淀粉基化学品用作吸附剂的应用研究进展

doi:10.19965/j.cnki.iwt.2020-0701

摘要/Abstract

摘要：

近年来随着石油资源的枯竭，人们对于可再生资源越来越关注，对淀粉基吸附剂的研究逐渐增加。综述了以淀粉为基材制备吸附剂及其吸附重金属离子、染料及其他物质的研究现状，并介绍了纳米淀粉改性用作吸附剂的应用情况，最后对淀粉基化学品用作吸附剂的发展趋势进行了展望。

关键词: 淀粉基化学品, 吸附剂, 改性, 再生资源

Abstract:

In recent years, with the depletion of petroleum resources, more and more attention has been paid to renewable resources, and the research on starch-based adsorbents has gradually increased. This paper summarized the research status of the preparation of adsorbents using starch as the substrate, and its adsorption of heavy metal ions, dyes, and other substances. The methods and applications of nano-starch modification as adsorbents were also introduced. Finally, the development trend of starch based chemicals as adsorbent was prospected.

Key words: starch-based chemicals, adsorbent, modified, renewable resources

中图分类号:

X703
TQ424

赵雅兰,陈启杰,谢琼华,梁春艳,魏雅琴. 淀粉基化学品用作吸附剂的应用研究进展[J]. 工业水处理, 2021, 41(7): 19-24, 33.

Yalan Zhao,Qijie Chen,Qionghua Xie,Chunyan Liang,Yaqin Wei. Research progress on application of starch-based chemicals as adsorbent[J]. Industrial Water Treatment, 2021, 41(7): 19-24, 33.

https://www.iwt.cn/CN/Y2021/V41/I7/19

图/表 2

参考文献 44

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吸附剂	改性剂	被吸附物质	吸附等温线	吸附动力学	吸附容量/(mg·g^-1)
淀粉基吸附剂	丙烯酸、丙烯酸胺^〔1〕	Cd²⁺	Langmuir	拟二阶	347.46
	二苯并-18-冠-6^〔2〕	Cu²⁺	Freundlich	拟二阶	385
		Zn²⁺			377.5
		Cd²⁺			368.5
	2-(N-(3-(羟甲基)氨基)-3-氧丙基)丙烯酰胺基)-2-甲基丙烷磺酸、2-(3-(N-(羟甲基)丙烯酰胺基)丙酰胺基)-2-甲基丙烷磺酸^〔3〕	Bi(Ⅲ)			1 005.41
		Hg(Ⅱ)			1 087.79
	单宁酸^〔7〕	Au(Ⅲ)	Langmuir	拟二阶	298.5
	壳聚糖^〔8〕	Cu²⁺	Langmuir	拟二阶	129.180
	丙烯酸^〔11〕	Cu²⁺	Langmuir		957.0
	聚丙烯酰胺^〔17〕	亚甲基蓝	Freundlich	拟二阶	2 000
	偏磷酸钠^〔20〕	亚甲基蓝	Langmuir	放热	11.66
	硫酸^〔25〕	孔雀石绿	Langmuir	拟一阶	173.92
	3-氯-2-羟丙基三甲基氯化铵^〔26〕	金黄色SNE染料	Langmuir	拟二阶	208.77
	乙二胺、戊二醛^〔28〕		Langmuir	拟二阶	35
	硅砂^〔15〕	亚甲基蓝	Langmuir	拟二阶	653.31±27.30
	硅砂^〔15〕	结晶紫			1 246.40±34.10
	甲基丙烯酸^〔30〕	苯酚			250.1
	2，2，6，6-四甲基哌啶基氧基、壳聚糖^〔36〕	花青素			83.0±2.1
	(3-氯-2-羟丙基)三甲基氯化铵^〔37〕	小球藻	Langmiur	拟二阶	9 148.14

吸附剂	改性剂	被吸附物质	吸附等温线	吸附动力学	吸附容量/(mg·g^-1)
淀粉基吸附剂	丙烯酸、丙烯酸胺^〔1〕	Cd²⁺	Langmuir	拟二阶	347.46
	二苯并-18-冠-6^〔2〕	Cu²⁺	Freundlich	拟二阶	385
		Zn²⁺			377.5
		Cd²⁺			368.5
	2-(N-(3-(羟甲基)氨基)-3-氧丙基)丙烯酰胺基)-2-甲基丙烷磺酸、2-(3-(N-(羟甲基)丙烯酰胺基)丙酰胺基)-2-甲基丙烷磺酸^〔3〕	Bi(Ⅲ)			1 005.41
		Hg(Ⅱ)			1 087.79
	单宁酸^〔7〕	Au(Ⅲ)	Langmuir	拟二阶	298.5
	壳聚糖^〔8〕	Cu²⁺	Langmuir	拟二阶	129.180
	丙烯酸^〔11〕	Cu²⁺	Langmuir		957.0
	聚丙烯酰胺^〔17〕	亚甲基蓝	Freundlich	拟二阶	2 000
	偏磷酸钠^〔20〕	亚甲基蓝	Langmuir	放热	11.66
	硫酸^〔25〕	孔雀石绿	Langmuir	拟一阶	173.92
	3-氯-2-羟丙基三甲基氯化铵^〔26〕	金黄色SNE染料	Langmuir	拟二阶	208.77
	乙二胺、戊二醛^〔28〕		Langmuir	拟二阶	35
	硅砂^〔15〕	亚甲基蓝	Langmuir	拟二阶	653.31±27.30
	硅砂^〔15〕	结晶紫			1 246.40±34.10
	甲基丙烯酸^〔30〕	苯酚			250.1
	2，2，6，6-四甲基哌啶基氧基、壳聚糖^〔36〕	花青素			83.0±2.1
	(3-氯-2-羟丙基)三甲基氯化铵^〔37〕	小球藻	Langmiur	拟二阶	9 148.14

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