壳聚糖及其衍生物在工业污水处理中的研究及应用

doi:10.11894/1005-829x.2000.20(4).7

摘要/Abstract

摘要：

介绍了近年来国内外壳聚糖及其衍生物在不同工业污水处理中的应用及相关机理。壳聚糖及其衍生物作为絮凝剂、金属离子的螯合剂以及有机物的吸附剂,在工业污水处理中有着相当广泛的应用,主要是絮凝和处理含重金属离子的工业废水,环境效益显著。壳聚糖及其衍生物是绿色的水处理剂,其未来发展的方向是合成性能更为优良的改性壳聚糖,与其他技术复合使用,并深入研究其对复杂工业废水的处理能力。

关键词: 壳聚糖, 絮凝, 重金属, 污水

Abstract:

The development and applications of chitosan and its derivatives in the treatment of different sources of industrial wastewater have been reviewed in recent years. Chitosan and its derivatives can be used as flocculant,heavy metal-chelating agent and adsorbent for organics,which offer widespread applications in industrial effluent treatment. They are applied mostly to the flocculation and treatment of industrial wastewater containing heavy metal and are of tremendous environmental benefits. Chitosan and its derivatives are green reagents and degradable in nature. Its future developing trend will be to synthesize better ramifications,to combine with other techniques and to investigate their treating effects for complex industrial wastewater.

Key words: chitosan, flocculation, heavy metal, wastewater

中图分类号:

X703.1

田艳, 张敏, 程爱民. 壳聚糖及其衍生物在工业污水处理中的研究及应用[J]. 工业水处理, 2007, 27(3): 7-9.

Tian Yan, Zhang Min, Cheng Aimin. Researches and applications of chitosan and its derivatives to the treatment of indus trial was tewater[J]. INDUSTRIAL WATER TREATMENT, 2007, 27(3): 7-9.

https://www.iwt.cn/CN/Y2007/V27/I3/7

参考文献

[1] Crini G. Non-conventional low-cost adsorbents for dye removal: A review[J]. Biores. Technol., 2006, 97(9) : 1 061-1 085.
[2] Sakkayawong N, Thiravetyan P, Nakbanpote W. Adsorption mechanismof synthetic reactive dye wastewater by chitosan [J]. J. Colloid Interface Sci., 2005, 286(1) : 36-42.
[3] 刘秉涛, 姜安玺.羧甲基壳聚糖处理染料废水的正交试验研究[J].工业水处理, 2005, 25(2) : 23-25.
[4] 郎雪梅, 赵建青. 凝固浴处理对聚氨基葡糖超滤膜分离性能的影响[J]. 过程工程学报, 2003, 3(5) : 442-446.
[5] 曾德芳, 李娟, 袁继祖.天然高分子絮凝剂在工业污水处理中的应用[J]. 工业水处理, 2004, 24(2) : 20-22.
[6] 吴根, 罗人明, 罗晓.香草醛改性壳聚糖的制备及其对洗毛废水絮凝处理性能的研究[J].精细化工, 2001, 18(8) : 464-466.
[7] 安胜姬.二异氰酸酯与壳聚糖交联产物对金属离子的吸附性能[J].长春科技大学学报, 1999, 29(2) : 197-199.
[8] 孙加龙, 陈克复.保留蛋白质的壳聚糖絮凝应用[J]. 中国造纸学报, 2002, 17(1) : 48-50.
[9] 朱思明, 于淑娟, 杨连生.用壳聚糖二次处理糖蜜酒精废液[J]. 中国甜菜糖业, 2004(2) : 13-15.
[10] Ahmad AL, Sumathi S, Hameed B H. Chitosan: A nature biopolymer for the adsorption of residue oil from oily wastewater[J].Adsorp. Sci.Technol., 2004, 22(1) : 75-88.
[11] 叶绮, 蔡伟民, 沈雄飞. 壳聚糖季铵盐的合成及其对炼油废水的絮凝和灭菌性能[J]. 福州大学学报, 2000, 28 (4) : 108-111.
[12] 王峰, 李义久, 倪亚明.丙烯酰胺接枝共聚壳聚糖絮凝剂的合成及絮凝性能研究[J]. 工业水处理, 2003, 23(12) : 45-47.
[13] 李肖玲, 臧利华, 刘玉婷.壳聚糖絮凝陶瓷废水机理研究[J]. 山东陶瓷, 2003, 26(4) : 10-11.
[14] Schmuhl S, Krieg H M, Keizer K.Adsorption of Cu(Ⅱ) and Ions by Chitosan: Kinetics and Equilibrium Studies[J].Water SA., 2001,27: 1-7.
[15] Dambies L, Vincent T, Guibal E. Treatment of arsenic-containing solutions using chitosan derivatives: Uptake mechanism and sorption performances[J]. Water Res., 2002, 36(8) : 3 699-3 710.
[16] Babel S, Kurniawan T A. Low-cost adsorbents for heavy metals uptake fromcontaminated water: Areview[J]. J. Hazard. Mater., 2003,B97: 219-243.
[17] 方忻兰. 高效絮凝剂壳聚糖螯合剂的研制及其絮凝效果的研究[J]. 污染防治技术, 1996, 18(2) : 4-6.
[18] 兰文艺, 邵刚.实用环境工程手册---水处理材料与药剂[M].北京: 化学工业出版社, 2002: 274.
[19] 金玉仁, 李冬梅, 张宝川, 等.磁性壳聚糖的制备及其对三价锕系和镧系的吸附性能研究[J]. 离子交换与吸附, 1999, 15(2) : 177-181.
[20] KimE, Benedetti MF, Boulégue J. Removal of dissolved rhenium by sorption onto organic polymers: Study of rhenium as an analogue of radioactive technetium[J]. Water Res., 2004, 38(2) : 448-454.
[21] Aoki N, Nishikawa M, Hattori K. Synthesis of chitosan derivatives bearing cyclodextrin and adsorption of p-nonylphenol and bisphenol A[J]. Carbohydr. Polym., 2003, 52(3) : 219-223.
[22] Yoshizuka K, Lou Z R, Inoue K. Silver-complexed chitosan microparticles for pesticide removal[J]. Rea. Func. Polym., 2000, 44(1) : 47-54.
[23] Van Daele Y, Thome J P. Purification of PCB contaminated water by chitosan: A biological test of efficiency using the common barbel,Barbus Barbus [J]. Bull. Environ. Contam. Toxicol., 1986, 37 (6) :858-865.
[24] Wada S, Lchikawa H, Tatsumi K. Removal of phenols and aromatic amines from wastewater by a combination treatment with tyrosinase and a coagulant[J]. Biotechnol. Bioeng., 1995, 45(4) : 304-309.
[25] Murcott S. The efficacy of chitosan and other natural polymers in removing COD, TSS, heavy metals and PAHs from municipal wastewater at Deer Island, Massachusetts (MITSG) [M]. Casa Publicadora :Sea Grant College Program, Massachusetts Institute of Technology,1992: 1-66.
[26] Tonegawa M, Dec J, Bollag J M.Use of additives to enhance the removal of phenols from water treated with horseradish and hydrogen peroxide[J]. J. Environ. Qual., 2003, 32(4) : 1 222-1 227.

选择文件类型/文献管理软件名称

选择包含的内容