工业水处理 ›› 2006, Vol. 26 ›› Issue (10): 75-77. doi: 10.11894/1005-829x.2006.26(10).75

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混凝—氧化法处理喷漆废水的应用研究

谭雨清1, 关晓辉1, 刘海宁2, 王旭生1   

  1. 1. 东北电力大学, 吉林市 132012;
    2. 中科院生态环境研究中心, 北京 100085
  • 收稿日期:2006-06-17 出版日期:2006-10-20 发布日期:2010-10-01
  • 作者简介:谭雨清(1964- ),1987 年毕业于大连轻工业学院。电话:13624322232,E-mail:tyqmm@21cn.com。

Application study of using coagulation oxidation method to the treatment of painting was tewater

Tan Yuqing1, Guan Xiaohui1, Liu Haining2, Wang Xusheng1   

  1. 1. Department of Applied Chemistry, Northeast China Institute of Electric Power Engineering, Jilin 132012, China;
    2. Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
  • Received:2006-06-17 Online:2006-10-20 Published:2010-10-01

摘要:

采用一种新工艺,以微生物为催化剂,常温常压下用空气氧化制备生物聚合硫酸铁(BPFS),结合Fenton试剂对喷漆废水进行混凝—氧化试验。BPFS与PAM联用,混凝去除喷漆废水中悬浮状有机物,混凝出水再经Fen-ton试剂氧化处理,进一步深度氧化去除溶解态有机物,实验确定了最佳处理条件。结果表明:研制的聚合铁性能优良,凝聚作用显著,经混凝—氧化处理后废水的CODCr从880mg/L降至25mg/L(去除率达97%),色度为0,悬浮物<50mg/L,完全可以达标排放。

关键词: 喷漆废水, 混凝, 氧化, 生物聚合硫酸铁

Abstract:

By using a new technological process, on the basis of microorganism as a catalyst, ferrous sulfate is oxidized by the air at normal temperature and pressure, and the polyferric sulfate is made. The product is named biological polyferric sulfate, and its abbreviation is BPFS. Combined with Fenton agent, it is used for treating painting wastewater in coagulation-oxidation experiment. BPFS combined with coagulant aid PAM for coagulation is used to treat the suspended organics, and Fenton agent for further treatment to oxidize the dissolved organics. The suitable condition is selected. Experiments indicate that, after coagulation and oxidation, the CODCr of painting wastewater has been decreased from 880mg/L to 25mg/L, the removal ratio up to 97%. The chroma reaches 0 and suspended matter is less than 50mg/L. The treated wastewater can be discharged away directly.

Key words: painting wastewater, coagulation oxidation, biological polyferric sulfate

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