工业水处理 ›› 2025, Vol. 45 ›› Issue (11): 1-7. doi: 10.19965/j.cnki.iwt.2025-0054

• 专论与综述 •    

地下水中非水相液体去除方法研究进展

左世伟1(), 师新阁1, 朴洪伟2, 赵健2()   

  1. 1. 中石化炼化工程(集团)股份有限公司洛阳技术研发中心,河南 洛阳 471003
    2. 天津工业大学纺织科学与工程学院,先进分离膜材料全国重点实验室,天津 300387
  • 收稿日期:2025-02-10 出版日期:2025-11-20 发布日期:2025-11-20
  • 通讯作者: 赵健
  • 作者简介:

    左世伟(1985— ),硕士,高级工程师,E-mail:

  • 基金资助:
    国家自然科学基金项目(52173038); 中石化科技项目(323064)

Research progress on removal methods of non-aqueous phase liquids in groundwater

Shiwei ZUO1(), Xinge SHI1, Hongwei PIAO2, Jian ZHAO2()   

  1. 1. Luoyang R&D Center of Technology, Sinopec Engineering (Group) Co. , Ltd. , Luoyang 471003, China
    2. State Key Laboratory of Advanced Separation Membrane Materials, School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China
  • Received:2025-02-10 Online:2025-11-20 Published:2025-11-20
  • Contact: Jian ZHAO

摘要:

油气勘探、开采、运输以及炼化等相关化学工业生产过程中,石油类物质的泄露导致非水相液体(NAPL)广泛存在于地下水中,对水生生态安全与人体健康构成严重威胁,治理需求十分迫切。目前常用的NAPL处理技术包括物理法、化学法和生物法。综述了NAPL处理技术的发展与应用情况;分析了各种技术的适用性与优缺点,其中,物理法处理较为彻底,但传统的开挖置换、离心处置工程量大,而多相抽提技术能耗高、效率有限且成本较高,膜分离技术则对膜材料性能提出了较高的要求;化学法药剂耗费量大,且易造成次生污染;生物法受环境变化、水文条件影响大;最后,对地下水中NAPL处理技术未来的发展趋势进行了展望。

关键词: 地下水处理, 非水相液体, 分离膜, 油水分离

Abstract:

During industrial processes such as oil and gas exploration, extraction, transportation, and refining, leaks of petroleum-based substances lead to the widespread presence of non-aqueous phase liquids (NAPLs) in groundwater, posing serious threats to aquatic ecological safety and human health and creating an urgent need for remediation. The common disposal methods include physical, chemical, and biological. This article summarized the development and application of NAPL phase treatment techniques. The advantages and disadvantages of these methods were analyzed. Among them, physical methods can achieve relatively thorough remediation. However, traditional techniques like excavation and replacement or centrifugal disposal involve massive engineering work, while multiphase extraction technology suffers from high energy consumption, limited efficiency, and high costs. Membrane separation, whereas, places high demands on the performance of the membrane materials. Chemical methods needed a lot of reagents, which could easily cause secondary pollution. Biological treatment was greatly influenced by the ambient environment. Finally, the future development trends of NAPL treatment technologies involving in groundwater were prospected.

Key words: groundwater treatment, non-aqueous phase liquid, separation membrane, oil-water separation

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