工业水处理 ›› 2018, Vol. 38 ›› Issue (11): 17-20. doi: 10.11894/1005-829x.2018.38(11).017

• 试验研究 • 上一篇    下一篇

煤气化联产合成氨工艺废水制备水煤浆

王明霞1, 李得第2, 何先标1, 唐量华1, 李亚平1, 刘建忠2   

  1. 1. 浙江丰登化工股份有限公司, 浙江兰溪 321100;
    2. 浙江大学能源清洁利用国家重点实验室, 浙江杭州 310027
  • 收稿日期:2018-08-14 出版日期:2018-11-20 发布日期:2018-11-16
  • 通讯作者: 刘建忠,教授,博士生导师。E-mail:jzliu@zju.edu.cn。 E-mail:jzliu@zju.edu.cn
  • 作者简介:王明霞(1965-),高工。E-mail:Wangmx@conbagroup.com。
  • 基金资助:
    国家重点研发计划(2016YFB0600505)

Preparation of water-coal-slurry from synthetic ammonia process wastewater in coal gasification combined production

Wang Mingxia1, Li Dedi2, He Xianbiao1, Tang Lianghua1, Li Yaping1, Liu Jianzhong2   

  1. 1. Zhejiang Fengdeng Chemical Industry Co., Ltd., Lanxi 321100, China;
    2. National Key Laboratory on Energy Source Clean Utilization, Zhejiang University, Hangzhou 310027, China
  • Received:2018-08-14 Online:2018-11-20 Published:2018-11-16

摘要: 用煤气化联产合成氨工艺中产生的各种废水制备水煤浆,研究成浆性、流变性及稳定性,并在水煤浆气化炉上应用。结果表明:煤气化联产合成氨工艺中产生的洗气水、硫磺水及外来工业废水均对成浆有促进作用,而碳化水不利于成浆;洗气水的假塑性流体特征最明显,硫磺水及工业废水次之,碳化水流变性较差;几种废水在静置1个月后均未产生硬沉淀,具有良好的稳定性;废水水煤浆气化联产合成氨具有良好的环境效益和经济效益。

关键词: 合成氨废水, 煤气化废水, 水煤浆, 成浆性, 流变性, 稳定性

Abstract: Water-coal-slurry has been prepared from various kinds of wastewaters generated from synthetic ammonia process in coal gasification combined production. The slurrying ability,rheology property and stability of the watercoal-slurry have been investigated and applied to the gasification burner of water-coal-slurry. The results show that all the gas washing water,sulfur water and external industrial wastewater produced from the synthetic ammonia process in coal gasification combined production have auxo-action on slurrying ability,while the carbonized water has a negative influence on slurrying. The pseudo-plastic fluid characteristic of gas washing water is the most obvious one, and the sulfur water and industrial wastewater are the second. The rheological property of carbonized water is comparatively poor. These kinds of wastewaters do not produce hard sediment after standing for a month,and have good stability. Thus,the synthetic ammonia in wastewater water-coal-slurry gasification combined production has good environmental and economic benefits.

Key words: synthetic ammonia wastewater, coal gasification wastewater, water-coal-slurry, slurrying, rheology property, stability

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