工业水处理 ›› 2020, Vol. 40 ›› Issue (9): 104-107. doi: 10.11894/iwt.2019-0853

• 试验研究 • 上一篇    下一篇

铁刨花曝气/H2O2体系改善腈纶废水的可生化性研究

刘文(),满强强   

  1. 山东能源集团兖州煤业鄂尔多斯能化内蒙古荣信化工有限公司, 内蒙古鄂尔多斯 014300
  • 收稿日期:2020-07-20 出版日期:2020-09-20 发布日期:2020-10-21
  • 作者简介:刘文(1976-),工程师。电话:18947768977, E-mail:ykrxlw@163.com

Improving the biodegradability of acrylic fiber wastewater by iron scrape aeration/H2O2 system

Wen Liu(),Qiangqiang Man   

  1. Shandong Energy Group, Yanzhou Ordos in Inner Mongolia Will Rongxin Chemical Co., Ltd., Ordos 014300, China
  • Received:2020-07-20 Online:2020-09-20 Published:2020-10-21

摘要:

在铁刨花曝气体系(Fe0/O2对照体系)中投加活性炭或H2O2构建了Fe0/O2/C体系和Fe0/O2/H2O2体系,考察3种体系对腈纶废水中COD、SCN-的去除效果。结果表明,当废水pH为3.0,H2O2投加量为3 mL/L,铁刨花投加量为75 g/L,曝气量为60 L/h,反应时间为30 min时,COD、SCN-的去除率分别达到70%、98%以上;Fe0/O2/H2O2体系中的COD被优先去除,H2O2对SCN-的去除起到了促进作用,降低了其对微生物的抑制作用,可生化性得到显著改善。曝气作用有利于COD的去除,曝气量过大则气泡黏滞、包裹在铁刨花表面,COD去除率反而下降。

关键词: 铁刨花曝气/H2O2体系, 铁刨花, 腈纶废水, 可生化性

Abstract:

Based to the iron scrape aeration system, the iron scrape aeration/C and iron scrape aeration/H2O2 systems were constructed by adding activated carbon or H2O2. The COD and SCN-removal efficiencies of three systems on the acrylic fiber wastewater were investigated. The results showed that when the wastewater was adjusted to pH 3.0, and the reaction conditions were ascertained as H2O2 dosage 3 mL/L, iron scrape about 75 g/L, aeration volume 60 L/h, reaction time 30 min, COD and SCN-removal efficiencies were more than 70% and 98%, respectively. COD in iron scrape aeration/H2O2 system was preferentially removed. H2O2 promoted the removal of SCN- and reduced its inhibition on microorganisms, the biodegradability was significantly improved, the aeration effect was beneficial to the COD removal. When the aeration was too large, the air bubbles were viscous and wrapped on the surface of the iron scraps, and the COD removal efficiency was decrease.

Key words: iron scrape aeration/H2O2 system, iron scraps, acrylic fiber wastewater, biodegradability

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