工业水处理 ›› 2021, Vol. 41 ›› Issue (4): 48-51. doi: 10.11894/iwt.2020-0668

• 试验研究 • 上一篇    下一篇

微电解耦合非均相Fenton法处理印染废水膜浓缩液

王震1(),王长智1,许青兰1,沈忱2,梅荣武1,谭映宇1,张宇1,任旭锋1,王睿1   

  1. 1. 浙江省生态环境科学设计研究院, 浙江杭州 310007
    2. 浙江师范大学地理与环境科学学院, 浙江金华 321004
  • 收稿日期:2021-02-01 出版日期:2021-04-20 发布日期:2021-04-23
  • 作者简介:王震(1987-), 博士, 高级工程师。E-mail: pjwzhen@163.com
  • 基金资助:
    水体污染控制与治理科技重大专项(2018ZX07208-009-06);浙江省基础公益研究计划(LGF19B070003)

Treatment of membrane concentrate from dyeing wastewater by micro-electrolysis coupling heterogeneous Fenton-like system

Zhen Wang1(),Changzhi Wang1,Qinglan Xu1,Chen Shen2,Rongwu Mei1,Yingyu Tan1,Yu Zhang1,Xufeng Ren1,Rui Wang1   

  1. 1. Environmental Science Research and Design Institute of Zhejiang Province, Hangzhou 310007, China
    2. College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua 321004, China
  • Received:2021-02-01 Online:2021-04-20 Published:2021-04-23

摘要:

针对印染废水膜浓缩液含盐量高、可生化性差等特点,以铁碳陶粒为催化填料,耦合微电解和非均相Fenton工艺进行处理。中试运行结果表明,CODCr、苯胺、总磷、氨氮、总氮最高去除率分别达到87.8%、95.3%、90.6%、76.9%、72.8%,色度可降至15倍以下,出水满足《纺织染整工业水污染物排放标准》(GB 4287—2012)表 2直接排放标准要求。该工艺运行效果稳定,直接运行费用约为4.99元/t。

关键词: 微电解, 非均相Fenton, 印染废水, 膜浓缩液

Abstract:

The membrane concentrate from dyeing wastewater has high salt content and poor biodegradability, which was treated by micro-electrolysis coupling heterogeneous Fenton-like system using iron-carbon ceramsite as catalytic filler. The pilot test results showed that the highest removal rates of major pollution indicators such as CODCr, aniline, total phosphorus, ammonia nitrogen, and total nitrogen reached 87.8%, 95.3%, 90.6%, 76.9% and 72.8%, respectively, and the chroma decreased to less than 15 times. The effluent met the direct emission standard of Discharge Standard of Water Pollutants for Dyeing and Finishing Industry(GB 4287-2012). The operation effect of this process is stable, and the direct operation cost is about 4.99 yuan/t.

Key words: micro-electrolysis, heterogeneous Fenton-like system, printing and dyeing wastewater, membrane filtration concentrate

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