双极膜电渗析技术的研究进展

doi:10.11894/iwt.2020-0501

摘要/Abstract

摘要：

在电场作用下，双极膜内的水能快速解离产生H⁺和OH^-，这一电化学特性使双极膜电渗析（BMED）逐渐发展为一种新型膜分离技术。首先介绍了BMED的基本工作原理，综述了其发展历程，接着介绍了近年来其在酸碱生产、污染控制、与其他化工技术耦合作用等方面的研究进展，最后提出目前应用中存在的问题，并对BMED的未来发展进行了展望。

关键词: 双极膜, 电渗析, 资源回收, 污染零排放

Abstract:

Under the effect of electronic field, the water in the bipolar membrane is rapidly dissociated to produce H⁺ and OH^-. This electrochemical property leads to the development of bipolar membrane electrodialysis(BMED) as a new membrane separation technology. This paper firstly gave a brief review on the basic operating principles of the BMED technology and summarized its development. Then the application and progress of the acid and alkali production, pollution control, coupled with other separation technologies in chemical engineering were reviewed and discussed. Finally, some problems were put forward together with the prospects for further development.

Key words: bipolar membrane, electrodialysis, resource recovery, zero pollution emissions

中图分类号:

X703

孙文文,唐元晖,张春晖,安康,林芷婧,林亚凯,王晓琳. 双极膜电渗析技术的研究进展[J]. 工业水处理, 2021, 41(5): 36-41.

Wenwen Sun,Yuanhui Tang,Chunhui Zhang,Kang An,Zhijing Lin,Yakai Lin,Xiaolin Wang. Research progress of bipolar membrane electrodialysis technology[J]. Industrial Water Treatment, 2021, 41(5): 36-41.

https://www.iwt.cn/CN/Y2021/V41/I5/36

图/表 3

参考文献 49

1	徐梅生. 我国电渗析技术的发展[J]. 水处理技术, 1985, 11 (5): 12- 15. URL
2	Frilette V J . Preparation and characterization of bipolar ion exchange membranes[J]. Physical Chemistry, 1956, 60 (4): 435- 439. doi: 10.1021/j150538a013
3	徐铜文, 何炳林. 双极膜-新的工业革命[J]. 世界科技研究与发展, 2000, 22 (3): 19- 27. doi: 10.3969/j.issn.1006-6055.2000.03.005
4	汪耀明. 双极膜电渗析法生产有机酸过程的几个关键科学问题研究[D]. 合肥: 中国科学技术大学, 2011.
5	廖尚志, 莫剑雄. 双极膜的发展和应用[J]. 水处理技术, 1995, 21 (6): 311- 318. URL
6	马洪运, 吴旭冉, 王保国. 双极膜分离技术及应用进展[J]. 化工进展, 2013, 32 (10): 2274- 2278. URL
7	张传洋. 双极膜电渗析应用于有机酸的生产[D]. 合肥: 合肥工业大学, 2017.
8	王欣欣. 双极膜电渗析法资源化草甘膦生产废水的研究[D]. 青岛: 中国海洋大学, 2013.
9	卫艳新. 双极膜电渗析法处理典型化工废水研究[D]. 合肥: 中国科学技术大学, 2012.
10	Xu Tongwen . Electrodialysis processes with bipolar membranes (EDBM) in environmental protection-a review[J]. Resources, Conservation and Recycling, 2002, 37 (1): 1- 22. doi: 10.1016/S0921-3449(02)00032-0
11	徐铜文. 均相离子交换膜暨双极膜的制备及其水解离机理研究[D]. 天津: 南开大学, 1997.
12	徐铜文, 杨伟华, 何炳林. 双极膜水解离现象——双极膜的物理构型、离子传递及其水解离压降分析[J]. 中国科学(B辑), 1999, 29 (6): 481- 488. URL
13	Onsager L . Deviations from ohm's law in weak electrolytes[J]. Chem. Phys., 1934, 2 (9): 599- 612. URL
14	王秋月. 双极膜制备及双极膜电渗析处理苯胺废水研究[D]. 合肥: 中国科学技术大学, 2017.
15	Simons R . Strong electric fields effects on proton transfer between membrane-bound amines and water[J]. Nature, 1979, 280, 824- 826. doi: 10.1038/280824a0
16	Simons R , Khanarian G . Water dissociation in bipolar membranes: Experiments and theory[J]. Journal of Membrane Biology, 1978, 38 (1/2): 11- 30. doi: 10.1007/BF01875160
17	唐宇, 王晓琳, 龚燕, 等. 双极膜电渗析理论与应用的研究进展[J]. 化工进展, 2004, 23 (10): 1107- 1112. doi: 10.3321/j.issn:1000-6613.2004.10.015
18	Juda W , Mcrae W A . Coherent ion-exchange gels and membran es[J]. Journal of the American Chemical Society, 1950, 72 (2): 1043- 1044. doi: 10.1021/ja01158a527
19	Bauer B , Gerner F J , Strathmann H . Development of bipolar membranes[J]. Desalination, 1988, 68 (2/3): 279- 292. URL
20	Simons R . A novel method for preparing bipolar membranes[J]. Electrochimica Acta, 1986, 31 (9): 1175- 1176. doi: 10.1016/0013-4686(86)80130-X
21	刘乾乾. 两性离子改性双极膜中间层的制备[D]. 北京: 北京化工大学, 2017.
22	闫凯旋, 郑强松, 刘俊生, 等. 双极膜电渗析技术在制酸领域的研究进展[J]. 应用化工, 2020, 49 (1): 196- 201. URL
23	董恒, 王建友, 卢会霞. 双极膜电渗析技术的研究进展[J]. 化工进展, 2010, 29 (2): 217- 222. URL
24	Wang Xiaolin , Wang Yaoming , Zhang Xu , et al. In-situ combination of fermentation and electrodialysis with bipolar membranes for the production of lactic acid: Continuous operation[J]. Bioresource Technology, 2013, 147, 442- 448. doi: 10.1016/j.biortech.2013.08.045
25	Yan Kaixuan , Hang Xiaofeng , Liu Junsheng , et al. Preparation of hypophosphorous acid by bipolar membrane electrodialysis: Process optimization and phosphorous acid minimization[J]. Industrial & Engineering Chemistry Research, 2019, 58 (47): 21855- 21863. URL
26	Li Ya , Shi Shaoyuan , Cao Hongbin , et al. Bipolar membrane electrodialysis for generation of hydrochloric acid and ammonia from simulated ammonium chloride wastewater[J]. Water Res., 2016, 89, 201- 209. doi: 10.1016/j.watres.2015.11.038
27	侯震东, 张伟, 潘杰峰, 等. 双极膜电渗析法制备高纯度四甲基氢氧化铵[J]. 水处理技术, 2017, 43 (4): 42- 46. URL
28	Liu Xiaohe , Li Qiuhua , Jiang Chenxiao , et al. Bipolar membrane electrodialysis in aqua-ethanol medium: Production of salicylic acid[J]. Journal of Membrane Science, 2015, 482, 76- 82. doi: 10.1016/j.memsci.2015.02.030
29	夏敏, 操容, 叶春松, 等. 双极膜电渗析技术在工业高含盐废水中的应用[J]. 化工进展, 2018, 37 (7): 2820- 2829. URL
30	夏敏. 基于双极膜电渗析处理脱硫废水的研究[D]. 武汉: 武汉大学, 2018.
31	Xia Min , Ye Chunsong , Cao Rong , et al. An innovative beneficial reclamation of flue gas desulfurization brine using bipolar membrane electrodialysis technique[J]. International Journal of Electrochemical Science, 2018, 13 (6): 5382- 5395.
32	吕燕. 双极膜电渗析处理氯化铵废水和制备高盐基度聚合硫酸铁的应用研究[D]. 合肥: 合肥工业大学, 2019.
33	Chen Beiyan , Liu Zhongqin , Zhou Lina , et al. Research on bipolar membrane electrodialysis for ion exchange of molecular sieves[J]. China Petroleum Processing and Petrochemical Technology, 2018, 20 (2): 1- 5. URL
34	Ye Wenyuan , Huang Jie , Lin Jiuyang , et al. Environmental evaluation of bipolar membrane electrodialysis for NaOH production from wastewater: Conditioning NaOH as a CO₂ absorbent[J]. Separation and Purification Technology, 2015, 144, 206- 214. doi: 10.1016/j.seppur.2015.02.031
35	Fatih I , Harun A K , Ugur K , et al. Recovery of mixed acid and base from wastewater with bipolar membrane electrodialysis-a case study[J]. Desalination and Water Treatment, 2016, 27 (11): 5165- 5173. URL
36	Chen Man , Zhang Fang , Zhang Yan , et al. Alkali production from bipolar membrane electrodialysis powered by microbial fuel cell and application for biogas upgrading[J]. Applied Energy, 2013, 103, 428- 434. doi: 10.1016/j.apenergy.2012.10.005
37	Tang Jing , Jia Surong , Qu Shanshan , et al. An integrated biological hydrogen production process based on ethanol-type fermentation and bipolar membrane electrodialysis[J]. International Journal of Hydrogen Energy, 2014, 39 (25): 13375- 13380. doi: 10.1016/j.ijhydene.2014.04.085
38	Chen Binglun , Jiang Chenxiao , Wang Yaoming , et al. Selectrodialysis with bipolar membrane for the reclamation of concentrated brine from RO plant[J]. Desalination, 2018, 442, 8- 15. doi: 10.1016/j.desal.2018.04.031
39	Melnikov S S , Mugtamov O A , Zabolotsky V I . Study of electrodialysis concentration process of inorganic acids and salts for the two-stage conversion of salts into acids utilizing bipolar electrodialysis[J]. Separation and Purification Technology, 2019, 235, 116198.
40	Lin Jiuyang , Lin Fang , Chen Xiangyu , et al. Sustainable management of textile wastewater: A hybrid tight ultrafiltration/bipolar-membrane electrodialysis process for resource recovery and zero liquid discharge[J]. Industrial & Engineering Chemistry Research, 2019, 58 (25): 11003- 11012. URL
41	任洪艳, 丛威. 电渗析中的膜污染及其控制方法研究进展[J]. 现代化工, 2007, (7): 18- 22. doi: 10.3321/j.issn:0253-4320.2007.07.005
42	Tanaka N , Nagase M , Higa M . Organic fouling behavior of commercially available hydrocarbon-based anion-exchange membranes by various organic fouling substances[J]. Desalination, 2012, 296, 81- 86. doi: 10.1016/j.desal.2012.04.010
43	王鹤宁. 阴离子交换膜酸传质对丙烯酸丁酯废水双极膜电渗析膜污染的影响[D]. 兰州: 兰州交通大学, 2017.
44	Park J S , Lee H J , Choi S J , et al. Fouling mitigation of anion exchange membrane by zeta potential control[J]. Journal of Colloid and Interface Science, 2003, 259 (2): 293- 300. doi: 10.1016/S0021-9797(02)00095-4
45	Vaselbehagh M , Karkhanechi H , Mulyati S , et al. Tmproved antifouling of anion-exchange membrane by polydopamine coating in electrodialysis process[J]. Desalination, 2014, 332 (1): 126- 133. doi: 10.1016/j.desal.2013.10.031
46	Berkessa Y W , Lang Qiaolin , Yan Binghua , et al. Anion exchange membrane organic fouling and mitigation in salt valorization process from high salinity textile wastewater by bipolar membrane electrodialysis[J]. Desalination, 2019, 465, 94- 103. doi: 10.1016/j.desal.2019.04.027
47	刘小菏, 李秋花, 葛亮, 等. 水-乙醇体系对双极膜中间界面层的影响[J]. 化工学报, 2016, 67 (1): 309- 314. URL
48	焦扬, 杨鹏波, 丛威. 双极膜电渗析质子渗漏相关因素的分析[J]. 膜科学与技术, 2011, 31 (6): 64- 68. doi: 10.3969/j.issn.1007-8924.2011.06.013
49	黄灏宇, 叶春松. 双极膜电渗析技术在高盐废水处理中的应用[J]. 水处理技术, 2020, 46 (6): 4- 8. URL

[1]	史金卓, 胡以松, 肖文倩, 李松华, 杨媛, 田文瑞. 电化学-膜生物反应器强化污废水处理的研究进展[J]. 工业水处理, 2024, 44(5): 32-41.
[2]	肖卓远, 黄南, 巫寅虎, 张倬玮, 徐雨晴, 吴乾元, 王文龙, 熊江磊, 罗嘉豪, 廖翔, 胡洪营. 集成电路废水的达标排放、资源回收和再生处理[J]. 工业水处理, 2024, 44(4): 1-9.
[3]	晋银佳, 王绍曾, 郭栋, 尤良洲, 衡世权. 基于双极膜电渗析的矿井浓盐水资源化处理工艺研究[J]. 工业水处理, 2024, 44(3): 104-111.
[4]	黄瀚文, 封铃, 田秉晖. 目标选择性填充床电渗析研究进展[J]. 工业水处理, 2024, 44(12): 31-39.
[5]	李福勤, 王世奕, 梁桢, 王瑾. 扩散渗析-纳滤分离工艺资源化钢铁酸性脱硫废水的研究[J]. 工业水处理, 2024, 44(11): 74-81.
[6]	冉婷婷, 李乐卓, 王兆冉, 石瑞莲. 光合细菌废水处理技术的研究进展[J]. 工业水处理, 2024, 44(11): 9-16.
[7]	门枢, 王凯, 杨飞. 焦化废水回用处理工艺设计及运行分析[J]. 工业水处理, 2023, 43(3): 186-191.
[8]	杨泽琨, 陈青柏, 王建友, 徐勇, 高阳. 基于可再生能源的膜脱盐技术进展[J]. 工业水处理, 2023, 43(12): 14-25.
[9]	徐萍, 占晓建, 李凤祥. 好氧颗粒污泥中的胞外聚合物及其应用的研究进展[J]. 工业水处理, 2023, 43(12): 36-45.
[10]	贺磊, 周涛, 赵由才. 气态膜法回收垃圾渗滤液氨氮技术进展与机理探讨[J]. 工业水处理, 2023, 43(12): 52-57.
[11]	张傲, 王好, 冉凡, 张琳婧, 陈子薇, 任宏洋. 页岩气压裂返排液电渗析脱盐处理技术研究[J]. 工业水处理, 2022, 42(8): 102-107.
[12]	蒋彬, 刘中亚, 陈垚, 袁绍春. 碳中和视角下污水处理现状与展望[J]. 工业水处理, 2022, 42(6): 51-58.
[13]	王文虎, 赵姗姗, 王伟, 阎光绪. 电化学氧化-电渗析联合处理丙烯腈四效蒸发凝液[J]. 工业水处理, 2022, 42(5): 150-156.
[14]	崔玮哲,纪志永,TUMBA Kaniki,汪婧,张忠德,袁俊生. 反电渗析处理海水淡化副产浓海水的研究[J]. 工业水处理, 2022, 42(3): 147-153.
[15]	罗胜,朱铭,田秉晖,MALALAGAMA Theekshana. 电渗析水处理除氟的研究进展及主要影响因素[J]. 工业水处理, 2022, 42(12): 1-9.

选择文件类型/文献管理软件名称

选择包含的内容