工业水处理 ›› 2012, Vol. 32 ›› Issue (1): 75-78. doi: 10.11894/1005-829x.2012.32.(1).75

• 工程实例 • 上一篇    下一篇

含铬电镀废水回用及铬酸回收工程实践

张文启1, 饶品华1, 张兴林2   

  1. 1. 上海工程技术大学化学化工学院, 上海 201620;
    2. 上海山青水秀环境工程有限公司, 上海 201615
  • 收稿日期:2011-11-07 修回日期:2011-11-07 出版日期:2012-01-20 发布日期:2014-10-08
  • 作者简介:张文启(1966- ),2005 年毕业于哈尔滨工业大学,博士,教授。E-mail:zhangwenqi_hit@163.com。
  • 基金资助:

    上海市教委创新项目(11ZZ176);上海市自然基金(10ZR1412600)

Engineering practice on electroplating chromium-containing wastewater reuse and waste chromic acid recycling

Zhang Wenqi1, Rao Pinhua1, Zhang Xinglin2   

  1. 1. School of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China;
    2. Shanghai Shanqingshuixiu Environmental Engineering Co., Ltd., Shanghai 201615, China
  • Received:2011-11-07 Revised:2011-11-07 Online:2012-01-20 Published:2014-10-08

摘要:

某减震器集团有限公司的钢件镀铬过程中产生大量漂洗废水,总量约为300 t/d,主要污染物为Cr(Ⅵ)及Fe、Zn、Mn 等金属离子。该企业原采用化学沉淀法对废水进行处理,但难以满足日益提高的废水处理要求,需进行工程改造。以离子交换技术为核心,灵活转换树脂类型,在较低的成本下使废水处理出水达到企业生产标准要求,实现了废水回用;成功回收了铬酸溶液,经浓缩后回用到生产线上,为企业节约了生产成本。

关键词: 电镀废水, 铬酸, 回收, 离子交换

Abstract:

A great deal of rinsing wastewater is produced in the process of electroplating of steel workpiece at a shock absorber group company. Its total quantity is about 300 t/d,and the main pollutants of the wastewater are Cr(Ⅵ),Fe2+,Zn2+,Mn2+. Precipitation process was used for this wastewater treatment in the enterprise. However,that process was difficult to meet the increasingly higher requirements of wastewater treatment at present,therefore,must be reformed. In this engineering practice,different ion exchange resins have been used properly for the wastewater treatment,and the effluent can meet the water quality standard with lower cost,realizing the reuse of wastewater and the recovery of chromic acid solution successfully. After the solution is concentrated,it can be reused in production,and save operating cost for the enterprise.

Key words: electroplating wastewater, chromic acid, reuse, ion exchange

中图分类号: