工业水处理 ›› 2021, Vol. 41 ›› Issue (4): 52-55. doi: 10.11894/iwt.2020-0654

• 试验研究 • 上一篇    下一篇

对磺胺嘧啶厌氧生物降解机理的研究

李欣航(),曹占平*(),惠婷,董妩嫘,王华   

  1. 天津工业大学环境科学与工程学院, 天津 300387
  • 收稿日期:2021-03-04 出版日期:2021-04-20 发布日期:2021-04-23
  • 通讯作者: 曹占平 E-mail:18714708391@163.com;caozhanping2012@126.com
  • 作者简介:李欣航(1994-), 硕士研究生。E-mail: 18714708391@163.com
  • 基金资助:
    国家自然科学基金(51078265)

Study on anaerobic biodegradation mechanism of sulfadiazine

Xinhang Li(),Zhanping Cao*(),Ting Hui,Wulei Dong,Hua Wang   

  1. School of Environmental Science and Engineering, Tiangong University, Tianjin 300387, China
  • Received:2021-03-04 Online:2021-04-20 Published:2021-04-23
  • Contact: Zhanping Cao E-mail:18714708391@163.com;caozhanping2012@126.com

摘要:

以磺胺嘧啶为目标污染物,考察厌氧生物对磺胺嘧啶的降解性能。结果表明,在25℃、pH为6.0、外加100 mg/L碳酸氢钠的条件下,微生物对20 mg/L磺胺嘧啶的降解率为99.7%,磺胺嘧啶的降解过程符合零级反应动力学特征。降解途径分析显示,厌氧生物通过3条平行途径降解磺胺嘧啶,将磺胺嘧啶逐渐转化为低毒和无毒的化合物,其中2-氨基-4-羟基嘧啶是主要降解产物。

关键词: 磺胺嘧啶, 厌氧, 生物降解

Abstract:

Choosing sulfadiazine as the target pollutant, the degradation performance of sulfadiazine by anaerobic organisms was investigated. The results showed that the degradation rate of sulfadiazine at 20 mg/L by microorganisms was 99.7% under the conditions of 25℃, pH=6.0, and 100 mg/L sodium bicarbonate. The degradation process of sulfadiazine met zero-order reaction kinetics. Analysis of degradation pathways showed that anaerobic organisms degrade sulfadiazine through three parallel pathways, the sulfadiazine was gradually transformed into low-toxic and nontoxic compounds, of which 2-amino-4-hydroxypyrimidine was main degradation product.

Key words: sulfadiazine, anaerobism, biodegradation

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