/kg橙黄Ⅱ	〔43〕
MEC-UASB	10	2，4-二氯硝基苯废水	石墨毡	1.5	50	2，4-二氯硝基苯去除率接近100%	能耗：0.02~0.04 kW·h/g苯胺	〔44〕
MEC-ABR	—	偶氮废水（茜素黄R）	石墨毡	0.7	200	脱色率（96.4±1.8）%	产电能力：24.1 A/m3	〔45〕
MEC-UASB	1.25	偶氮废水（酸性橙7）	碳纤维刷，碳棒	0.5	200	脱色率（94.91±1.55）%	电化学贡献率：（71.96±4.97）%	〔30〕
MEC-CW	0.7	磺胺甲恶唑废水（SMX）	不锈钢环，碳纤维	0.84~1.01	30	SMX去除率95%	产电能力：1.243~5.812 A/m3	〔46〕
MEC-CSTR	—	偶氮废水（茜素黄R）	碳纤维刷	0.5	100	脱色率（97.04±0.06）%	—	〔47〕
MEC-BCOR	5.95	偶氮废水（AO7)	集成碳刷	0.59	100	脱色率（94.62±0.63）%	能耗：（687.57 ± 3.86）J/gAO7	〔48〕

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难降解废水生物电化学系统强化处理的研究进展

Research progress on enhanced treatment of refractory wastewater by bioelectrochemical system

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