工业水处理 ›› 2008, Vol. 28 ›› Issue (6): 56-58. doi: 10.11894/1005-829x.2008.28(6).56

• 试验研究 • 上一篇    下一篇

聚季铵盐反相破乳剂的合成及性能评价

王素芳1,2, 林蓓2, 马英3, 滕厚开2   

  1. 1. 天津大学化工学院, 天津 300072;
    2. 天津化工研究设计院, 天津 300131;

    3. 冀东油田分公司, 河北唐山 063200
  • 收稿日期:2008-03-20 出版日期:2008-06-20 发布日期:2010-10-01
  • 作者简介:王素芳(1971- ),1997年毕业于兰州大学,硕士,高级工程师,天津大学在职博士。电话:022-26689147,E-mail: wsufan@yahoo.com.cn。

Study on the synthesis and properties of a novel reverse demulsifier of polyquaternary ammonium

Wang Sufang1,2, Lin Pei2, Ma Ying3, Teng Houkai2   

  1. 1. School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, China;
    2. Tianjin Research and Design Institute of Chemical Industry, Tianjin 300131, China;
    3. Jidong Branch, China National Petroleum Corporation, Tangshan 063200, China
  • Received:2008-03-20 Online:2008-06-20 Published:2010-10-01

摘要:

以环氧氯丙烷和二甲胺、叔胺、多乙烯多胺等合成了聚季铵盐, 并与聚铝复配, 得到了适于采油污水处 理的高效反相破乳剂 TS-761L; 研究了反应时间、复配比例对产品性能的影响; 确定了合成聚季铵盐的最佳保温时 间为 4.5 h, 聚季铵盐与无机絮凝剂的最佳复配比例为 1: 1。应用研究表明:TS-761L 投加质量浓度为 50 mg/L 时,除油 率达到 97%, 悬浮物去除率达 94%, 是一种高效反相破乳剂。

关键词: 聚季铵盐, 反相破乳剂, 采油污水, 絮凝剂

Abstract:

A series polyquaternary ammonium (PQA) have been synthesized with epichlorohydrin, dimethylamine, trialkylamine and multiethylenemultiamine.A novel reverse demulsifier, TS-761L,which is suitable for treating oil- making wastewater, is prepared by PQA and PAC.The effect of its reaction time and the ratio of the two components on the properties of the product have been studied.The optimal reaction time is 4.5 h and the technology ratio is 1∶ 1.The experimental results for treating the wastewater show that when the dosage is 50 mg/L, the deoil rate and suspended solid removal rates could reach 97% and 94% respectively.It is a kind of highly efficient reverse demulsifier.

Key words: polyquaternary ammonium, reverse demulsifier, oil-making wastewater, flocculant

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